Cu基络合物催化甲醇液相氧化羰化反应

针对甲醇液相氧化羰基化法合成碳酸二甲酯(DMC)工艺,开发了新型Cu基络合催化剂(CuB rnLm)。对CuB rnLm催化剂的活性及其稳定性进行了研究。实验结果表明,采用该催化剂,甲醇转化率和DMC选择性较高;元素价态和物质结构分析表明,CuB rnLm催化剂循环使用5次后仍保持较好的稳定性。采用正交设计和中心响应曲面法设计实验,并使用S tatistica软件进行统计分析,寻求出反应的主要影响因素,并得到优化的工艺条件:反应温度100~110℃、反应压力3.0~3.5M Pa、反应时间4~6h、CuB rnLm催化剂质量浓度(以甲醇的体积计)0.15~0.20g/mL。在此工艺条件下,甲醇转化率可达23%以上,DMC的选择性为96%~98%。     

一种基于双阈值红外图像增强新算法

针对红外图像的特点,提出了一种基于双阈值的红外图像增强算法.首先利用第一类灰度阈值,将图像分割成感兴趣的目标区及背景区两部分;然后根据各区域的特点,提取两部分局部直方图,并根据第二类阈值对各部分使用不同的算法进行修正,最后基于各自修正的局部直方图,在两部分灰度空间范围内进行直方图均衡化.实验表明,该算法克服了直方图均衡化对背景和噪声增强过度的问题以及基于直方图单一阈值的增强算法不具有普适性等缺点.实验证明,该算法对红外图像增强后,图像对比度和信噪比都大幅提高,具有较强的实用价值.     

A refined algorithm for multisensor image registration based on pixel migration.

Multimodality image registration via pixel migration is a powerful approach. However, it suffers from a serious problem--the global maximum on the sum of squared gradient magnitude (SSG) surface does not correspond to the correct solution of registration. To solve the problem, we partition the search space into feasible and infeasible regions. The genetic algorithm (global optimizer) is used to obtain a good initial estimate of registration parameters and followed by a fast refining with Powell's approach (local optimizer). The experimental results demonstrate that the use of this modified pixel migration algorithm on multisensor image registration is very effective.     

Reduced-rate retransmissions for spread-spectrum packet radio multimedia networks

A reduced-rate retransmission (RRR) scheme is proposed for improving the throughput performance of spread-spectrum packet radio networks. The scheme takes advantages of the available multi-rate scalable source coding techniques. It assumes that several versions of a data packet with different sizes (number of information bits) are available. The transmission of a packet starts from its full-size version. If the full-size version is not correctly received, its half-size version is used in the retransmission. If further retransmissions are needed, the quarter-size version and so on are used. The shrunk packets are transmitted either in a minislot if the processing gain is kept the same, or occupying a slot duration by increasing the processing gain proportionally. In both cases, the effective signal to interference ratio for a packet is increased. As a result, the system throughput is improved. Theoretical and numerical results are provided in this paper which illustrate the throughput improvement. Another advantage of the proposed RRR scheme is that the packet-size reduction provides finer granules for link adaptation. Therefore, it is especially suitable for multimedia applications for which codes of variable rate for the source data are available and which can tolerate gracefully degraded quality of service. The performance of the proposed scheme in fading channels is also addressed.     

服务质量测量技术及其应用

文章在概述服务质量测量技术的基础上，介绍了服务质量测量技术的服务质量性能评估、网络推测、网络定位等应用，并给出了服务质量测量的一般数学模型。     

磷酸酯类离子液体在燃油深度脱硫中的应用

研究了3种磷酸酯类离子液体,即1,3-二甲基咪唑磷酸二甲酯盐([MM im]DM P)、1-乙基-3-甲基咪唑磷酸二乙酯盐([EM im]DEP)和1-丁基-3-甲基咪唑磷酸二丁酯盐([BM im]DBP)的制备过程,考察了这3种磷酸酯类离子液体对模型油中3-甲基噻吩、苯并噻吩和二苯并噻吩的脱除效果及磷酸酯类离子液体的电化学再生方法。实验结果表明,这3种磷酸酯类离子液体的脱硫能力强弱顺序为:[EM im]DEP>[BM im]DBP[MM im]DM P;且对二苯并噻吩的脱除效果最好,对苯并噻吩的脱除效果次之,对3-甲基噻吩的脱除效果较差。以[EM im]DEP为萃取剂,油剂质量比为1∶1时,经5次萃取后,二苯并噻吩的脱除率可达到99.5%。利用电解法对[EM im]DEP进行了再生,在5~10V电压下电解10h,[EM im]DEP的脱硫率可以达到新鲜[EM im]DEP的90%以上。     

电磁发射兵器用电容器的选取

本文首先从理论上论述了膜电容器的储能密度与寿命之间的关系，对国际电容器制造水平和趋势进行了分析，提出采用干式金属化膜电容器作为储能元件。最后，根据电磁发射兵器整体寿命配合原则，提出高储能密度脉冲电容器的合理寿命指标。     

Recovery of gold cyanide using inherently conducting polymers

Removal of gold from basic solutions containing [Au(CN)₂]^? has been demonstrated using the inherently conducting polymer polypyrrole. Polymers containing sulfonated aromatic dopants have been found to display a significant ability to remove gold from such solutions. Experiments performed in solutions containing both gold and copper cyanide complexes indicate that the recovery process is not highly selective. However, the polypyrroles used display significantly faster rates of gold recovery than activated carbon. © 2003 Society of Chemical Industry     

Evaluation of the Properties of Si3N4/Si3N4 Joint Brazed Using a Filler Alloy Containing Pd

Si3N4 ceramic was jointed to itself using a filler alloy of Cu76.5Pd8.5Ti15, and the mechanical properties of the jointwere measured and analyzed. By using a filler alloy of Cu76.5Pd8.5Ti15, the SisN4/SisN4 joints were obtained bybrazing at 1373～1473 K f     

宽带光接入技术的发展

首先介绍了宽带光接入网的特征和主要应用需求,以及目前几种主要宽带光接入技术的特点,最后分析了光接入技术的应用发展方向.