Use of sea water in the flotation of carbonate rich sedimentary phosphate rock

There is an appreciable amount of carbonaceous sedimentary phosphate deposits in the northern Africa and the Middle East which are expected to gain importance in the near future because of the depletion of the deposits in Florida. In many of the regions where phosphate deposits are found there is a shortage of fresh water, and sea is not very far. The use of sea water instead of fresh water in flotation of carbonaceous phosphate rock is successfully demonstrated. Thus an appreciable reduction in the operating cost and an ample amount of saving in the fresh water resources of the region is expected.     

Heat exchangers for he II cooling loops with self-sustained fountain effect pumps

A cooling cycle with He II convection driven by self-sustained fountain effect pumps is being investigated. Special attention is drawn to the problem of heat transfer at both ends of the superfilter of this loop. The heat exchanger requirements are derived from theoretical considerations on the degradation of the cooling characteristic effected by non-perfect heat exchangers. A shell and tube type heat exchanger, optimized for the warm end of the filter has been operated in this loop with a thermal load of up to 9 W, with 2.8 g s⁻¹ maximum helium flow rate and with inlet temperatures between 1.8 and 3.4 K. Its performance is well described by computations. A different heat exchanger design with finned Cu walls is suggested for the cold end of the pump. Some considerations on its optimization are given.     

Investigation of the stability of tablets prepared from sucrose and citric acid anhydride utilizing response surface methodology

Inversion of sucrose is a stability problem particularly of candies with acidic taste that contain sucrose and small amounts of organic acids such as citric acid, since the free d-fructose produced by hydrolysis is hygroscopic. The following possibilities were investigated for preventing the hydrolysis of sucrose in tablets containing sucrose and citric acid: Adding various amounts of tri-sodium citrate to the formulation to neutralize the citric acid, (Hot) melt coating of citric acid and tri-sodium citrate with a vegetable fat at different coating ratios, variation of the ratio of coated citric acid and tri-sodium citrate in formulations, and compressing the formulations with different compression forces. After tablet processing and storage of tablets, the concentration of d-fructose was determined on the basis of enzymatic reactions. A response surface central composite design was used. The above-mentioned variations were chosen as independent variables and the amount of d-fructose was chosen as response variable. The lowest rates of inversion could be achieved by increasing the content of tri-sodium citrate and the ratio of coating material and decreasing the ratio of coated citric acid and tri-sodium citrate in the tablet formulations. The compression force had no significant effect on the inversion of sucrose.     

Lipid peroxides, glutathione, gamma-glutamylcysteine synthetase and gamma-glutamyltranspeptidase activities in several tissues of rats following water-immersion stress

The effects of water-immersion restraint (WIR) stress on lipid peroxide, glutathione (GSH), glutathione peroxidase (GSH-Px), gamma-glutamylcysteine synthetase (gamma-GCS) and gamma-glutamyltranspeptidase (gamma-GT) activities in several tissues of rats were investigated. Hepatic and intestinal lipid peroxide levels were increased significantly in the WIR stress group. In both tissues, GSH levels were significantly decreased and gamma-GCS activity was significantly increased. In addition, gamma-GT activities remained unchanged in both tissues following WIR stress. However, lipid peroxide and GSH levels did not change in the stomach and brain in the WIR stress group compared to the control group. These results suggest that lipid peroxidation, but not the depression of GSH synthesis and/or the increase of GSH breakdown may be a factor in hepatic and intestinal GSH reduction following WIR stress.     

Synthesis and characterization of novel polyacrylate-clay sol-gel materials

Organo-functional silanes which were able to form chemical bonds with kaolinite and could also have an affinity to the materials of concern here, were studied by the sol-gel process. Polymethacrylate with trialkoxy silyl functional groups were prepared, hydrolysed and co-condensed with kaolinite. The progress of the hydrolysis, which proceeded very slowly, was followed by Karl-Fischer titration. Thermal behavior was investigated by differential thermal analysis. The extent of the reaction leading to network formation was qualitatively followed by Fourier transform-infrared spectroscopy and X-ray diffraction. Free-radical polymerization was carried out ultrasonically in the presence of a catalyst. Trimethoxy silane end-capped silane was found to be covalently bonded to kaolinite. The copolymers, with various amounts of kaolinite, were then hydrolysed and co-condensed in the presence of a catalyst to yield sol-gel materials which have a controllable combination of properties of both the polymer and kaolinite.     

Inotropic effects of glyceryl trinitrate and spontaneous NO donors in the dog heart

Facial fractures may portend intracranial and skullbase injury and may lead to rapid compromise of the airway. Primary care physicians may provide emergency care for patients who have sustained facial trauma. After immediate resuscitation and stabilization, management of facial fractures requires knowledge of the anatomy, rapid treatment methods and identification of potential associated injuries for each type of facial fracture. Differentiation between the life-threatening aspects of these injuries and the less urgent, but more apparent, facial injuries will lessen the risk of complications such as bleeding, meningitis and asphyxia. Knowledge of the anatomy of the facial skeleton and of the potential injuries associated with each of the various types of facial fractures will facilitate effective management decisions. Consultation should be sought when functional features are involved or when the injury threatens to produce future cosmetic anomalies.     

The effect of elevated temperature and silicon addition on a cobalt-based wear resistant superalloy

The effects of an elevated temperature and a 5 wt% silicon addition on the resultant microstructure and inherent phases of Stellite 6 were investigated by using room and high temperature optical microscopy, X-ray diffraction, scanning electron microscopy (SEM) and also bulk hardness and microhardness measurements. It has been observed that exposing Stellite 6 to heat treatments at 1000°C results in a characteristic textured structure and coarsening of interdendritic regions due to bulk diffusion. In addition, both dendritic and interdendritic hardness values increase due to texture formation and increased amounts of carbide and intermetallic phases, respectively. On the other hand, silicon addition to Stellite 6 causes the transformation of the original spongy dendritic microstructure in as-cast Stellite 6 to a eutectic dendritic and skeleton interdendritic structure. Also, when silicon added Stellite 6 was heat treated at 1000°C, particulates emanating from the interdendritic skeleton become irregularly dispersed in the dendritic region. In addition, similarly to Stellite 6; a high temperature heat treatment results in an increase in hardness values of silicon added Stellite 6 due to the presence of an Co₂ Si intermetallic phase.