Dynamic diffusion model for tracing the real-time potential response of polymeric membrane ion-selective electrodes

A numerical solution for the prediction of the time-dependent potential response of a polymeric-based ion-selective electrode (ISE) is presented. The model addresses short- and middle-term potential drifts that are dependent on changes in concentration gradients in the aqueous sample and organic membrane phase. This work has important implications for the understanding of the real-time response behavior of potentiometric sensors with low detection limits and with nonclassical super-Nernstian response slopes. As a model system, the initial exposure of membranes containing the well-examined silver ionophore O,O' '-bis[2-(methylthio)ethyl]-tert-butylcalix[4]arene was monitored, and the large observed potential drifts were compared to theoretical predictions. The model is based on an approximate solution of the diffusion equation for both aqueous and organic diffusion layers using a numerical scheme (finite difference in time and finite elements in space). The model may be evaluated on the basis of experimentally available parameters and gives time-dependent information previously inaccessible with a simpler steady-state diffusion model. For the cases studied, the model gave a very good correlation with experimental data, albeit with lower than expected diffusion coefficients for the organic phase. This model may address numerous open questions regarding the response time and memory effects of low-detection-limit ion-selective electrodes and for other membrane electrodes where ion fluxes are relevant.     

Der Einfluß von Bariumoxid auf die Zähigkeit von Hochofenschlacken

Messung der Zähigkeit der Hochofenschlacken mit einem Massengehalt von 0 bis 14% BaO. Änderung der Aktivierungsenergie des viskosen Fließens mit steigendem Anteil an Bariumoxid. Veränderungen der Schlackenstruktur sowie Entmischungen und Abweichungen der chemischen Zusammensetzung in Mikrobereichen bei Erhöhung der Bariumoxidgehalte.     

The effect of boron on the stereological characteristics of the structural phases present in the structure of the 13% Cr white iron

In this paper, the results of the examination of the effect of boron, in the amounts of 0.26, 0.39 and 0.59 wt%, on the stereological characteristics of the structural phases present in the structure of 13%Cr–2.3%C white iron, are reviewed. The examined stereological characteristics were: volume fraction of phases, dendrite arm spacing-DAS and size of eutectic carbides.It has been concluded that with the increasing of boron content, the volume fraction of the matrix of austenite partially transformed into martensite decreases, whereas the volume fraction of the eutectic carbides increases. The increasing of the boron content also decreases the value of DAS, but at the same time the eutectic carbides become coarser.     

Modeling diffraction in free-space optical interconnects by the mode expansion method

Free-space optical interconnects (FSOIs), made up of dense arrays of vertical-cavity surface-emitting lasers, photodetectors and microlenses can be used for implementing high-speed and high-density communication links, and hence replace the inferior electrical interconnects. A major concern in the design of FSOIs is minimization of the optical channel cross talk arising from laser beam diffraction. In this article we introduce modifications to the mode expansion method of Tanaka et al. [IEEE Trans. Microwave Theory Tech. MTT-20, 749 (1972)] to make it an efficient tool for modelling and design of FSOIs in the presence of diffraction. We demonstrate that our modified mode expansion method has accuracy similar to the exact solution of the Huygens-Kirchhoff diffraction integral in cases of both weak and strong beam clipping, and that it is much more accurate than the existing approximations. The strength of the method is twofold: first, it is applicable in the region of pronounced diffraction (strong beam clipping) where all other approximations fail and, second, unlike the exact-solution method, it can be efficiently used for modelling diffraction on multiple apertures. These features make the mode expansion method useful for design and optimization of free-space architectures containing multiple optical elements inclusive of optical interconnects and optical clock distribution systems.     

On the Feedback Capacity of Power-Constrained Gaussian Noise Channels With Memory

For a stationary additive Gaussian-noise channel with a rational noise power spectrum of a finite-order L, we derive two new results for the feedback capacity under an average channel input power constraint. First, we show that a very simple feedback-dependent Gauss-Markov source achieves the feedback capacity, and that Kalman-Bucy filtering is optimal for processing the feedback. Based on these results, we develop a new method for optimizing the channel inputs for achieving the Cover-Pombra block-length- n feedback capacity by using a dynamic programming approach that decomposes the computation into n sequentially identical optimization problems where each stage involves optimizing O(L ²) variables. Second, we derive the explicit maximal information rate for stationary feedback-dependent sources. In general, evaluating the maximal information rate for stationary sources requires solving only a few equations by simple nonlinear programming. For first-order autoregressive and/or moving average (ARMA) noise channels, this optimization admits a closed-form maximal information rate formula. The maximal information rate for stationary sources is a lower bound on the feedback capacity, and it equals the feedback capacity if the long-standing conjecture, that stationary sources achieve the feedback capacity, holds     

Dirty RF: A New Paradigm

The implementation challenge for new low-cost low-power wireless modem transceivers has continuously been growing with increased modem performance, bandwidth, and carrier frequency. Up to now we have been designing transceivers in a way that we are able to keep the analog (RF) problem domain widely separated from the digital signal processing design. However, with today’s deep sub-micron technology, analog impairments – “dirt effects” – are reaching a new problem level which requires a paradigm shift in the design of transceivers. Examples of these impairments are phase noise, non-linearities, I/Q imbalance, ADC impairments, etc. In the world of “Dirty RF” we assume to design digital signal processing such that we can cope with a new level of impairments, allowing lee-way in the requirements set on future RF sub-systems. This paper gives an overview of the topic and presents analytical evaluations of the performance losses due to RF impairments as well as algorithms that allow to live with imperfect RF by compensating the resulting error effects using digital baseband processing.     

A CALCULATION METHOD OF OBTAINING DESORPTION ISOTHERMS OF BEECH (FAGUSMOESL4CA) WOOD

ABSTRACT

This paper presents the specific methods to obtain sorption isotherms. Sorption isotherms were first obtained experimentally for 20°C and 100°C and then, by using the presented method, isotherms were also obtained for 50°C and 80°C. The same treatment can be applied in finding any isotherm sorption in the temperature range between 20°Cand 100°C.

The experiments were carried out on beech (Fagus moesiaca) and sample dimensions were 3×3×3cm. Based on the results of the experiment, by regression analysis, the most suitable analytic formula was proposed. It relsites temperature and air humidity with the equilibrium moisture content in wood. Experimental results were compared with psychrometric tables and Bramhall's formula for desorption curves with good agreement. This proves that the method presented in this paper is precise and efficient to decrease the lime needed to obtain sorption isotherms experimentally.     

Fully-Naphthalenoid Hydrocarbons and their Conjugation Modes

Abstract

A fully-naphthalenoid hydrocarbon (FUN) is a benzenoid hydrocarbon whose all π-electrons can be (formally) grouped into disjoint naphthalene-units. The cyclic conjugation in FUNs is studied by means of the energy-effects of their various cycles. It is found that the dominant conjugation modes in FUNs are those involving the 6- and 10-membered cycles of the “full” naphthalene fragments. The cycles belonging to the “empty” domains of a FUN have significantly smaller energy-effects.     

Influence of microstructure and phase composition on the nanoindentation characterization of bioceramic materials based on hydroxyapatite

The aim of the study was to investigate the influence of microstructure and phase composition on the mechanical behaviour of hydroxyapatite (HAp) and biphasic HAp/β-tricalcium phosphate (β-TCP) bioceramic materials using nanoindentation. The formation of β-TCP phase in the HAp ceramic had the predominant influence on the nanomechanical properties of compact ceramics. For investigated microstructures there appear to be a slight decrease in the elastic modulus with increasing load and a higher decrease in hardness, which are in agreement with upper bounds of the results reported in literature. Maximal value of reduced modulus and hardness is yielded with pure HAp, and is measured to be 133.76 GPa for average grain size of 3 μm and 12.18 GPa for average grain size of 140 nm, respectively. The average modulus and hardness results for HAp/β-TCP ceramics with higher (101.61 GPa, 6.76 GPa) and lower grain size (115.72 GPa, 8.76 GPa) show sufficient mechanical properties in order to serve as hard tissue replacement material.