Trimetallic PtCoFe Alloy Monolayer Superlattices as Bifunctional Oxygen‐Reduction and Ethanol‐Oxidation Electrocatalysts

A synthesis strategy for the preparation of trimetallic PtCoFe alloy nanoparticle superlattices is reported. Trimetallic PtCoFe alloy monolayer array of nanoparticle superlattices with a large density of high index facets and platinum‐rich surface are successfully prepared by coreduction of metal precursors in formamide solvent. The concentration of cetyl trimethyl ammonium bromide plays a vital role for the formation of a monolayer array of nanoparticle superlattices, while the size of nanoparticles is determined by NaI. The prepared monolayer array of nanoparticle superlattices is the superior catalyst for oxygen reduction reaction as well as for ethanol oxidation owing to their specific structural and compositional characteristics.     

Nutratherapeutics approach against cancer: tomato‐mediated synthesised gold nanoparticles

In this study, an eco‐friendly biosynthesis of stable gold nanoparticles (T‐GNPs) was carried out using different concentrations of tomato juice (nutraceuticals) as a reducing agent and tetrachloroauric acid as a metal precursor to explore their potential application in cancer therapeutics. The synthesis of T‐GNPs was monitored by UV‐visible absorption spectroscopy, which unveiled their formation by exhibiting the typical surface plasmon absorption maxima at 522 nm. The size of T‐GNPs was found to be 10.86 ± 0.6 nm. T‐GNPs were characterised by dynamic light scattering, zeta potential, transmission electron microscopy analysis and Fourier transform infrared spectroscopy. T‐GNPs were further investigated for their anti‐cancer activity against human lung carcinoma cell line (A ₅₄₉) and human cervical cancer cell line wherein the IC₅₀ values were found to be 0.286 and 0.200 mM, respectively. T‐GNPs inhibited the growth of cancer cells by generating ROS and inducing apoptosis. T‐GNPs were found highly effective by virtue of their size, metallic property and capping molecules. Thus, this study opens up the prospects of using nutraceutical (tomato juice) as nutratherapeutic agent (T‐GNPs) against critical diseases like lung cancer and cervical cancer.Inspec keywords: gold, nanoparticles, particle size, cancer, ultraviolet spectra, visible spectra, electrokinetic effects, transmission electron microscopy, Fourier transform infrared spectra, cellular biophysics, spectrochemical analysis, nanomedicine, nanofabricationOther keywords: tomato‐mediated synthesised gold nanoparticles, tomato juice, reducing agent, tetrachloroauric acid, cancer therapeutics, UV‐visible absorption spectroscopy, surface plasmon absorption, dynamic light scattering, zeta potential, transmission electron microscopy analysis, Fourier transform infrared spectroscopy, human lung carcinoma cell line, anticancer activity, human cervical cancer cell line, nutratherapeutic agent, lung cancer, Au     

End-to-End 2D Convolutional Neural Network Architecture for Lung Nodule Identification and Abnormal Detection in Cloud

The extent of the peril associated with cancer can be perceived from the lack of treatment, ineffective early diagnosis techniques, and most importantly its fatality rate. Globally, cancer is the second leading cause of death and among over a hundred types of cancer; lung cancer is the second most common type of cancer as well as the leading cause of cancer-related deaths. Anyhow, an accurate lung cancer diagnosis in a timely manner can elevate the likelihood of survival by a noticeable margin and medical imaging is a prevalent manner of cancer diagnosis since it is easily accessible to people around the globe. Nonetheless, this is not eminently efficacious considering human inspection of medical images can yield a high false positive rate. Ineffective and inefficient diagnosis is a crucial reason for such a high mortality rate for this malady. However, the conspicuous advancements in deep learning and artificial intelligence have stimulated the development of exceedingly precise diagnosis systems. The development and performance of these systems rely prominently on the data that is used to train these systems. A standard problem witnessed in publicly available medical image datasets is the severe imbalance of data between different classes. This grave imbalance of data can make a deep learning model biased towards the dominant class and unable to generalize. This study aims to present an end-to-end convolutional neural network that can accurately differentiate lung nodules from non-nodules and reduce the false positive rate to a bare minimum. To tackle the problem of data imbalance, we oversampled the data by transforming available images in the minority class. The average false positive rate in the proposed method is a mere 1.5 percent. However, the average false negative rate is 31.76 percent. The proposed neural network has 68.66 percent sensitivity and 98.42 percent specificity.     

Leveraging Transfer Learning for Spatio-Temporal Human Activity Recognition from Video Sequences

Human Activity Recognition (HAR) is an active research area due to its applications in pervasive computing, human-computer interaction, artificial intelligence, health care, and social sciences. Moreover, dynamic environments and anthropometric differences between individuals make it harder to recognize actions. This study focused on human activity in video sequences acquired with an RGB camera because of its vast range of real-world applications. It uses two-stream ConvNet to extract spatial and temporal information and proposes a fine-tuned deep neural network. Moreover, the transfer learning paradigm is adopted to extract varied and fixed frames while reusing object identification information. Six state-of-the-art pre-trained models are exploited to find the best model for spatial feature extraction. For temporal sequence, this study uses dense optical flow following the two-stream ConvNet and Bidirectional Long Short Term Memory (BiLSTM) to capture long-term dependencies. Two state-of-the-art datasets, UCF101 and HMDB51, are used for evaluation purposes. In addition, seven state-of-the-art optimizers are used to fine-tune the proposed network parameters. Furthermore, this study utilizes an ensemble mechanism to aggregate spatial-temporal features using a four-stream Convolutional Neural Network (CNN), where two streams use RGB data. In contrast, the other uses optical flow images. Finally, the proposed ensemble approach using max hard voting outperforms state-of-the-art methods with 96.30% and 90.07% accuracies on the UCF101 and HMDB51 datasets.     

Infrared Spectroscopy-Based Chemometric Analysis for Lard Differentiation in Meat Samples

One of the most pressing concerns for the consumer market is the detection of adulteration in meat products due to their preciousness. The rapid and accurate identification mechanism for lard adulteration in meat products is highly necessary, for developing a mechanism trusted by consumers and that can be used to make a definitive diagnosis. Fourier Transform Infrared Spectroscopy (FTIR) is used in this work to identify lard adulteration in cow, lamb, and chicken samples. A simplified extraction method was implied to obtain the lipids from pure and adulterated meat. Adulterated samples were obtained by mixing lard with chicken, lamb, and beef with different concentrations (10%–50% v/v). Principal component analysis (PCA) and partial least square (PLS) were used to develop a calibration model at 800–3500 cm⁻¹. Three-dimension PCA was successfully used by dividing the spectrum in three regions to classify lard meat adulteration in chicken, lamb, and beef samples. The corresponding FTIR peaks for the lard have been observed at 1159.6, 1743.4, 2853.1, and 2922.5 cm⁻¹, which differentiate chicken, lamb, and beef samples. The wavenumbers offer the highest determination coefficient R² value of 0.846 and lowest root mean square error of calibration (RMSEC) and root mean square error prediction (RMSEP) with an accuracy of 84.6%. Even the tiniest fat adulteration up to 10% can be reliably discovered using this methodology.     

Simultaneous state estimation and parameter identification in linear fractional order systems using coloured measurement noise

In the present paper, the identification and estimation problem of a single-input–single-output (SISO) fractional order state-space system will be addressed. A SISO state-space model is considered in which parameters and also state variables should be estimated. The canonical fractional order state-space system will be transformed into a regression equation by using a linear transformation and a shift operator that are appropriate for identification. The identification method provided in this paper is based on a recursive identification algorithm that has the capability of identifying the parameters of fractional order state-space system recursively. Another subject that will be addressed in this paper is a novel fractional order Kalman filter suitable for the systems with coloured measurement noise. The promising performance of the proposed methods is verified using two stable fractional order systems.     

Identifying plant species using mid-wave infrared (2.5–6 μm) and thermal infrared (8–14 μm) emissivity spectra

Plant species discrimination using remote sensing is generally limited by the similarity of their reflectance spectra in the visible, NIR and SWIR domains. Laboratory measured emissivity spectra in the mid infrared (MIR; 2.5 μm–6 μm) and the thermal infrared (TIR; 8 μm–14 μm) domain of different plant species, however, reveal significant differences. It is anticipated that with the advances in airborne and space borne hyperspectral thermal sensors, differentiation between plant species may improve. The laboratory emissivity spectra of thirteen common broad leaved species, comprising 3024 spectral bands in the MIR and TIR, were analyzed. For each wavelength the differences between the species were tested for significance using the one way analysis of variance (ANOVA) with the post-hoc Tukey HSD test. The emissivity spectra of the analyzed species were found to be statistically different at various wavebands. Subsequently, six spectral bands were selected (based on the histogram of separable pairs of species for each waveband) to quantify the separability between each species pair based on the Jefferies Matusita (JM) distance. Out of 78 combinations, 76 pairs had a significantly different JM distance. This means that careful selection of hyperspectral bands in the MIR and TIR (2.5 μm–14 μm) results in reliable species discrimination.     

SAPDS: self-healing attribute-based privacy aware data sharing in cloud

This paper addresses the issue of data governance in a cloud-based storage system. To achieve fine-grained access control over the outsourced data, we propose Self-Healing Attribute-based Privacy Aware Data Sharing in Cloud (SAPDS). The proposed system delegates the key distribution and management process to a cloud server without seeping out any confidential information. It facilitates data owner to restrain access of the user with whom data has been shared. User revocation is achieved by merely changing one attribute associated with the decryption policy, instead of modifying the entire access control policy. It enables authorized users to update their decryption keys followed by each user revocation, making it self-healing, without ever interacting with the data owner. Computation analysis of the proposed system shows that data owner can revoke n′ users with the complexity of O(n′). Besides this, legitimate users can update their decryption keys with the complexity of O(1).     

Timely vs. delayed CEO turnover

This paper investigates changes in company performance following timely versus delayed CEO resignations due to financial wrongdoings. A timely resignation is proactively pushed by the company, and a delayed resignation is driven by investigations initiated by the SEC or other regulatory authorities. Our results show significant negative abnormal returns following the announcement of CEO resignations. In addition, compared with timely resignations, delayed resignations experience a larger and longer lasting negative stock market reaction. This suggests that CEO resignations due to financial wrongdoings are not perceived as good news by investors, and the delayed resignations could make investors lose more confidence, possibly because of worries about the ineffective corporate governance and supervision mechanism. We have found a significant negative relationship between CEO-chairman duality and the timeliness of CEO resignations. Our results have important implications for investors and policy makers.