STUDY ON THE ACETYLENE HYDROGENATION PROCESS FOR ETHYLENE PRODUCTION: SIMULATION,MODIFICATION, AND OPTIMIZATION

In this study, an industrial acetylene hydrogenation unit is simulated utilizing three available kinetic models. The results are compared against six-day experimental data and the best model is selected. Effects of feed temperature and the amount of injected hydrogen on ethylene selectivity are also studied. According to the simulation results, the unit is not working under its optimum conditions. Furthermore, by reduction of the hydrogen flow rate to 52 kg/h, process selectivity is increased. In addition, a new approach is proposed to modify the hydrogenation process and reduce undesired by-products. In the simulation of the modified process, hydrogenation reactors temperature, hydrogen flow rate, and H-1/H-2 ratio were regulated as adjustable parameters for the process optimization. The simulation shows that ethylene selectivity increases by 12%, while acetylene concentration and hydrogenation reactor temperature remains within acceptable ranges. Such selectivity could be achieved at the hydrogen flow rate of 50 kg/h with H-1/H-2 ratio of 0.1/0.9.     

Improving CO2/CH4 adsorptive selectivity of carbon nanotubes by functionalization with nitrogen-containing groups

Multi-walled carbon nanotubes containing oxygenated groups (O-MWCNTs) have been functionalized with ammonia to improve the adsorption capacity and selectivity of CO₂/CH₄ in gas adsorption process. The effects of oxygen and nitrogen containing functional groups (e.g. hydroxyl and amine), on CO₂ and CH₄ adsorption were studied. The ideal adsorption capacities of MWCNTs were determined using volumetric method at ambient temperature and moderate pressures (from 0.1 to 3.0 MPa). The MWCNTs containing nitrogen groups (N-MWCNTs) showed much higher adsorption capacity of CO₂ and selectivity of CO₂/CH₄ against the O-MWCNTs at different pressures. The highest selectivity was observed at lower pressures at 298 K for the N-MWCNTs. The dynamic adsorption experiments were carried out with a feed containing one to fivefold of CO₂ to CH₄ in a packed bed of N-MWCNTs at 298 K and atmospheric pressure. The breakthrough curves and breakthrough times of CO₂ and CH₄ were determined for the mixed gases. The results indicated high efficiency of the prepared N-MWCNTs in dynamic separation of CO₂ and CH₄.     

Influence of Zataria multiflora Boiss. essential oil on oxidative stability of sunflower oil

In this study, the influence of the application of 0.025%, 0.05% and 0.075% of Zataria multiflora Boiss. essential oil (EO) on oxidative stability of sunflower oil was examined and the EO was compared to butylated hydroxyanisole (BHA) and butylated hydroxytoluene (BHT) during storage at 37°C and 47°C. The main components of EO were identified as carvacrol (45.6%), p‐cymene (18.1%) and thymol (16.3%). Peroxide value (PV), anisidine value (AnV) and thiobarbituric acid (TBA) value measurement in sunflower oil showed that all concentrations of EO had a lower antioxidant effect in comparison to BHA and BHT. Samples supplemented with EO concentration of 0.075% were the most stable during storage at both temperatures (p<0.05). Furthermore, Totox value, antioxidant activity (AA), stabilization factor (F) and antioxidant power (AOP) determination confirmed efficacy of this EO as antioxidant in sunflower oil. EO also was able to reduce the stable 2,2‐diphenyl‐1‐picrylhydrazyl free radical (DPPH ^. ) with a 50% inhibition concentration (IC₅₀) of 34.3 ± 0.8 µg/mL. The results indicate that EO could be used as a natural antioxidant in oils for food uses.     

Influence of a curved conical turbulator on heat transfer augmentation in a helical double-pipe heat exchanger

The rate of heat transfer in helical pipes is much more than straight pipes. In the present study, heat transfer and fluid flow in a double-coil heat exchanger with an innovative swirl generator with a curved structure in the inner channel (hot side) are studied, numerically. The proposed turbulator has a curved structure and 12 blades to produce swirl flows. Also, two holes are considered at the semi-conical part of the turbulator. The effects of geometrical parameters of the proposed turbulator including the inner radius of the turbulator and the radius of the turbulator's holes are evaluated. Results indicate that the maximum effectiveness belongs to the case with inner diameter of the turbulator and radius of turbulator' holes equal to 19 and 3.6 mm, respectively, at $\dot{m}=0.008\mathrm{k}\mathrm{g}\mathrm{/}\mathrm{s}$. Also, the generated swirl flows by the turbulator has a significant influence on heat transfer augmentation. Furthermore, a high inner radius of the turbulator leads to an increase in heat transfer rate and effectiveness, consequently. As a result, by increasing the inner radius of turbulator by 26.7%, the effectiveness rises by 80% (maximum at $\dot{m}$ = 0.008 kg/s). Increasing the radius of turbulator's hole by 133.34% leads to an growth in effectiveness of about 50% (maximum at $\dot{m}$ = 0.058 kg/s).     

Vibration analysis of piezoelectric FGM sensors using an accurate method

In this study, free vibration analysis of moderately thick smart FG annular/circular plates with different boundary conditions is presented on the basis of the Mindlin plate theory. This structure comprised a host FG plate and two bonded piezoelectric layers. Piezoelectric layers are open circuit therefore this plate can be used as a sensor. According to power-law distribution of the volume fraction of the constituents, material properties vary continuously through the thickness of host plate while Poisson's ratio is set to be constant. Using Hamilton's principle and Maxwell electrostatic equation yields six complex coupled equations which are solved via an exact closed-form method. The accuracy of the frequencies is verified by the available literature, finite element method (FEM) and the Kirchhoff theory. The effects of plate parameters like boundary condition and gradient index are investigated and significance of coupling between in-plane and transverse displacements on the resonant frequency is proved.     

Tensile and flexural properties of injection-moulded short glass fibre and glass bead ABS composites in the presence of weldlines

The effect of weldline on tensile and flexural properties of ABS reinforced with short glass fibres (ABS/GF) and spherical glass beads (ABS/GB) was investigated as a function of glass fibre and glass bead concentrations. The weldline was formed in the moulded specimens by direct impingement of two opposing melt fronts (i.e. cold weld). It was found that elastic modulus of ABS/GF composites, with or without weldlines increased linearly with increasing volume fraction of fibres (ϕ_f), according to the rule-of-mixtures for moduli. The presence of weldline reduced tensile and flexural modulus of the ABS/GF composites. Weldline integrity factor for elastic modulus of ABS/GF composites decreased linearly with increasing ϕ_f. Results showed that tensile and flexural strength of ABS/GF increased with increasing ϕ_f in a nonlinear fashion. Flexural strength was consistently greater than tensile strength for the same ϕ_f. Weldline affected both strengths in a significant way; weldline integrity factor decreased with increasing ϕ_f and was independent of loading mode. Tensile and flexural modulus of ABS/GB composites increased linearly with increasing volume fraction of glass beads (ϕ_b), showing no loading mode dependency. Although modulus of the ABS/GB system was not affected significantly by the weldline, its strength was affected, and more so in flexure than in tension. Weld and unweld strengths decreased with increasing ϕ_b in both tension and flexure according to Piggott and Leidner relationship; for the same ϕ_b, flexural strength was always greater than tensile strength. Weldline integrity factor for tensile strength of ABS/GF system was considerably lower than that for ABS/GB system but weldline integrity factor for flexural strength was almost the same for the two composite systems.     

Preparation of and studies on the functional properties and bactericidal activity of the lysozyme–xanthan gum conjugate

The purpose of this research was to produce a xanthan gum–lysozyme conjugate (Lyz–XM) and to investigate the effect of conjugation on functional properties and antimicrobial properties of the conjugated products. The antimicrobial activity of Lyz is limited to Gram positive bacteria, but its antibacterial spectrum can be extended towards Gram negative bacteria by conjugation with carbohydrate through the Maillard reaction. Lyz was allowed to react with XG under mild Maillard reaction condition (pH 8.5 and 60 °C for 10 days) and conjugation was confirmed by SDS-PAGE, enzyme activity and determination of sugar content of the product. Results showed that under optimal conditions approximately 1.9 mmol XG was attached to one mol Lyz. The Lyz–XG conjugate showed higher solubility at acidic pHs and at different temperatures, increased heat stability with improved emulsion and foaming properties. Additionally, Lyz–XG conjugate showed antioxidant properties and significantly inhibited the growth of Staphylococcus aureus and Escherichia coli in a dose dependent manner. These findings may broaden food applications of Lyz as a functional ingredient with high quality emulsifier, foam producer or natural antibacterial agent in food or pharmaceutical industries.     

Using affective human-machine interface to increase the operation performance in virtual construction crane training system: A novel approach

In the construction industry, some progress have been achieved by researchers to design and implement environments for task training using VR technology and its derivatives such as Augmented and Mixed Reality. Although, these developments have been well recognized at the application level, however crucial to the virtual training system is the effective and reliable measurement of training performance of the particular skill and handling the experiment for long-run. It is known that motor skills cannot be measured directly, but only inferred by observing behaviour or performance measures. The typical way of measuring performance is through measuring task completion time and accuracy, but can be supported by indirect measurement of some other factors. In this paper, a virtual crane training system has been developed which can be controlled using control commands extracted from facial gestures and is capable to lift up loads/materials in the virtual construction sites. Then, we integrate affective computing concept into the conventional VR training platform for measuring the cognitive load and level of satisfaction during performance using human's forehead bioelectric-signals. By employing the affective measures and our novel control scheme, the designed interface could be adapted to user's affective status during the performance in real-time. This adaptable user interface approach helps the trainee to cope with the training for long-run performance, leads to gaining more expertise and provides more effective transfer of learning to other operation environments. The detailed methodology of the affective control is presented in the paper. The results and future applications of the proposed method for disabled users, especially from neck down are discussed.     

Constitutive Modeling of a Schistose Rock in the Himalaya

Strain‐controlled triaxial tests have been conducted using servo‐controlled loading system on three schistose rocks from a hydropower project in the Himalaya. A constitutive model based on the disturbed state concept is used to model the behavior of the rocks. Predictions are made using a single point method and finite element method. The constitutive model is found to provide satisfactory predictions. The DSC model is used to predict observed behavior of a powerhouse cavern; the relevant paper, “Analysis of a Powerhouse Cavern in the Himalaya,” appears in this issue.