An experimental and kinetic modeling study of cyclopentadiene pyrolysis: First growth of polycyclic aromatic hydrocarbons

The importance of 1,3-cyclopentadiene (CPD) and cyclopentadienyl (CPDyl) moieties in the growth of polycyclic aromatic hydrocarbons (PAHs) was studied using new experimental data and ab initio calculations. The experimental investigation was performed in a tubular continuous flow pyrolysis reactor under both high (24molN₂/molCPD)$(24{\text{mol}}_{{\text{N}}_2}/{\text{mol}}_{\text{CPD}})$ and low (5molN₂/molCPD)$(5{\text{mol}}_{{\text{N}}_2}/{\text{mol}}_{\text{CPD}})$ nitrogen dilutions, covering a temperature range of 873–1123 K, at a fixed pressure of 1.7 bara. At the most severe conditions up to 84% of CPD is converted, and the amount of PAHs is more than 65 wt%. Major products observed during CPD pyrolysis were benzene, indene, methyl-indenes and naphthalene, in line with previous studies. On-line GC × GC-FID/(TOF-MS) also allowed to quantify minor species (methane, toluene, styrene, phenanthrene, anthracene, etc.), never reported before at this level of accuracy. The new experimental data have been used to further analyze the role of the successive interactions of CPD, indene, and naphthalene as well as the recombination and addition reactions of their resonantly stabilized radicals and refine their kinetics. The results of the modeling study are in good agreement with existing and new experimental observations.     

Antifungal activity of sourdough fermented wheat germ used as an ingredient for bread making

This study aimed at investigating the antifungal activity of sourdough fermented (Lactobacillus plantarum LB1 and Lactobacillus rossiae LB5) wheat germ (SFWG). Preliminarily, methanol and water/salt-soluble extracts from SFWG were assayed by agar diffusion towards Penicillium roqueforti DPPMAF1. As shown by hyphal radial growth rate, the water/salt-soluble extract showed the inhibition of various fungi isolated from bakeries. The antifungal activity was attributed to a mixture of organic acids and peptides which were synthesized during fermentation. Formic (24.7 mM) acid showed the highest antifungal activity. Four peptides, having similarities with well known antifungal sequences, were identified and chemically synthesized. The minimal inhibitory concentration was 2.5–15.2 mg/ml. Slices of bread made by addition of 4% (wt/wt) of freeze dried SFWG were packed in polyethylene bags and stored at room temperature. Slices did not show contamination by fungi until at least 28 days of storage and behaved as the calcium propionate (0.3%, wt/wt).     

Nonenzymatic glucose sensing based on deposited palladium nanoparticles on epoxy-silver electrodes

A new approach for nonenzymatic glucose sensing, based on a simple modification of epoxy-silver surfaces deposited on the tip of commercial copper electric wires, is presented. Palladium was galvanically displaced on the surface of the epoxy-silver surface in order to obtain metal nanoparticles that act as catalyst for the direct oxidation of glucose. Scanning electron microscopy revealed the formation of the metal nanoparticles. X-ray photoelectron spectroscopy confirmed the metallic nature of the formed nanostructures on the surface. Electrochemical characterization and calibration of the palladium-modified epoxy-silver electrode is reported, obtaining a linear range of 1–20 mM for the detection of glucose with low interference of ascorbic acid and uric acid. A simple 3-step coulometry was used as the detection technique. The developed sensing material is believed to be a great candidate for integration in small devices for clinical essays, due to the simplicity and cost effectiveness of the presented approach, compared to the state-of-the-art devices reported recently in the literature. Simplicity in the coulometry determinations makes these Pd-modified epoxy-silver sensors a good candidate for easy glucose determinations.     

Assessment of biodiesel blending detection capability of the on-board diagnostic of the last generation automotive diesel engines

Results of a research project aimed at studying the capability to develop a method (economic and simple) for on-board biodiesel blending detection are described. The method is based on the direct measurement of the Indicated Mean Effective Pressure (IMEP).The study was carried out on a 2.0L four-cylinder “torque-controlled” Euro 5 diesel engine for passenger car (PC) application. This engine, equipped with instrumented glow plug for combustion closed-loop control, represents the state of the art of the diesel engine control technology.Two biodiesels were chosen for the experiments: a rapeseed methyl-ester (RME) and an aged RME, while the conventional diesel fuel was an European (EU) certification diesel fuel.Results indicate generally a good response in blending detection of the method. However, in order to attain an acceptable accuracy, a pre-calibration appears necessary.     

Functionalization of Scanning Force Microscopy Cantilevers via Galvanic Displacement Technique

A galvanic displacement technique is used to coat silicon scanning force microscopy cantilevers with copper. The copper coating is characterized using X-ray photoelectron spectroscopy, scanning force microscopy, contact angle measurements, scanning electron microscopy and energy-dispersive X-ray spectroscopy. This coating technique results in uniform, reflective and conformal films and hence, no stress-induced bending of the cantilever is observed. To demonstrate the effectiveness of this approach for tribological studies, the coated cantilevers are chemically modified with alkanethiol monolayers in order to functionalize the cantilevers. The effect of changed surface energy are detected with adhesion measurements in water and ethanol.     

Microstructure and mechanical properties of acicular mullite

Porous acicular mullite (ACM) ceramics are known to be mechanically robust even at high porosities. This study was undertaken to better understand what aspects of acicular mullite's needle-like microstructure affect the overall mechanical properties and how the microstructure might be modified to improve mechanical performance. ACMs with a variety of porosities, pore sizes, and needle diameters were produced, and their elastic moduli, flexure strengths, and fracture toughnesses were measured. Three-dimensional image analysis was an invaluable tool in determining the needle diameters of these complex 3D network structures. It was found that porosity was the most dominant factor in determining the mechanical properties of ACM and that its behavior could be described using the Gibson–Ashby foam model.     

Process simulation of a hybrid SOFC/mGT and enriched air/steam fluidized bed gasifier power plant

The aim of this work is to experimentally and numerically analyze the performance of a integrated power plant composed by a steam oxygen fluidized bed biomass gasifier fed by woods, a Solid Oxide Fuel Cell (SOFC) and a micro Gas Turbine (mGT). The numerical analysis is carried out by using ChemCAD software. In particular, SOFC and gasifier were modeled using proper developed Fortran subroutines interfaced to the basic software. The adopted SOFC model was already validated by the authors in previous works, while the gasifier model was here developed and validated by means of experimental activities carried out by using a bench scale gasifier. Different compounds (Benzene, Toluene, Naphthalene, Phenols) were chosen to analyze the tar evolution in the gaseous stream during the gasification process. Hot gas cleaning (based on catalytic ceramic filter candles inserted in the freeboard of the gasifier – UNIQUE concept) was adopted to remove tar and particulates from the fuel hot gas stream. Different moisture contents in the range between 10 and 30% (i.e. in a deviation of 10% around the usual wood moisture content of 20%) were numerically simulated as well as the degree of purity of the oxygen utilized in the power plant (between 25% and 95%, the rest being N₂). The power requirement for pure oxygen production leads to a reduction of the electrical efficiency of the whole power plant. For this reason, a sensitivity analysis was conducted to find the optimal operation conditions in order to maximise the syngas (H₂, CO) content in the produced gas, while maintaining a high overall electrical efficiency.