亚洲城市主义——公共街道中住区生活的动态性之解读

针对亚洲文脉下的高密度城市环境,提出“亚洲城市主义”作为一种新的研究和设计模式,并提出“一席之地”的概念作为环境设计中的焦点。研究关注的是“街道社会生态”,特别是在某一时刻街道上循环的事物、活动和空间结构的一幕最小的互相依赖图景,称作“社会即景”,倡导为高密度城市环境作契合文化内涵的设计。     

Solid dispersion particles of tolbutamide prepared with fine silica particles by the spray-drying method

Solid dispersion particles of tolbutamide (TBM) were prepared by formulating nonporous (Aerosil 200 (hydrophilic), Aerosil R972 (hydrophobic)) or porous (Sylysia 350 (hydrophilic), Sylophobic 200 (hydrophobic)) silica as a carrier and applying the spray-drying (SD) or evaporation (Eva) method. In the solid dispersion particles prepared by the SD method, TBM existed in a meta-stable form (Form II) irrespective of the type of silica. On the other hand, when the Eva method was used, various crystalline forms of TBM were observed in the solid dispersion particles according to the type of silica. Polymorphs of Forms III and IV were prepared with Aerosil 200 and Aerosil R972, respectively, while crystalline Form II was obtained when either of the forms of porous silica, Sylysia 350 or Sylophobic 200, was formulated. The dissolution property of TBM in the solid dispersion particles prepared with hydrophilic silica was remarkably improved compared with those of the original TBM crystals (Form I) or spray-dried TBM without silica (Form II). In the case of hydrophobic silica, the release rate of TBM from the solid dispersion particles was much slower than that of original TBM. The meta-stable form of TBM in the solid dispersion particles was stable for at least 4 weeks when stored at 60 °C and 0% RH, while the spray-dried TBM without silica (Form II) was gradually converted to the stable form (Form I) under the same storage conditions. Under the humid storage conditions (60 °C, 75% RH), the spray-dried TBM without silica (Form II) immediately converted into the stable form (Form I) within 1 day, while TBM (Form II) in the solid dispersions in a matrix of silica was stable for at least 1 week.     

A self‐commutated back‐to‐back system and its performance under a single line‐to‐ground fault condition

This paper deals with a self‐commutated BTB (Back‐To‐Back) system for the purpose of power flow control and/or frequency change in transmission systems. Each BTB unit consists of two sets of 16 three‐phase voltage‐source converters, and their AC terminals are connected in series to each other via 16 three‐phase transformers. Hence, the BTB unit uses totally 192 switching devices capable of achieving gate commutation. This results in a great reduction of voltage and current harmonics without performing PWM control. Simulation results verify the validity of the proposed system configuration and control scheme not only under a normal operating condition but also under a single line‐to‐ground fault condition. © 2003 Wiley Periodicals, Inc. Electr Eng Jpn, 143(3): 68–78, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10124     

A three‐phase voltage‐source PWM inverter system characterized by sinusoidal output voltage with neither common‐mode voltage nor normal‐mode voltage

This paper deals with an inverter system integrating a small‐rated passive EMI filter with a three‐phase voltage‐source PWM inverter. The purpose of the EMI filter is to eliminate both common‐mode and normal‐mode voltages from the output voltage of the inverter. The motivation of this research is based on the well‐known fact that the higher the carrier or switching frequency, the smaller and the more effective the EMI filter. An experimental system consisting of a 5‐kVA inverter, a 3.7‐kW induction motor, and a specially designed passive EMI filter was constructed to verify the viability and effectiveness of the EMI filter. As a result, it is shown experimentally that both three‐phase line‐to‐line and line‐to‐neutral output voltages look purely sinusoidal as if the inverter system were an ideal variable‐voltage, variable‐frequency power supply when viewed from the motor terminals. This results in complete solution of serious issues related to common‐mode and normal‐mode voltages produced by the inverter. © 2003 Wiley Periodicals, Inc. Electr Eng Jpn, 145(4): 88–96, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10206     

Photolysis of poly(3-buten-2-one), poly(4,4-dimethyl-1-penten-3-one), and poly(3-methyl-3-buten-2-one) in the presence of oxygen

Photolysis of poly(3-buten-2-one) (PMVK), poly(4,4-dimethyl-1-penten-3-one) (PBVK), and poly(3-methyl-3-buten-2-one) (PMIK) were carried out in dioxane under oxygen or nitrogen bubbling. The main chain degradations of PBVK and PMIK were quenched and polymeric peroxides were produced. The heat treatment of the polymer irradiated in the presence of oxygen promoted the degradation. The photodegradation of PMVK was enhanced in the presence of oxygen.     

Application of tritium radioluminography to the detection of hydrogen diffusion in Ti-Cr alloy

Tritium radioluminography has been applied to determine the hydrogen (H) diffusion coefficients in Ti₅₀Cr₅₀ and Ti₄₀Cr₆₀ alloys, both with two-phase structures of a body-centered cubic (bcc) phase and a Laves phase. Using radioluminography, H distributions in those phases have been observed, and H penetration profiles have been measured. The tritium diffusion coefficients in the Ti₅₀Cr₅₀ and Ti₄₀Cr₆₀ alloys have been successfully determined by analyzing the tritium penetration profiles to be 3.3±0.3 × 10^?12 and 1.4±0.1×10^?12 m²/s, respectively. These values suggest that the H diffusion in the Laves phase is slower than that in the bcc phase. It is also suggested that H diffuses by short-circuiting diffusion through the interface between the bcc phase and the Laves phase.     

Structures and stability of water nanoclusters in hydrophobic nanospaces

The temperature dependencies of in situ small-angle X-ray scattering (SAXS) of water adsorbed and of adsorption isotherm of water in hydrophobic carbon nanopores were measured over the temperature range of 293 to 328 K. The structures of water nanoclusters adsorbed in the nanopores were determined with the density fluctuation analysis of in situ SAXS data. The difference of the density fluctuations between adsorption and desorption was ascribed to the water structural difference. The structural transitions of the water nanoclusters were observed around 318 K for adsorption and 308 K for desorption.