Silica Colloidal Membranes with Enantioselective Permeability

Robust mesoporous membranes composed of silica spheres were surface-modified with chiral selector moieties, including small molecules, macrocycles, and polymers. Diffusion rates of enantiomers of a chiral dye through the resulting asymmetrically modified colloidal membranes were measured and the corresponding permselectivities were calculated. The membranes showed enantioselectivities in the range of 1.2–1.8, which were not significantly affected by the structure of the surface-immobilized chiral electors. This selectivity is on par with most reported polymer-based solid membranes and bulk liquid membranes. The enantioselectivity results from the surface-facilitated mechanism of transport of enantiomers through the mesopores.     

Time-optimal velocity planning along predefined path for static formations of mobile robots

International Journal of Control, Automation and Systems - This paper is concerned with the problem of finding a time-optimal velocity profile along the predefined path for static formations of...     

Effect of amine-terminated butadiene-acrylonitrile/clay combinations on the structure and properties of epoxy nanocomposites

The effect of the clay content and the method of its combination with amine-terminated butadiene-acrylonitrile (ATBN) on the structure and behavior of epoxy was studied. In the case of the simultaneous addition of both components, the increasing clay content had a very small effect on the size of the reaction-induced phase separation-formed particles at 5% rubber content due to predominant elimination of two major clay effects, i.e., the nucleation due to phase separation and the kinetics. As a result, both the time window between the onset of phase separation and vitrification and the viscosity at the cloud point did not change significantly. The minor change in the particle size/clay content dependences with different curing temperatures indicates that the balance between the two clay effects shifted. The corresponding study of the mechanical behavior indicated that the best balanced mechanical properties were obtained at certain clay/ATBN ratios, and thus, there was synergy between the components. Similar mechanical parameters were obtained for the application of both components in the form of ATBN/montmorillonite intercalate. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

SmartK: Smart cards in operating systems at kernel level

A smart card is a tamper-resistant miniature computer that performs some basic computations on input a secret information. So far, smart cards have been widely used for securing many digital transactions (e.g., pay television, ATM machines).We focus on the implementation of operating system security services leveraging on smart cards. This very challenging feature allows one to personalize some functionalities of the operating system by simply changing a smart card. Current solutions for integrating smart card features in operating system services require at least a partial execution of some of the operating system functionalities at “user level”. Unfortunately, system functionalities built on top of components lying at both kernel and user levels may negatively affect the overall system security, due to the introduction of multiple points of failure.In this work, we present the design and implementation of SmartK: a framework that integrates features of smart cards uniquely in the Linux kernel. In order to validate our approach, we propose a host of enhancements to the Linux operating system built on top of SmartK: 1) in-kernel clients' authentication with Kerberos; 2) execution of trusted code; 3) key management in secure network filesystems.In particular, we present an experimental Linux OS distribution (SalSA), which addresses the security issues related to downloading packages and to updating an operating system through the Internet.     

Broadening the Scope of Hypermedia Principles

Hypermedia systems have been implemented for such a wide range of applications that one must wonder whether their principles should not be included among the building blocks of computer environments themselves. In this paper, we argue that this would indeed be desirable and present a model on which such extension could be based.

After a brief review of hypermedia principles and the terminology used in this paper, we give examples of several computer applications in which hypermedia already are or could advantageously be used. We then suggest that most computer applications would greatly benefit if hypermedia were extended from isolated applications to a system-wide facility and that this could substantially simplify implementation of new hypermedia applications. This claim is then generalized and it is shown that extending hypermedia concepts to the organization of the computer environment itself --- the file system --- and to the user interface would make computer environments more flexible and easier to use.

We then list the main characteristics of such a ‘hyperenvironment’ and conclude the paper with an outline of its implementation model and an example.     

STW resonator with organo-functionalized metallic nanoparticle film for vapor sensing

A 1 GHz surface transverse wave resonator on 36° Y-cut quartz plate coated with organothiol-functionalized gold nanoparticle film has been studied as a chemical gas sensor. Considerable sensitivity of the resonant frequency to vapors of ethanol, methanol, chloroform, and acetic acid has been found. Owing to the high short-term stability of the oscillator built, the detection limit is in the low ppm range. The results qualitatively confirm previous results on the same film type obtained by conductivity measurements. In the present case, the conductivity effect resulting from variable separation of nanoparticles is accompanied with surface-attached mass of the absorbed gas. The film matrix exhibits considerable capacity to absorb large amounts of molecules at high gas concentrations.     

Phosphotungstic heteropoly acid as efficient heterogeneous catalyst for solvent-free isomerization of α-pinene and longifolene

Silica-supported H₃PW₁₂O₄₀ (PW), the strongest heteropoly acid in the Keggin series, is an efficient, environmentally friendly heterogeneous catalyst for the liquid-phase isomerization of α-pinene and longifolene into their more valuable isomers – camphene and isolongifolene, respectively, which are intermediates in the synthesis of expensive fragrances. The reactions occur under solvent-free conditions in the temperature range of 80–100 °C, with low catalyst loadings (0.15–5 wt%) and high turnover numbers (up to 6000 per proton). The catalyst can be easily recovered and reused. No PW leaching is observed in the reaction system.     

Detecting and tracking mesoscale precipitating objects using machine learning algorithms

Accurate identification of precipitating clouds is a challenging task. In the present work, Support Vector Machines (SVMs), Decision Trees (DT), and Random Forests (RD) algorithms were applied to extract and track mesoscale convective precipitating clouds from a series of 22 Geostationary Operational Environmental Satellite-13 meteorological image sub-scenes over the continental territory of Colombia. This study’s aims are twofold: (i) to establish whether the use of five meteorological spectral channels, rather than a single infrared (IR) channel, improves rainfall objects detection and (ii) to evaluate the potential of machine learning algorithms to locate precipitation clouds. Results show that while the SVM algorithm provides more accurate classification of rainfall cloud objects than the traditional IR brightness temperature threshold method, such improvement is not statistically significant. Accuracy assessment was performed using STEP (shape (S), theme (T), edge (E), and position (P)) object-based similarity matrix method, taking as reference precipitation satellite images from the Tropical Rainfall Measuring Mission. Best thematic and geometric accuracies were obtained applying the SVM algorithm.     

Semi-discretization for stability analysis of in-feed cylindrical grinding with continuous workpiece speed variation

This paper presents the advances of semi-discretization approach for the dynamic stability analysis of in-feed cylindrical grinding process. The corresponding mathematical model is an autonomous delay-differential equation and the application of continuous workpiece speed variation (CWSV) in the process leads to a time-varying delay. Discretization techniques are a good way of dealing with differential equations for which the solution cannot be given in closed forms. Therefore, the semi-discretization method is proposed to analyze the equation. Stability maps are devised to study the influence of the CWSV application. Contrary to milling and turning processes, stability in grinding is very much influenced by the residual flexibility due to the deformation of the grinding wheel-workpiece system, so this term has been included in the approach. The validation has been carried out experimentally and good correlation between test and simulation results has been achieved.