Visible laser lights in photoinduced polymerization. VI. Thioxanthones and ketocoumarins as photoinitiators

The efficiency of thioxanthones and ketocoumarins as photoinitiators has been checked in visible laser light-induced polymerization reactions and discussed in terms of excited-state reactivity (as revealed by time-resolved laser spectroscopy). These compounds undergo fast electron transfer reaction in the presence of amines and onium salts. Transient absorption spectra and rate constants of the processes involved have been determined. The combination photoinitiator-amine-onium salt appears as very promising for the design of efficient photosensitive systems.     

A Broadband CPW-to-Microstrip Modes Coupling Technique

A broadband vertical transition from coplanar waveguide (CPW)-to-microstrip modes is presented. The transition has a double resonance and can be tuned for very wide-band operation. The CPW-to-microstrip modes coupling technique is useful for the vertical integration of multi-layer millimeter-wave circuits, packaging and antenna feeding networks. A vertical transition has been fabricated on 100 μm silicon substrate for operation at W-band frequencies and shows less than 0.3 dB of insertion loss and better than 12 dB of return loss from 75 to 110 GHz. A 94 GHz CPW-fed microstrip antenna showing a 10-dB bandwidth of about 30 % has been built using the same transition technique.     

Stress-strain relationships in uniaxial extension of high cis-1,4-polyisoprene networks with different molecular weight precursors

Equilibrium stress-strain relationships in uniaxial extension for high cis-1,4-polyisoprene (Shell IR 307) networks were obtained by extrapolation of relaxation measurements to infinite time through a BKZ constitutive equation. Three series of networks were investigated, each series being characterized by its polymer precursor molecular weight. Influence of crosslinking density was studied through varying amounts of dicumyl peroxide as crosslinking agent. These results were used to test Flory and Erman's recent molecular elasticity theory of imperfect networks with constraints on junctions. It was shown that this later theory treating entanglements as restrictions on junction fluctuations could be reasonably used to characterize network topology. A universal value of 0.50 for the interpenetration parameter I is confirmed and an interpretation of parameter ζ in terms of network inhomogeneity is tentatively given.     

Formation of the Perovskite Phase in the PbMg1/3Nb2/3O3─PbTiO3 System

The reaction sequences during calcination of oxide mixtures were studied for the PbMg_1/3Nb_2/3O₃─PbTiO₃ (PMN-PT) system. The effect of reactivity and composition of the starting mixtures was investigated. In the present study, a B-site-deficient, cubic pyrochlore phase in the PbO-Nb₂O₅ system was formed at 500°C. The perovskite phase of PMN was formed at 7007deg;C through the diffusion of MgO into the pyrochlore phase. The lattice parameter of the pyrochlore phase decreased as this transformation to perovskite progressed.     

Monoepoxy polymerization initiated by BF3-amine complexes in bulk. III. Influence of γ-butyrolactone on polymer formation

The influence of γ-butyrolactone (γ-BL), used as solvent of BF₃-amine complexes, on the polymerization of monoepoxides was studied. Different intermediate reaction products of PGE initiated by BF₃-4-methoxyaniline (BF₃-4MA) previously solubilized in γ-BL (55% by weight), were separated and analyzed by ¹H-NMR. It is shown that there is the opening of both epoxy and γ-BL. The latter does not homopolymerize, but copolymerizes well with epoxy groups. The use of a large quantity of γ-BL leads to a decreasing molar mass of the formed polymer. The kinetic study allowed to propose the mechanism of the cationic polymerization of epoxy initiated by BF₃-amine complex in the presence of γ-BL. © 1994 John Wiley & Sons, Inc.     

Hardness and fracture toughness of thermoelectric La<Subscript>3−<Emphasis Type="Italic">x</Emphasis></Subscript>Te<Subscript>4</Subscript>

Lanthanum telluride (La_3?x Te₄) is a state-of-the-art n-type high temperature thermoelectric material that behaves as a weak and brittle ceramic. Vickers microindentation hardness testing was explored as a rapid analysis technique to characterize the mechanical properties of this material. An indentation size effect was observed with hardness values ranging from 439 ± 31 kgf/mm² (0.01 kgf/10 s contact time) to 335 ± 6 kgf/mm² (0.5 kgf/10 s contact time). The Vickers indentation fracture toughness, K _VIF, based on measurements of crack lengths emanating from the corners of the Vickers indents was 0.70 ± 0.06 MPa m^1/2.     

Comparison of contact resistance between accumulation-mode and inversion-mode multigate FETs

The performances of accumulation-mode and inversion-mode multigate FETs are compared. The influence of gate underlap on the electrical properties is analyzed. Both simulation results and experimental data show that in a device with gate underlap, accumulation-mode devices have a higher current drive, lower source and drain resistance and less process variability than inversion-mode FETs.