一种安全的网上数字签名系统的设计与实现

基于Internet的信息查询系统应用广泛,为了保证查询数据的真实性和权威性,需要信息查询系统对客户查询的数据进行数字签名,以便客户验证数据的来源和完整性。该文设计并实现了一个适用于网上信息查询系统的安全的数字签名系统,该系统能对客户查询的数据进行签名,实现客户对查询数据的来源和完整性进行验证,但在查询服务器上不需要保存签名的私钥,杜绝了私钥被入侵者窃取的风险,从而提高了信息查询系统的安全性。     

Poly(acrylic acid)-modified silica nanoparticles as a nonmetal catalyst for NaBH4 methanolysis

In the present work, a SiO₂@PAA catalyst for NaBH₄ methanolysis composed of silica nanoparticles modified with poly(acrylic acid) has been developed. The morphology and composition of the prepared SiO₂@PAA catalyst were analyzed with transmission electron microscopy, Fourier transform-infrared spectroscopy, x-ray photoelectron spectroscopy and thermogravimetric analysis. This catalyst showed excellent catalytic performance for methanolysis of NaBH₄. The NaBH₄ methanolysis reaction catalyzed by SiO₂@PAA showed an average hydrogen generation rate 5.5 times as high as the reaction catalyzed by unmodified SiO₂ and 10.6 times as high as the uncatalyzed reaction, respectively. The activation energy for methanolysis of NaBH₄ catalyzed by this SiO₂@PAA catalyst was 24.03 kJ/mol. Moreover, although the catalytic activity of SiO₂@PAA catalyst partially lost after being used, it could be restored after being regenerated by washing with diluted hydrochloric acid solution.     

歧口凹陷歧北次凹沙河街组三段页岩油地质特征与勘探突破

歧口凹陷歧北次凹沙河街组三段（沙三段）湖泛期细粒沉积发育、烃源岩品质好、页岩油资源丰富，但其研究尚处于起步阶段，在沧东凹陷孔店组二段湖相页岩油工业化开发的带动下，落实其勘探前景势成必然。为探究歧北次凹沙三段页岩油的地质特征及勘探潜力，依据F39X1井、QY10-1-1井等多口井的岩心、分析化验、测井资料和录井资料，对沙三段页岩层系的地质特征、页岩油类型与富集模式、甜点的空间分布规律等开展了综合研究。歧北次凹沙三段的矿物组成和岩石类型多样，主要包括灰质白云质页岩、长英质页岩、混合质页岩及微晶白云岩、亮晶生屑白云岩、粉砂岩等；烃源岩的总有机碳（TOC）含量主要分布在1%~3%，以Ⅱ型干酪根为主且指示热演化成熟度的镜质体反射率（R_o）普遍高于0.7%；储集空间主要包括粒间孔、晶间孔、生物体腔孔、有机孔及层理缝、构造（微）缝等；页岩油的超越效应明显（油饱和度指数平均为116.3 mg/g）、荧光显示良好。在歧北次凹沙三段中识别出单一型和夹层型2类页岩油，构建了高TOC滞留型页岩油和低TOC运移型页岩油2种富集模式，并建立了基于油饱和度指数、TOC和脆性指数等多参数的甜点定量评价方法及标准。针对甜点区部署了QY10-1-1水平井，其初期的折算产油量达103.5 t/d，预计可形成亿吨级增储新领域。勘探发现证实歧口凹陷的沙三段细粒岩段具备良好的页岩油勘探潜力。     

Temperature-sensitive polyurethane (TSPU) film incorporated with carvacrol and cinnamyl aldehyde: antimicrobial activity,sustained release kinetics and potential use as food packaging for Cantonese-style moon cake

Temperature-sensitive polyurethane (TSPU) films incorporated with carvacrol and cinnamyl aldehyde were prepared for the potential use of food packaging. The antimicrobial properties and sustained release kinetics of carvacrol and cinnamyl aldehyde in TSPU film were investigated. Results indicated that cinnamyl aldehyde and carvacrol had favourable antimicrobial properties at relatively low addition ratio. The diffusion and release of carvacrol were linearly related to temperature and its addition ratio. The release rates of carvacrol from TSPU film increased from 0.6% to 2.2% with the increase of addition ratio and temperature. The first-order kinetic equation could be used to describe its diffusion and sustained release process. TSPU films could significantly prolong the shelf life of Cantonese-style moon cakes by effectively inhibiting microbial growth and decreasing lipid oxidation comparing with commonly used polyethylene food packaging. Results obtained in the present work can provide technical guide of sustained release food packaging films with antimicrobial properties.     

N-enriched porous carbon doped with co,ni, and Mo as efficient electrocatalyst for hydrogen evolution reaction

Splitting water for hydrogen production is still a promising technique to meet the energy requirements of society and overcome many environmental problems. However, the development of carbon-based transition electrocatalysts with superior activity for hydrogen evolution reaction (HER) is still challenging. In this study, a CoNiMo/NPC electrocatalyst was successfully fabricated using ZIF-67 as a precursor via facile absorption, pyrolysis and annealing processes. The fabricated CoNiMo/NPC was used as an electrocatalyst for hydrogen production. The results revealed that the doping of Ni and Mo increase the number of active sites and enhance the conductivity of electrocatalysts. CoNiMo/NPC exhibits excellent HER activity in alkaline solutions and only requires an overpotential of 182 mV to reach a current density of 10 mA/cm². Furthermore, long-term measurements demonstrated that CoNiMo/NPC has superior durability in alkaline solutions. The excellent HER performance of CoNiMo/NPC can be attributed to the doping of Co, Ni, and Mo on porous carbon. In addition, the high specific surface area and high graphitisation degree of the electrocatalyst are beneficial for rapid charge transport and collection.     

Optimal control data scheduling with limited controller-plant communication

This paper considers optimal control data scheduling for finite-horizon linear quadratic regulation (LQR) control of scalar systems with limited controller-plant communication. Both the single-system and multiple-system scenarios are studied. For the first scenario, we derive the necessary and sufficient condition for a comparison function to be positive. Using this condition, the optimality of an explicit schedule is extended from unstable systems in the existing work to general systems. For the second scenario, we are able to construct explicit optimal scheduling policies for three particular classes of problems. Numerical examples are provided to illustrate the proposed results.     

Al-Mg-Si合金线导电率演变规律与机制

通过不同温度退火处理模拟架空输电用Al-Mg-Si合金线的热服役环境,对不同退火温度下Al-Mg-Si合金线的导电率演变规律与机制进行了研究。结果表明,Al-Mg-Si合金线的导电率随着退火温度的升高呈现3阶段特征,第一阶段温度为90~150 ℃,Al-Mg-Si合金线导电率略微增大,缺陷的回复是本阶段Al-Mg-Si合金线导电率增大的原因;第二阶段温度为150~200 ℃,析出相的长大和固溶原子的析出导致Al-Mg-Si合金线导电率大幅增大;第三阶段温度为200~300 ℃,晶粒长大是Al-Mg-Si合金线导电率缓慢增大的主要原因。     

恒定磁场阻垢除垢的分子动力学模拟

磁场的阻垢除垢机理研究不足阻碍了该法的实际应用。为了进一步认识恒定磁场的阻垢除垢机理,研究了不同磁感应强度、不同温度下的阻垢除垢效果。建立模型A和模型B,其中模型A是含少量钙离子和碳酸根离-子的水溶液,模型B是包含方解石(110)晶面与水接触的混合体系。用分子动力学软件Material Explorer 5.0研究在改变磁感应强度和体系温度下,模型A、B分别表现出的阻垢除垢效果。结果表明:对于模型A,只有温度323 K时,磁场的作用下才能表现出阻垢效果,而且磁感应强度与模型温度的不同组合会导致3种趋势:阻垢、促垢、无变化。对于模型B,在磁感应强度与温度改变多次组合后,并未发现有导致水垢被溶解的情形。由此可得恒定磁场的除垢效果缺乏机理的支撑。     

带状光纤多波长阵列光栅刻写工艺研究

为了实现一次性在八芯带纤上不同波长阵列光纤光栅刻写,采用专门设计的带纤夹具夹持光纤,使用电控位移平台对带状光纤整体施加拉力,利用相位掩膜工艺对光纤逐根曝光,采用扫描写入的方法进行汉明切趾,仅用单一相位模板就实现了八芯带纤上不同波长阵列布喇格光纤光栅刻写。刻栅过程由电脑编程控制,中心波长、波长间隔以及切趾方式可以灵活调整。结果表明,获得的光栅其3dB带宽为0.2nm、波长间隔为0.5nm、波长偏差小于50pm、反射率达到80%~85%。此种带状光纤多波长阵列光栅刻写工艺是完全可行的。     

基于单一相位模板的带状光纤上多波长阵列光纤光栅刻写工艺研究

设计了一种带状光纤上阵列光纤光栅刻写系统,仅利用一块相位掩模板,即实现8芯带纤上阵列光纤布拉格光栅的刻写.使用自行设计的带纤夹具夹持带纤,电控位移平台对带纤整体施加拉伸力,采用相位掩模工艺对光纤逐根曝光,并同时以扫描写入的方法进行汉明切趾.刻栅过程由电脑编程控制,中心波长、波长间隔以及切趾方式可以灵活调整.测试结果表明,刻写完成的阵列光纤布拉格光栅3 dB带宽为0.2 nm、波长间隔为0.5 nm、波长偏差小于±50 pm、反射率达到80％～85％.