Recent advances in controlled modification of the size and morphology of metal-organic frameworks

Advances in metal-organic frameworks (MOFs) resulted in significant contributions to diverse applications such as carbon capture, gas storage, heat transformation and separation along with emerging applications toward catalysis, medical imaging, drug delivery, and sensing. The unique in situ and ex situ structural features of MOFs can be tailored by conceptual selection of the organic (e.g., ligand) and inorganic (e.g., metal) components. Here, we provide a comprehensive review on the synthesis and characterization of MOFs, particularly with respect to controlling their size and morphology. A better understanding of the specific size and morphological parameters of MOFs will help initiate a new era for their real-world applications. Most importantly, this assessment will help develop novel synthesis methods for MOFs and their hybrid/porous materials counterparts with considerably improved properties in targeted applications.

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BallotMaps: detecting name bias in alphabetically ordered ballot papers

The relationship between candidates' position on a ballot paper and vote rank is explored in the case of 5000 candidates for the UK 2010 local government elections in the Greater London area. This design study uses hierarchical spatially arranged graphics to represent two locations that affect candidates at very different scales: the geographical areas for which they seek election and the spatial location of their names on the ballot paper. This approach allows the effect of position bias to be assessed; that is, the degree to which the position of a candidate's name on the ballot paper influences the number of votes received by the candidate, and whether this varies geographically. Results show that position bias was significant enough to influence rank order of candidates, and in the case of many marginal electoral wards, to influence who was elected to government. Position bias was observed most strongly for Liberal Democrat candidates but present for all major political parties. Visual analysis of classification of candidate names by ethnicity suggests that this too had an effect on votes received by candidates, in some cases overcoming alphabetic name bias. The results found contradict some earlier research suggesting that alphabetic name bias was not sufficiently significant to affect electoral outcome and add new evidence for the geographic and ethnicity influences on voting behaviour. The visual approach proposed here can be applied to a wider range of electoral data and the patterns identified and hypotheses derived from them could have significant implications for the design of ballot papers and the conduct of fair elections.     

Shortcut fusion rules for the derivation of circular and higher-order programs

Functional programs often combine separate parts using intermediate data structures for communicating results. Programs so defined are modular, easier to understand and maintain, but suffer from inefficiencies due to the generation of those gluing data structures. To eliminate such redundant data structures, some program transformation techniques have been proposed. One such technique is shortcut fusion, and has been studied in the context of both pure and monadic functional programs. In this paper, we study several shortcut fusion extensions, so that, alternatively, circular or higher-order programs are derived. These extensions are also provided for effect-free programs and monadic ones. Our work results in a set of generic calculation rules, that are widely applicable, and whose correctness is formally established.     

Spoken emotion recognition through optimum-path forest classification using glottal features

A new method for the recognition of spoken emotions is presented based on features of the glottal airflow signal. Its effectiveness is tested on the new optimum path classifier (OPF) as well as on six other previously established classification methods that included the Gaussian mixture model (GMM), support vector machine (SVM), artificial neural networks – multi layer perceptron (ANN-MLP), k-nearest neighbor rule (k-NN), Bayesian classifier (BC) and the C4.5 decision tree. The speech database used in this work was collected in an anechoic environment with ten speakers (5 M and 5 F) each speaking ten sentences in four different emotions: Happy, Angry, Sad, and Neutral. The glottal waveform was extracted from fluent speech via inverse filtering. The investigated features included the glottal symmetry and MFCC vectors of various lengths both for the glottal and the corresponding speech signal. Experimental results indicate that best performance is obtained for the glottal-only features with SVM and OPF generally providing the highest recognition rates, while for GMM or the combination of glottal and speech features performance was relatively inferior. For this text dependent, multi speaker task the top performing classifiers achieved perfect recognition rates for the case of 6th order glottal MFCCs.     

Shrinking‐horizon dynamic programming

We describe a heuristic control policy for a general finite‐horizon stochastic control problem, which can be used when the current process disturbance is not conditionally independent of the previous disturbances, given the current state. At each time step, we approximate the distribution of future disturbances (conditioned on what has been observed) by a product distribution with the same marginals. We then carry out dynamic programming (DP), using this modified future disturbance distribution, to find an optimal policy, and in particular, the optimal current action. We then execute only the optimal current action. At the next step, we update the conditional distribution, and repeat the process, this time with a horizon reduced by one step. (This explains the name ‘shrinking‐horizon dynamic programming’). We explain how the method can be thought of as an extension of model predictive control, and illustrate our method on two variations on a revenue management problem. Copyright © 2010 John Wiley & Sons, Ltd.     

Vehicle license plate tilt correction based on the straight line fitting method and minimizing variance of coordinates of projection points

Tilt correction is a very crucial and inevitable task in the automatic recognition of the vehicle license plate (VLP). In this paper, according to the least square fitting with perpendicular offsets (LSFPO), the VLP region is fitted to a straight line. After the line slope is obtained, rotation angle of the VLP is estimated. Then the whole image is rotated for tilt correction in horizontal direction by this angle. Tilt correction in vertical direction by minimizing the variance of coordinates of the projection points is proposed. Character segmentation is performed after horizontal correction and character points are projected along the vertical direction after shear transform. Despite the success of VLP detection approaches in the past decades, a few of them can effectively locate license plate (LP), even when vehicle bodies and LPs have similar color. A common drawback of color-based VLP detection is the failure to detect the boundaries or border of LPs. In this paper, we propose a modified recursive labeling algorithm for solving this problem and detecting candidate regions. According to different colored LP, these candidate regions may include LP regions. Geometrical properties of the LP such as area, bounding box and aspect-ratio are then used for classification. Various LP images were used with a variety of conditions to test the proposed method and results are presented to prove its effectiveness.     

New Compliance-Mechanism Design for Small Companion Robots

The compliance mechanisms used on robotic arms can be classified into two major categories: mechanical and electronic. The ideal characteristics of a compliance mechanism include small volume, simple mechanical structure, low cost, large complaint range, and high precision and accuracy under displacement control. Most mechanical compliance mechanisms are able to meet the first three conditions but have a small compliant range and low precision and accuracy under displacement control. The electronic compliance mechanism is hardly limited in the degree of deformation and comes with a higher precision and accuracy under the displacement control, but its sensors are expensive and the system is difficult to control. To combine the advantages of both types, this research aims to develop a new design of compliance mechanism in which a small-scale torque-limiting mechanism with a self-locking feature is installed between the actuator and the arm structure to minimize the volume while providing an ample torque limit. When the robotic arm is overloaded under an external force, a slide will occur inside the compliance mechanism so that the robotic arm will move along the direction of the external force to avoid damage. The robotic arm will automatically return to its original position after the external force is removed. The new compliance mechanism not only exceeds most of the current mechanical designs in the range of compliance but also does not affect the precision and accuracy of the displacement control. Furthermore, the new compliance mechanism does not require any sensors, which will benefit small robotic arms.     

Collaborative user modeling with user-generated tags for social recommender systems

With the popularity of social media services, the sheer amount of content is increasing exponentially on the Social Web that leads to attract considerable attention to recommender systems. Recommender systems provide users with recommendations of items suited to their needs. To provide proper recommendations to users, recommender systems require an accurate user model that can reflect a user’s characteristics, preferences and needs. In this study, by leveraging user-generated tags as preference indicators, we propose a new collaborative approach to user modeling that can be exploited to recommender systems. Our approach first discovers relevant and irrelevant topics for users, and then enriches an individual user model with collaboration from other similar users. In order to evaluate the performance of our model, we compare experimental results with a user model based on collaborative filtering approaches and a vector space model. The experimental results have shown the proposed model provides a better representation in user interests and achieves better recommendation results in terms of accuracy and ranking.     

An haptic-based immersive environment for shape analysis and modelling

Currently, the design of aesthetic products is a process that requires a set of activities where digital models and physical mockups play a key role. Typically, these are modified (and built) several times before reaching the desired design, increasing the development time and, consequently, the final product cost. In this paper, we present an innovative design environment for computer-aided design (CAD) surface analysis. Our system relies on a direct visuo-haptic display system, which enables users to visualize models using a stereoscopic view, and allows the evaluation of sectional curves using touch. Profile curves are rendered using an haptic device that deforms a plastic strip, thanks to a set of actuators, to reproduce the curvature of the shape co-located with the virtual model. By touching the strip, users are able to evaluate shape characteristics, such as curvature or discontinuities (rendered using sound), and to assess the surface quality. We believe that future computer-aided systems (CAS)/CAD systems based on our approach will contribute in improving the design process at industrial level. Moreover, these will allow companies to reduce the product development time by reducing the number of physical mockups necessary for the product design evaluation and by increasing the quality of the final product, allowing a wider exploration and comparative evaluation of alternatives in the given time.     

Local and Global Interactions in an Evolutionary Resource Game

Conditions for the emergence of cooperation in a spatial common-pool resource game are studied. This combines in a unique way local and global interactions. A fixed number of harvesters are located on a spatial grid. Harvesters choose among three strategies: defection, cooperation, and enforcement. Individual payoffs are affected by both global factors, namely, aggregate harvest and resource stock level, and local factors, such as the imposition of sanctions on neighbors by enforcers. The evolution of strategies in the population is driven by social learning through imitation, based on local interaction or locally available information. Numerous types of equilibria exist in these settings. An important new finding is that clusters of cooperators and enforcers can survive among large groups of defectors. We discuss how the results contrast with the non-spatial, but otherwise similar, game of Sethi and Somanathan (American Economic Review 86(4):766–789, 1996).