Production of aromatics by catalytic fast pyrolysis of cellulose in a bubbling fluidized bed reactor

Catalytic fast pyrolysis of cellulose was studied at 500°C using a ZSM‐5 catalyst in a bubbling fluidized bed reactor constructed from a 4.92‐cm ID pipe. Inert gas was fed from below through the distributor plate and from above through a vertical feed tube along with cellulose. Flowing 34% of the total fluidization gas through the feed tube led to the optimal mixing of the pyrolysis vapors into the catalyst bed, which experimentally corresponded to 29.5% carbon aromatic yield. Aromatic yield reached a maximum of 31.6% carbon with increasing gas residence time by changing the catalyst bed height. Increasing the hole‐spacing in the distributor plate was shown to have negligible effect on average bubble diameter and hence did not change the product distribution. Aromatic yields of up to 39.5% carbon were obtained when all studied parameters were optimized. © 2014 American Institute of Chemical Engineers AIChE J, 60: 1320–1335, 2014     

Demonstration of the monolithic interconnection on CIS solar cells by picosecond laser structuring on 30 by 30 cm2 modules

In this paper, we present the selective structuring of all three patterns (P1, P2 and P3) of a monolithic interconnection of CIS (Cu(In,Ga)(S,Se)₂) thin film solar cells by picosecond laser pulses at a wavelength of 1064 nm. We show results for single pulse ablation threshold values and line scribing of molybdenum films on glass (P1), CIS on molybdenum (P2) and zinc oxide on CIS (P3). The purposes of these processes are the p‐type isolation (P1), cell interconnect (P2) and n‐type isolation (P3), which are required for complete cell architecture. The half micron thick molybdenum back electrode can be structured with a process speed of more than 15 m/s at about 15 W average power without detectable residues and damage by direct induced laser ablation from the back side (P1). The CIS layer can be structured selectively down to the molybdenum at process speeds up to 1 m/s at about 15 W average power, due to the precision of direct laser ablation in the ultrashort pulse regime (P2). The ZnO front electrode layer is separated by clean trenches with straight side walls at process speeds of up to 15 m/s at about 10 W average power, as a result of indirect induced laser ablation (P3). A validation of functionality of all processes is demonstrated on CIS solar cell modules (30 × 30 cm²). By replacing one state‐of‐the‐art process by a picosecond laser process at a time, solar efficiencies could be increased for P1 and P2 and stayed on a similar level for P3. After an optimization of the patterning processes in the R&D pilot line of AVANCIS, we achieved a new record efficiency for an all‐laser‐patterned CIS solar module: 14.7% as best value for the aperture area efficiency of a 30 × 30 cm² sized CIS module was reached. Copyright © 2014 John Wiley & Sons, Ltd.     

Automatic reconstruction of as-built building information models from laser-scanned point clouds: A review of related techniques

Building information models (BIMs) are maturing as a new paradigm for storing and exchanging knowledge about a facility. BIMs constructed from a CAD model do not generally capture details of a facility as it was actually built. Laser scanners can be used to capture dense 3D measurements of a facility's as-built condition and the resulting point cloud can be manually processed to create an as-built BIM — a time-consuming, subjective, and error-prone process that could benefit significantly from automation. This article surveys techniques developed in civil engineering and computer science that can be utilized to automate the process of creating as-built BIMs. We sub-divide the overall process into three core operations: geometric modeling, object recognition, and object relationship modeling. We survey the state-of-the-art methods for each operation and discuss their potential application to automated as-built BIM creation. We also outline the main methods used by these algorithms for representing knowledge about shape, identity, and relationships. In addition, we formalize the possible variations of the overall as-built BIM creation problem and outline performance evaluation measures for comparing as-built BIM creation algorithms and tracking progress of the field. Finally, we identify and discuss technology gaps that need to be addressed in future research.     

Thermal models for bobbin tool friction stir welding

This study presents three thermal 3D models for bobbin tool Friction stir welding (FSW) implemented in Comsol and Matlab. The models use thermal pseudo-mechanical (TPM) heat sources and include tool rotation, an analytic shear layer model and ambient heat sinks like the machine and surrounding air. A new transient moving geometry approach has been implemented. It includes the full tool motion along the weld line, while the other two models use fixed geometry with and without moving heat source.The computational effort is small for all three models. The steady state model can be solved in approximately 5 min on a state of the art workstation. Experiments on the FlexiStir experimental welding unit have been carried out to validate the models’ outputs. The predictions of all models are in excellent agreement with each other and the experiment.     

Relating Complex Fluid Composition and Thermophysical Properties with the Advanced Distillation Curve Approach

Complex fluids have long posed a significant challenge in our ability to characterize and model fluid properties. Here, we consider complex fluids to be mixtures with many components that can differ significantly in polarity and polarizability. The penultimate complex fluid is crude oil, although many other fluids such as finished fuels are also highly complex. We have recently introduced a measurement strategy that can simplify these efforts and provides the added potential of linking chemical composition (i.e. analytical) information with physical property information. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic and transport properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The collected sample fractions can be analyzed by any method that is appropriate. Analytical methods we have applied include gas chromatography (with flame ionization, mass spectrometric and sulfur chemiluminescence detection), thin‐layer chromatography, FTIR, Karl Fischer coulombic titrimetry, refractometry, corrosivity analysis, neutron activation analysis and cold neutron prompt gamma activation analysis. We have applied this method on product streams such as finished fuels (gasoline, diesel fuels, aviation fuels, rocket propellants), crude oils (including a crude oil made from swine manure) and waste oil streams (used automotive and transformer oils). In this review, we describe the essential features of the ADC metrology with illustrative examples.     

A Generalization of Short-Cut Fusion and its Correctness Proof

Short-cut fusion is a program transformation technique that uses a single, local transformation—called the foldr-build rule—to remove certain intermediate lists from modularly constructed functional programs. Arguments that short-cut fusion is correct typically appeal either to intuition or to free theorems—even though the latter have not been known to hold for the languages supporting higher-order polymorphic functions and fixed point recursion in which short-cut fusion is usually applied. In this paper we use Pitts' recent demonstration that contextual equivalence in such languages is relationally parametric to prove that programs in them which have undergone short-cut fusion are contextually equivalent to their unfused counterparts. For each algebraic data type we then define a generalization of build which constructs substitution instances of its associated data structures, and use Pitts' techniques to prove the correctness of a contextual equivalence-preserving fusion rule which generalizes short-cut fusion. These rules optimize compositions of functions that uniformly consume algebraic data structures with functions that uniformly produce substitution instances of those data sructures.     

Low-threshold room-temperature operation of injectorless quantum-cascade lasers: influence of doping density

The influence of the doping density in the active sections of InP-based injectorless quantum cascade lasers, emitting at 6.8 mum, is investigated. The doping sheet density is varied in the range 2.5-8.6times10¹⁰ cm^-2. Lasing is observed in the whole range, with a threshold current density as low as 1.2 kA/cm² at 300 K for the smallest doping sheet density of 2.5times10 ¹⁰ cm^-2. Further improvement has been made by additionally increasing the number of periods in the active region from 40 to 60. With the same doping level of 2.5times10¹⁰ cm^-2 record low threshold current densities of 0.73 kA/cm² at 300 K were achieved