Grafting of unsaturated acids and silanes to ethylene polymers: A kinetic model

A general kinetic model was developed to simulate the grafting of monomers such as unsaturated carboxylic acids and silanes to ethylene polymers. The polymers considered were ethylene-co-vinyl acetate (EVA), ethylene-co-butyl acrylate (EBA), and low-density polyethylene (LDPE). Grafting was assumed to proceed by a free-radical mechanism involving chain transfer. Organic peroxides having a strong tendency for hydrogen abstraction were selected as the source of primary radicals. The model simulated the grafting reaction as taking place in a single screw extruder. The residence time distribution in the extruder was experimentally determined by tracer analysis, according to which the extruder was a plug-flow reactor connected to two mixed reactors in parallel. The model is able to predict the extent of grafting in terms of predefined parameters. Comparison of model predictions with available experimental data showed slight deviations, the possible causes of which are discussed. However, the kinetic behavior expected on the basis of the input parameters was observed, and, as such, the model allowed study of the effect of process variables on grafting kinetics and provided insight into the reaction mechanism.     

Effect of obesity on the response to insulin therapy in noninsulin-dependent diabetes mellitus

An initial improvement in glycemic control is often followed by gradual deterioration of glycemia during insulin treatment of patients with noninsulin-dependent diabetes mellitus (NIDDM). We examined the causes of such worsening in a 12-month follow-up analysis of 100 insulin-treated NIDDM patients in the Finnish Multicenter Insulin Therapy Study who were treated with either combination therapy with insulin or insulin alone. In the entire study group, glycemic control averaged 9.7 +/- 0.2% at 0 months and 8.0 +/- 0.1%, 8.0 +/- 0.1%, 8.2 +/- 0.1%, and 8.5 +/- 0.2% at 3, 6, 9, and 12 months (P < 0.001 for each time point vs. 0 months). Glycemic control at 12 months was significantly worse than that at 3 (P < 0.001), 6 (P < 0.001), and 9 months (P < 0.02). Baseline body mass index was the most significant predictor of deterioration in glycemic control. During 1 yr, hemoglobin A1c decreased almost 3-fold more (by 1.7 +/- 0.2%; P < 0.001 vs. 0 months) in patients whose baseline weight was below the mean baseline body mass index of 28.1 kg/m2 (nonobese patients) than in those whose weight exceeded 28.1 kg/m2 (obese patients; 0.5 +/- 0.2%; P = NS vs. 0 months; P < 0.01 vs. obese patients). Glycemic control improved similarly over 1 yr in the nonobese subjects and deteriorated similarly in the obese patients regardless of their treatment regimen. Insulin doses, per body weight, were similar in the nonobese and obese patients. The nonobese patients consistently gained less weight during 12 months of combination therapy with insulin (3.5 +/- 0.6 kg at 12 months) than during insulin therapy alone (5.1 +/- 0.6 kg; P < 0.05). The treatment regimen did not influence weight gain in the obese group, who gained 4.4 +/- 1.0 kg during combination therapy with insulin and 4.5 +/- 1.1 kg during insulin therapy alone. We reached the following conclusions: 1) after an initial good response, glycemic control deteriorates more in obese than in nonobese patients with NIDDM; 2) in obese patients, weight gain per se cannot explain the poor glycemic response to combination or insulin therapy, but it may induce a disproportionately large increase in insulin requirements because of greater insulin resistance in the obese than in the nonobese; 3) in nonobese patients, glycemic control improves equally during 1 yr with combination therapy with insulin and insulin alone, but combination therapy with insulin is associated with less weight gain than treatment with insulin alone; 4) weight gain appears harmful, as it is associated with increases in blood pressure and low density lipoprotein cholesterol.     

Culture of Helicobacter pylori from gastric biopsies transported in biopsy urease test tubes

Gastric biopsy specimens of 57 consecutively observed dyspeptic patients were studied for the presence of Helicobacter pylori by histological examination, biopsy urease test (BUT) and culture. For culture, biopsy samples were transported in both Stuart media and BUT tubes. All 15 isolates could be cultured from both Stuart and BUT tubes. Thus, if the main reason for culture of Helicobacter pylori is for antimicrobial susceptibility testing, only positive BUT tubes need to be submitted. This would reduce both the expense and the number of biopsies needed.     

Copolymers of ethylene with butene-1 and long chain α-olefins. I. Decene-1 as long chain α-olefin

The possibility was studied of using decene-1 as comonomer with ethylene in a slurry type polymerization with Ziegler–Natta catalysts. Under the reaction conditions used decene contents remained at the 2 wt% level in ethylene/decene-1 copolymers. When additionally butene-1 was present in the polymerization, decene-1 contents were significantly higher. A synergistic effect was identified in the reactivities of butene-1 and decene-1 in terpolymerization with ethylene. The comonomer reactions were determined and comonomer contents measured by ¹³C-NMR spectroscopy. Decene-1 content had an effect on the polymer density and crystallinity, but virtually no effect on melting temperature. With high comonomer contents an additional melting range was identified in DSC curves at about 100°C.     

Modeling and Simulation of High Pressure Water Mist Systems

This paper describes work done to improve and validate the capability of fire dynamics simulator (FDS) to predict the dynamics of water mist sprays. Three single orifice and five multi-orifice spray heads are modeled with FDS based on information on the flow-rate, spray angle, operating pressure and experimentally determined particle size distribution. The capability of FDS to predict the drop size, velocity, mist flux and number concentration profiles within the spray cone is assessed. The effects of turbulence modeling on the predictions of the spray dynamics is investigated. The capability of FDS to predict the air entrainment by high-speed water sprays is validated using experiments in rectangular channels with open ends.     

Will New Antenna Materials Enable Single Path Multiple Access (SPMA)?

The aim of this paper is to introduce a novel frequency reuse concept especially for macro cellular networks to substantially increase the mobile network capacity, and simultaneously to avoid the implementation of low efficient small cells. Single path multiple access (SPMA) utilizes the characteristics of independent propagation paths for particular geographical location in the coverage area of mobile network. The proposed concept is based on the assumption that new approach will be adopted by the antenna manufacturers for producing advanced antennas by utilizing materials like metamaterials including carbon based nanotechnology, and graphene. In SPMA concept, communication between base station and mobile station happens through only single independent propagation path, and frequency resources can be reused in 5 m  \(\times \)  5 m areas or even more often in 1 m  \(\times \)  1 m areas, but limited by a base station/mobile station antenna requirement. Thus, the capacity of the network will be increased dramatically, and it can be managed in centralized manner at certain macro site locations. In already deployed cellular networks, these macro sites are mostly easily available, and that would help to implement SPMA to enhance the network capacity. Simulation results provided in this paper show the applicability of SPMA technique, by limiting the radiation of signal as single path propagation between base station and mobile station.     

Synthesis of cobalt nanoparticles to enhance magnetic permeability of metal–polymer composites

Metallic cobalt nanoparticles were synthesized by hydrogen reduction method. Particles were coated in situ with carbon by adding ethene to reaction flow. Particles were characterized by transmission electron microscopy, energy dispersive X-ray emission, X-ray diffraction, X-ray fluorescence and BET method. The observed cobalt particle size distributions in different cobalt batches produced with unvarying reaction parameters was reproducible: The mean diameter of primary cobalt particle varied only 5% from the mean value of 76 nm in different batches. Increased carbon precursor concentration decreased mean diameter of cobalt particles to 17 nm. The produced nanoparticles were used as filler material in 0–3 type metal–polymer composites. Composite samples with varying filler loading were fabricated with mixing extrusion and injection moulding techniques. The magnetic properties of the fabricated composites were measured up to 1 GHz. In order to analyse the particle distribution in composite matrix and its effect on magnetic properties the microstructure was studied.     

High-precision diode-laser-based temperature measurement for air refractive index compensation

We present a laser-based system to measure the refractive index of air over a long path length. In optical distance measurements, it is essential to know the refractive index of air with high accuracy. Commonly, the refractive index of air is calculated from the properties of the ambient air using either Ciddor or Edlén equations, where the dominant uncertainty component is in most cases the air temperature. The method developed in this work utilizes direct absorption spectroscopy of oxygen to measure the average temperature of air and of water vapor to measure relative humidity. The method allows measurement of temperature and humidity over the same beam path as in optical distance measurement, providing spatially well-matching data. Indoor and outdoor measurements demonstrate the effectiveness of the method. In particular, we demonstrate an effective compensation of the refractive index of air in an interferometric length measurement at a time-variant and spatially nonhomogeneous temperature over a long time period. Further, we were able to demonstrate 7 mK RMS noise over a 67 m path length using a 120 s sample time. To our knowledge, this is the best temperature precision reported for a spectroscopic temperature measurement.     

Light transmission model for determination of the refractive index of solid particles in suspensions: an immersion study

We report on a model to determine the light transmission of solid particles in immersion liquids. Using the model, optical and physical properties of suspensions such as the refractive index of the particles can be retrieved. The model can also be used in the case of colored suspensions, where the detection of only the maximum transmission would give an inaccurate refractive index for a particle. The validity of the method was tested with CaF(2) particles. Potential applications include scientific studies of the optical properties of micro- and nanoparticles or microorganisms in a liquid matrix. The model is also useful in industry where monitoring of suspensions and colloids is an issue.     

Comparison between infrared and Raman spectroscopic analysis of maturing rabbit cortical bone

The molecular composition of the organic and inorganic matrices of bone undergoes alterations during maturation. The aim of this study was to compare Fourier transform infrared (FT-IR) and near-infrared (NIR) Raman microspectroscopy techniques for characterization of the composition of growing and developing bone from young to skeletally mature rabbits. Moreover, the specificity and differences of the techniques for determining bone composition were clarified. The humeri of female New Zealand White rabbits, with age range from young to skeletally mature animals (four age groups, n = 7 per group), were studied. Spectral peak areas, intensities, and ratios related to organic and inorganic matrices of bone were analyzed and compared between the age groups and between FT-IR and Raman microspectroscopic techniques. Specifically, the degree of mineralization, type-B carbonate substitution, crystallinity of hydroxyapatite (HA), mineral content, and collagen maturity were examined. Significant changes during maturation were observed in various compositional parameters with one or both techniques. Overall, the compositional parameters calculated from the Raman spectra correlated with analogous parameters calculated from the IR spectra. Collagen cross-linking (XLR), as determined through peak fitting and directly from the IR spectra, were highly correlated. The mineral/matrix ratio in the Raman spectra was evaluated with multiple different peaks representing the organic matrix. The results showed high correlation with each other. After comparison with the bone mineral density (BMD) values from micro-computed tomography (micro-CT) imaging measurements and crystal size from XRD measurements, it is suggested that Raman microspectroscopy is more sensitive than FT-IR microspectroscopy for the inorganic matrix of the bone. In the literature, similar spectroscopic parameters obtained with FT-IR and NIR Raman microspectroscopic techniques are often compared. According to the present results, however, caution is required when performing this kind of comparison.