Influence of helical tube dimensions on open channel natural convection heat transfer

Natural convection heat transfer of a helical tube was investigated experimentally for varying tube diameter, length, height, pitch, radius, and number of turns, in order to determine an appropriate characteristic length to describe the phenomenon. Mass-transfer rates of a CuSO₄–H₂SO₄ electroplating system were measured by replacing the heat transfer system according to the analogy concept. When the pitch-to-diameter ratio was larger than 5 and the pitch-to-radius ratio was smaller than 2.3, the heat transfer rates were very close to those of a horizontal cylinder, and decreased with the diameter of the tube while remaining unaffected by the total length and height. The natural convection heat transfer of the Nth turn of a helical tube was measured for varying pitch-to-diameter ratio and number of turns, and the results were formulated as an empirical correlation.     

Hybrid DSO-GA-based sensorless optimal control strategy for wind turbine generators

The operation of a wind turbine generator involves natural uncertainty due to aerodynamic characteristics, resulting in a system that performs inefficiently. In general, the conventional controller now in wide use is not suitable for every operating point, because its tuning parameters and set-points do not meet the varying system characteristics. A study into an optimal control technique is conducted to reduce the negative effects of inherent uncertainty in system operation. In order to resolve the uncertainty problem, an optimal control method for an effective wind turbine generator is designed on the basis of a sensorless frame by utilizing a hybrid of the direct search optimization method (DSO) and the genetic algorithm (GA). This method is easy to implement and computation of functional derivatives is not necessary. The conventional GA is well known for its high performance in global optimization and its effectiveness in making ideal choices for control variables. The proposed DSO-GA hybrid differs from the conventional GA in terms of the sampling survey and the crossover operation. Moreover, the proposed multivariable optimal control strategy is a sensorless optimization technique that determines the pitch angle of the blades and the yaw angle of the nacelles to produce stable maximum power from a wind turbine system under steady-state operation. The proposed DSO-GA controller is implemented for a lab-scale wind turbine generator exposed to artificial wind, and the experimental results constitute a 3-D performance surface model of output voltage, which is used as an objective function for simulation. The optimization procedure with the objective function is carried out by means of the conventional and proposed methods, whose results reveal that the proposed DSO-GA optimizer yields far better performance in terms of generation number, convergence rate, and robustness. Both techniques are applied to a wind power generator through simulation and experiments. The performances are compared, and conclusions are drawn for each case.     

Redox-induced performance degradation of anode-supported tubular solid oxide fuel cells

Redox behavior of a Ni-Y₂O₃-stabilized ZrO₂ (YSZ) composite anode support and the performance degradation of an anode-supported tubular solid oxide fuel cell (SOFC) were studied under complete oxidation and reduction conditions (degrees of oxidation and reduction = 100%). Materials characterization studies showed that the exposure time in oxidizing and reducing atmospheres played a critical role in the degradation of the porous structures and the physical properties of the anode support. In particular, the redox cycling with an 8 h exposure time resulted in the cracking of YSZ network, leading to significant decay of the mechanical strength. The polarization experiments on the redox-cycled anode-supported tubular cell showed serious performance degradation as a result of the decreases of open-circuit potential and power density. The ac-impedance measurements combined with microstructural observations indicated that the performance degradation resulted mainly from (i) the degradation of anode support, (ii) microcracks across the whole cell, and (iii) interface delamination.     

The public's value of hydrogen fuel cell buses: A contingent valuation study

With the increasing interest in global warming, there has been intense international competition with regard to the introduction of the hydrogen (H₂) fuel cell (FC) bus, which represents a promising solution for the low-carbon age. With respect to the investment in H₂-based technology development and the expansion of H₂ FC vehicles, the consumer attitude is a crucial factor because the Korean government will consider it one of the most important factors in its decision to approve a large-scale introduction of H₂ FC buses. In this regard, this study measures the public's willingness to pay (WTP) for a large-scale introduction of H₂ FC buses in Korea by employing a survey approach termed the contingent valuation. Furthermore, to enhance statistical efficiency, this study employs the one-and-one-half-bound dichotomous choice method. The annual mean WTP estimate was KRW 4230 (USD 4.55) per household as of 2007. The estimate of the annual benefits to the affected residents was KRW 32.3 billion (USD 34.7 million). The results of this study are expected to be helpful in policy decisions related to the introduction of H₂ FC buses and investment in H₂ technology development.     

ZnO spintronics and nanowire devices

ZnO is a very promising material for spintronics applications, with many groups reporting room-temperature ferromagnetism in films doped with transition metals during growth or by ion implantation. In films doped with Mn during pulsed laser deposition (PLD), we find an inverse correlation between magnetization and electron density as controlled by Sn-doping. The saturation magnetization and coercivity of the implanted single-phase films were both strong functions of the initial anneal temperature, suggesting that carrier concentration alone cannot account for the magnetic properties of ZnO:Mn and factors such as crystalline quality and residual defects play a role. Plausible mechanisms for ferromagnetism include the bound magnetic polaron model or exchange that is mediated by carriers in a spin-split impurity band derived from extended donor orbitals. The progress in ZnO nanowires is also reviewed. The large surface area of nanorods makes them attractive for gas and chemical sensing, and the ability to control their nucleation sites makes them candidates for microlasers or memory arrays. Single ZnO nanowire depletion-mode metal-oxide semiconductor field effect transistors exhibit good saturation behavior, threshold voltage of ∼−3 V, and a maximum transconductance of 0.3 mS/mm. Under ultraviolet (UV) illumination, the drain-source current increased by approximately a factor of 5 and the maximum transconductance was ∼5 mS/mm. The channel mobility is estimated to be ∼3 cm²/Vss, comparable to that for thin film ZnO enhancement mode metal-oxide semiconductor field effect transistors (MOSFETs), and the on/off ratio was ∼25 in the dark and ∼125 under UV illumination. The Pt Schottky diodes exhibit excellent ideality factors of 1.1 at 25°C, very low reverse currents, and a strong photoresponse, with only a minor component with long decay times thought to originate from surface states. In the temperature range from 25°C to 150°C, the resistivity of nanorods treated in H₂ at 400°C prior to measurement showed an activation energy of 0.089 eV and was insensitive to ambient used. By contrast, the conductivity of nanorods not treated in H₂ was sensitive to trace concentrations of gases in the measurement ambient even at room temperature, demonstrating their potential as gas sensors. Sensitive pH sensors using single ZnO nanowires have also been fabricated.     

Application of micellar electrokinetic capillary chromatography for the determination of benzoic acid and its esters in liquid formula medicines as preservatives

We described a method for the simultaneous determination of preservatives including benzoic acid, methyl-, ethyl- and propyl-benzoate by micellar electrokinetic capillary chromatography (MECC). The factors affecting the reproducibility in the quantitative analysis of pharmaceuticals by MECC were investigated by varying the running buffer and washing condition in-between runs. Preservatives in liquid formula medicines have been determined by optimum MECC condition using p-hydroxy benzoic acid as an internal standard. The reproducibility of this method was acceptable as a validate method for the quality control of pharmaceuticals (RSD < 2%). Routine quantitative analysis of pharmaceuticals using MECC could be possible with well characterized reproducible procedure.     

Titanium implants and BMP-7 in bone: an experimental model in the rabbit

This study evaluates the effect of rhBMP-7/OP-1 on the osseointegration of commercially pure titanium implants in an experimental implant model in rabbits. Threaded titanium implants with two transverse parallel canals were inserted in the femur and tibia of rabbits. The canals were filled with, 10 g of BMP-7/collagen carrier, pure collagen carrier or were left empty as a control. The stiffness of the implant fixation was evaluated by Resonance Frequency Analysis (RFA) at baseline and four weeks postoperativly. Percentage of bone ingrowth in the canals was measured on microradiographs. Histomorphometry along the threaded part of the implants was performed on 15 m thin sections. The results from the RFA demonstrated a higher mean value for the BMP-7 treated implants in the tibia than the carrier treated implants but not compared to the control implants. The control implants in the tibia demonstrated more bone ingrowth in the upper canal than to the carrier or the BMP-7 treated implants. Apart from these differences there were no significant effects of BMP. In this study BMP-7 did not contribute to any substantially improved bone anchorage of titanium implants.     

Activity-Sensitive Flip-Flop and Latch Selection for Reduced Energy

This paper presents new techniques to evaluate the energy and delay of flip-flop and latch designs and shows that no single existing design performs well across the wide range of operating regimes present in complex systems. We propose the use of a selection of flip-flop and latch designs, each tuned for different activation patterns and speed requirements. We illustrate our technique on a pipelined MIPS processor datapath running SPECint95 benchmarks, where we reduce total flip-flop and latch energy by over 60% without increasing cycle time.