Comparison of bioactive phytochemical content and release of isothiocyanates in selected brassica sprouts

The consumption of brassica sprouts as raw vegetables provides a fair amount of glucosinolates (GLs) and active plant myrosinase, which enables the breakdown of GLs into health-promoting isothiocyanates (ITCs). This study reports the determination of the main constituents related to human health found in edible sprouts of two Brassica oleracea varieties, broccoli and Tuscan black kale, and two Raphanus sativus varieties, Daikon and Sango. Radish sprouts exhibited the highest ability to produce ITCs, with Daikon showing the greatest level of conversion of GLs into bioactive ITCs (96.5%), followed by Sango (90.0%). Tuscan black kale gave a value of 68.5%, whereas broccoli displayed the lowest with 18.7%. ITCs were not the exclusive GL breakdown products in the two B. oleracea varieties, since nitriles were also produced, thus accounting for the lower conversion observed. Measuring the release of plant ITCs is a valuable tool in predicting the potential level of exposure to these bioactive compounds after the consumption of raw brassica sprouts.     

Sol–Gel Processing and Characterization of Pure and Metal-Doped SnO2 Thin Films

A chloride-based inorganic sol–gel route was used for preparing pure and metal (osmium, nickel, palladium, platinum)-doped SnO₂ sol. SnCl₄ was first reacted with propanol, then the resulting compound was hydrolyzed and subsequently mixed with solutions of the metal dopants. The obtained sols were used for depositing thin films by spin coating or for preparing powders by solvent evaporation at 110°C. FTIR spectroscopy and thermal analysis of the powders revealed that chlorine still bound to tin stabilized the sol against gelation by hindering the condensation reactions. Film characterizations showed that platinum and palladium, unlike nickel and osmium, were likely to form nanoparticles in the SnO₂ lattice. This result was discussed with regard to the different ways that platinum and palladium, on one hand, and nickel and osmium, on the other, modified the growth of SnO₂ grains and the film roughness and morphology. Dopants that formed nanoparticles (platinum, palladium) resulted in the roughest film, while dopants that did not form particles (nickel, osmium) resulted in SnO₂ grain size very close to that of pure SnO₂.     

Landscape dynamics of Mediterranean montane grasslands over 60 years and implications for habitats conservation. A case study in the northern Apennines (Italy)

Widespread trends of abandonment have strongly affected Mediterranean mountains after the Second World War, triggering spontaneous recolonisation of forests. A diachronic analysis of the landscape in a Natura 2000 site (Tuscany, Italy) was carried out using digital aerial photographs (1954, 2013) and a GIS-based methodology, focusing on territories above 1300 m a.s.l. The detected variations of total areas, patch shape, patch dimensions and selected metrics showed a notable shift of the vegetation towards woody types and a drastic reduction of open grasslands, some with high conservation value, accompanied by a strong increase in patch number, surface and edge. A decrease of SDI and SEI diversity indices was also observed. Considering that fragmentation is one of the main causes threatening habitats and species, our results point out a clear necessity for a monitoring programme and suitable actions aimed at improving the status of biodiversity-rich montane grasslands.     

Corrosion behaviour of sol–gel treated and painted AA2024 aluminium alloy

Design, development and scale-up of environmentally friendly coatings are very important in order to replace chromate based coatings for aluminium alloys. Barrier properties, paint adhesion and possibly self-healing ability are relevant aspects for replacement of chromate-based pre-treatments. Sol–gel materials are candidates for use in protective coating applications, as it is possible to form highly adherent and chemically inert oxide films on metal substrates.     

Bed Sediment Characteristics in the Paraná and Paraguay Rivers

ABSTRACT

This paper presents a granulometric characterization of the Paraná and Paraguay rivers bed sediments. Samples obtained along 2,900 km of the thalweg of those rivers form the basis of this study. The main results and other features of the study are as follows: a) the bed sediment of both rivers is composed mainly of medium to fine well-sorted sands, with sizes in the Paraná slightly higher than those in the Paraguay river; b) the variations of mean diameters for both rivers are well correlated with the energy slopes. The correlation coefficient in the Paraguay river increases notably if the discharge and width/depth relationship variations along the channel are included in the regression; and, c) the origin of the transported sands could be related to the geologic characteristics of the Paraná river basin. An explanation is also suggested for the different bed sediment texture found in the Paraná de las Palmas and Paraná Guazú rivers in the lower delta. The explanation is based on the geomorphic processes that built that region of the Paraná river.     

Corrosion behavior of thermoelectric clathrates α- and β-Eu8Ga16−xGe30+x in air

The corrosion of thermoelectric clathrates α- and β-Eu₈Ga_16−xGe_30+x is studied under static air (DSC/TG) up to 650 °C. Oxidation product layers with thicknesses of 10.5 μm (α-Eu₈Ga_16−xGe_30+x) and 4.5 μm (β-Eu₈Ga_16−xGe_30+x) are formed. The oxidation begins at 360 and 380 °C, respectively. XRD pattern of the β-Eu₈Ga_16−xGe_30+x oxidized layer shows Ge and four Eu₂O₃ reflections; while α-Eu₈Ga_16−xGe_30+x data (sample crushed and grinded) shows α-Eu₈Ga_16−xGe_30+x reflections (majority phase), two EuGa_2±xGe_4?x strongest reflections and Ge (minority phases). These results indicate the amount of oxides is very small or they are amorphous. High temperature powder XRD measurements on α-Eu₈Ga_16−xGe_30+x under air confirm the oxidation onset temperature determined in DSC studies.     

Multi-agent quality of experience control

International Journal of Control, Automation and Systems - In the framework of the Future Internet, the aim of the Quality of Experience (QoE) Control functionalities is to track the personalized...     

Software corrections of vocal disorders

We discuss how vocal disorders can be post-corrected via a simple nonlinear noise reduction scheme. This work is motivated by the need of a better understanding of voice dysfunctions. This would entail a 2-fold advantage for affected patients: Physicians can perform better surgical interventions and on the other hand researchers can try to build up devices that can help to improve voice quality, i.e. in a phone conversation, avoiding any surgical treatment. As a first step, a proper signal classification is performed, through the idea of geometric signal separation in a feature space. Then through the analysis of the different regions populated by the samples coming from healthy people and from patients affected by T1A glottis cancer, one is able to understand which kind of interventions are necessary in order to correct the illness, i.e. to move the corresponding feature vector from the sick region to the healthy one. We discuss such a filter and show its performance.