Preparation and magnetoelectric properties of NiFe2O4–PZT composites obtained in-situ by gel-combustion method

Magnetoelectric composites of xNiFe₂O₄–(1 ? x)Pb(Zr,Ti)O₃ with x = 2, 5, 10, 20, 30% were prepared by citrate–nitrate combustion using PZT-based template powders. In order to ensure a better connectivity of dissimilar phases, we have used chemical methods for preparation in situ composites, followed by adequate sintering procedure. The structural, microstructural and functional properties of di-phase magnetoelectric composites of NiFe₂O₄–PZT are reported. The XRD analysis is demonstrating the synthesis of pure ferrite phase directly on the ferroelectric templates. An excellent mixing was obtained in the composite powders, as proved by a detailed SEM analysis.The magnetic and dielectric behaviors of the ceramic composites vary with the ratio of the two phases. The dielectric behavior is greatly influenced by the magnetic phase. The magnetoelectric (ME) coefficient was measured as a function of applied DC magnetic field. The maximum ME coefficient (dE/dH) varies from 0.0011 mV/(cm Oe) to 0.5 mV/(cm Oe) with increasing of NF addition.     

Electric capacity expansion under uncertain demand: decompositionapproaches

The authors present a stochastic model of electric capacity expansion planning under uncertainty in demand. The goal of this problem is to determine the most interesting investments (plants and capacity levels) over the considered planning time (up to several years). Periods are divided into smaller subperiods (e.g. weekly or monthly) for which demand is assumed uncertain and modeled as a continuous probability distribution function. This leads to consider the risk associated to each decision for the capacity to be used (electricity generation). A first approach as a nonlinear continuous model is presented. Benders decomposition and Lagrangean relaxation-decomposition are proposed as solution methods, where the structures of the related sub-problems are exploited to speed up the convergence. The authors provide a large computational experience and comparisons within these methods and other general purpose optimization packages, and focus the report on the advantages of each     

功耗低于1.5mW的精密倾斜/下落检测器

当你需要检测与地球重力有关的角度位置时,你可以使用Analog Devices公司的三轴MEMS加速计。ADXL335有三路模拟输出,对应于正交坐标系统的X、Y、Z     

A general inelastic internal state variable model for amorphous glassy polymers

This paper presents the formulation of a constitutive model for amorphous thermoplastics using a thermodynamic approach with physically motivated internal state variables. The formulation follows current internal state variable methodologies used for metals and departs from the spring-dashpot representation generally used to characterize the mechanical behavior of polymers like those used by Ames et al. in Int J Plast, 25, 1495–1539 (2009) and Anand and Gurtin in Int J Solids Struct, 40, 1465–1487 (2003), Anand and Ames in Int J Plast, 22, 1123–1170 (2006), Anand et al. in Int J Plast, 25, 1474–1494 (2009). The selection of internal state variables was guided by a hierarchical multiscale modeling approach that bridged deformation mechanisms from the molecular dynamics scale (coarse grain model) to the continuum level. The model equations were developed within a large deformation kinematics and thermodynamics framework where the hardening behavior at large strains was captured using a kinematic-type hardening variable with two possible evolution laws: a current method based on hyperelasticity theory and an alternate method whereby kinematic hardening depends on chain stretching and material plastic flow. The three-dimensional equations were then reduced to the one-dimensional case to quantify the material parameters from monotonic compression test data at different applied strain rates. To illustrate the generalized nature of the constitutive model, material parameters were determined for four different amorphous polymers: polycarbonate, poly(methylmethacrylate), polystyrene, and poly(2,6-dimethyl-1,4-phenylene oxide). This model captures the complex character of the stress–strain behavior of these amorphous polymers for a range of strain rates.     

Nanocrystalline silicon films formed under the impact of pulsed excimer laser radiation on polyimide substrates

Polycrystalline silicon films on polyimide substrates were obtained by a method based on the crystallization of amorphous films under the impact of nanosecond pulses of excimer laser radiation. Characteristics of the film structure were studied by methods of Raman scattering and high-resolution electron microscopy. For the laser crystallization regimes employed, nanocrystalline silicon films with an average grain size of 5 nm were obtained. The results are of interest for the development of large-scale microelectronic devices (active thin-film transistor matrices) on cheap flexible substrates.     

Compositional, structural, optical and electrical characterization of CulnTe2 grown by the tellurization of stoichiometric Cu and in in the liquid phase

A new method to grow single crystals with stoichiometry close to 1:1:2 of CuInTe₂, an important member of the Cu-III-VI₂ family of semiconductors is described. This consists of tellurization in the liquid phase of stoichiometric Cu and In and later solidification under directional freezing. It is found from energy dispersive spectroscopy that the ingots obtained with the evaporation temperature (T_t) of Te at 590 and 635°C were very close to the ideal stoichiometry 1:1:2. Samples of all ingots obtained with T_t between 530 and 690°C, as studied by x-ray and differential thermal analysis, were of single phase having chalcopyrite structure and p-type conductivity. Optical and electrical characterization of different ingots were made. The acceptor ionization energy E_A and the density of states effective mass m _p ^* of the holes are estimated from the temperature dependence of the hole concentration p in samples of different ingots. m _p ^* = (0.78 ± 0.02) m_e agrees quite well with the reported value. From a combined analysis of the variation of E_A with p^1/3 and the knowledge of molecularity and valence stoichiometry of each sample, it is established that the shallow acceptor level observed in different samples with E_A (0) ⋍ 30 meV is due to V_In.     

Phonological competition and cooperation in form-related priming: Sequential and nonsequential processes in word production.

Phonological competition theory states that competition among discrepant segments of similar words leads to inhibition of high-frequency word-naming responses in form-related priming tasks. If segments are selected sequentially, competition should be greater for begin-related pairs (storage-story), in which discrepant segments are late in the words, than for end-related pairs (glory-story), in which discrepant segments are selected before the shared ones. This pattern was not observed in standard visual priming, probably because of the influence of parallel orthographic input. However, it was observed in a repetitive word-pair production task in which visual input was absent. The findings favor a class of models in which nonsequential activation of phonological content precedes sequential selection of the segments of words to be spoken. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

一所大学建筑中用高效率的照明合理使用电能

0 引言 为了在用能效率上作出工程努力,Cortagena技术大学去年4月已决定实施一项雄心勃勃的计划,要在此后的4年中削减用电费用。为了证实不同政策的可行性和成本效益,应用于原海军医院(工业工程高等技术学校总部)的许多展示活动将在最近期内完成。当然,在此建筑中合理用电的对象将集中在两个主要的电气末端即:电     

Cationic polyelectrolytes,XI. Polymers with quaternary N-atoms in the main chain obtained by condensation polymerization of epichlorohydrin with amines

Water soluble cationic polyelectrolytes containing quaternary nitrogen atoms within the main chain were prepared via condensation polymerization of epichlorohydrin (ECH) with dimethylamine (DMA) and N,N-dialkylaminoalkylamines. The main parameters of the reaction that influence the polymer properties are: DMA/asymmetrical diamine molar ratio, the initial concentration of amine solution, NaOH/amine molar ratio, ECH/amine molar ratio, and asymmetrical diamine structure. The feature of flexible polyelectrolyte own to the investigated polymers was emphasized by the viscosimetric behaviour in dilute aqueous solutions with and without salt presence.     

Alkylcarbenium Ion Concentrations in Zeolite Pores During Octane Hydrocracking on Pt/H-USY Zeolite

Hydroconversion of octane over platinum loaded acid zeolites was simulated using a single-event microkinetic model. Significantly different values for the alkene standard protonation enthalpies, i.e., ?59.2 and –94 kJ mol^?1 for the charging of secondary and tertiary carbon atoms respectively, were obtained. This difference is in favor of a carbocationic nature of the reactive intermediates on the acid sites rather than surface alkoxides. The concentration of alkylcarbenium ions on a Pt/H-USY catalyst resulting from protonation of alkenes in n-octane hydrocracking was calculated. It was strongly dependent on pressure and temperature. At a reaction temperature of 506 K, a total pressure of 0.45 MPa and H₂/HC molar ratio of 13.13, the concentration of alkylcarbenium ions corresponds to 15% of the total acid site concentration. At higher total pressures this percentage is lower and can be assumed to be negligible. The presence of a finite alkylcarbenium ion concentration in the zeolite pores results in a reduction of the free space available for physisorption of alkanes. Refined kinetic models are obtained when including this effect. Depending on the nature of the zeolite, alkylcarbenium ion concentrations can be significantly different owing to differences in alkane physisorption and alkene protonation. Literature data were rationalized using the refined kinetic model.