Use of low‐level plasma for enhancing the shrink resistance of wool fabric treated with a silicone polymer

This study examines the effects of an atmospheric pressure plasma (APP) pre‐treatment on the shrink resistance of wool fabric treated subsequently, by the pad/dry method, with an aqueous emulsion of the amino‐functional polydimethylsiloxane, SM 8709. Optimal shrink resistance (with no impairment of fabric handle) was obtained after a low‐level plasma treatment (1–3 s exposure time), using 5% of the polymer emulsion. Higher levels of silicone polymer could be used to achieve shrink resistance in the absence of a plasma pre‐treatment, but the fabric handle would be adversely affected. X‐ray photoelectron spectroscopy (XPS) studies showed that the bulk of the covalently bound surface lipid layer was removed after a plasma exposure time of 30 s. For treatment times of 3 s or less, however, the removal was incomplete, suggesting that optimum shrink resistance (after treatment with the silicone polymer) was associated with the modification of the surface layer rather than its complete destruction. Scanning electron micrographs (SEMs) revealed that the plasma pre‐treatment did not lead to any physical modifications (such as smoothening of the scale edges), even for long exposure times, and had no significant impact on the extent or nature of the inter‐fibre bonding of the polymer. Confocal microscopy showed uniform spread of polymer on single fibres. It is concluded that the main impact of the plasma pre‐treatment was to enhance the distribution of polymer both on and between fibres and to improve adhesion of polymer to the fibre.     

Theoretical and practical investigations of copper ion selective electrode with polymeric membrane based on N,N′-(2,2-dimethylpropane-1,3-diyl)-bis(dihydroxyacetophenone)

A novel ion-selective poly(vinyl chloride) (PVC) membrane sensor for Cu²⁺ ions based on N,N′-(2,2-dimethylpropane-1,3-diyl)-bis(dihydroxyacetophenone) (NDHA) as a new ionophore was prepared and studied. The best performance was observed for the membrane composition, including 30:65:1:4 (wt%) = PVC:DBP:KTpClPB:NDHA. The electrode showed a good Nernstian slope of 30.0 ± 0.5 mV/decade in a wide linear range activity of 3.0 × 10⁻⁷ to 1.0 × 10⁻² mol dm⁻³ Cu(NO₃)₂ with limit of detection 2.5 × 10⁻⁷. Sensor exhibited a fast response time (t_95% < 10 s) and could be used for about 4 months in the pH range of 3.0–7.4. The proposed potentiometric sensor was found to work satisfactorily in partially non-aqueous media up to 30 (vol%) content of methanol, ethanol and acetone. Applications of this electrode for the determination of copper in real samples, and as an indicator electrode for potentiometric titration of Cu²⁺ ion using EDTA, were reported. In order to predict the extraction ability of NDHA for different metallic ions, the complexes [M(NDHA)] and [M(H₂O)₆] (where M = Cu²⁺, Co²⁺, Hg²⁺, Pb²⁺, Ag⁺, Mg²⁺, Ca²⁺, Mn²⁺, Zn²⁺, Cd²⁺, K⁺ and Al³⁺) were investigated using ab initio theoretical calculations. The metal binding capability was evaluated using the binding energy. Results of our study could be useful for prediction of the extraction power of this Schiff base and could play a guiding role in planning experiments.     

Production of three anti-listerial peptides by Lactobacillus curvatus in MRS broth

Three novel bioactive peptides (BAP1–3) from Lactobacillus curvatus CWBI-B28 were isolated and purified using de Man, Rogosa and Sharp (MRS) broth by a three-step protein purification protocol including ammonium sulfate precipitation, hydrophobic C₁₈ Sep-Pak column and reverse-phase high performance liquid chromatography (RP-HPLC). This procedure allowed the recovery of chromatographically pure antimicrobial peptides with the yields of 19%, 10% and 15% of BAP1, BAP2 and BAP3, respectively. The respective apparent molecular masses as determined by tricine-SDS-polyacrilamide gel electrophoresis were 6365, 3426 and 3496. N-terminal amino acid sequencing of the BAPs and comparison of their sequences with those of international data bases indicated that BAP1 is more likely to be a casein-derived bioactive protein produced upon hydrolysis of the tryptone present in MRS broth by Lb. curvatus CWBI-B28 during active growth. However, the identity of BAP2 and BAP3 could not be determined with certainty; yet, they would be novel bacteriocins not fitting in any of the known classes of bacteriocins. Therefore, this strain would have the ability to produce intrinsic antimicrobial substances and also release bioprotective peptides from milk-proteins upon cultivation in milk or casein-containing food products due to its proteolytic activity. Thus, Lb. curratus CWBI-B28 possesses a good potential to be used in food preservation and safety.     

Analysis of the hazards for the molten cuprous chloride pouring operation in an industrial hydrogen production facility

An analysis is reported of a design for a local exhaust ventilation system for the molten cuprous chloride pouring station in an industrial plant. Heat recovery from molten cuprous chloride is a key process within the copper–chlorine (Cu–Cl) cycle of thermochemical water splitting for hydrogen production. Because of particulate matter, dust, and vapors emitted by the molten salt, an effective and safe design is crucial. The design process involves calculating duct diameters to provide the desired duct air velocity through the system. The static pressure is evaluated so that the fan size can be determined. An adequate supply of makeup air must be provided to replace the air exhausted through the ventilation system. The economics of the ventilation system and ways to protect employee health, as well as minimize the costs associated with exhaust ventilation, are also described. Copyright © 2011 John Wiley & Sons, Ltd.     

Miscibility and tack of blends of poly (vinylpyrrolidone)/acrylic pressure-sensitive adhesive

In this study, miscibility and tack of blends of poly (vinylpyrrolidone) (PVP)/acrylic pressure-sensitive adhesive (PSA) were evaluated. For this purpose, appropriate amounts of PVP (2–30% w/w) were added to an acrylic PSA to obtain visually homogeneous solution. The resulting solution was evenly applied on a polyethylene terephthalate (PET) film with final specific thicknesses of 10, 40, and 70 μm by using a film applicator and miscibility as well as tack values were evaluated. With the addition of 2% (w/w) PVP the tack value decreased and increased in 5% (w/w) PVP and then continuously decreased up to 30%(w/w). It was found that the tack value was related to miscibility as well as to viscosity and the free functional group such as hydroxyl group of the blend. By the morphological analysis performed through scanning electron microscopy (SEM) and also by the study of thermal analysis using the differential scanning calorimetry (DSC) behavior of blends, it was found that the two distinct phases constituted after adding 5% (w/w) of PVP. This resulted in the acrylic PSA forming the continuous phase, and by increasing the concentration of PVP a dispersed phase was developed. The dispersed phase has a higher viscosity than the continuous phase and therefore cannot wet the adherent and hence result in lowering the tack values.     

Optimization of the water-based road-marking paint by experimental design, mixture method

The main purpose of this research is formulating and optimizing a new road-marking paint which is an environmentally friendly product. This paint is produced with an emulsion of an acrylic copolymer and contains the least of the volatile organic compounds. The formulation and optimization procedure is carried out on the base of experimental design by the method of mixture in which the important paint properties are modeled by using special cubic model. The present method has the capability of investigation the effect of raw materials at different levels with fewer experiments than factorial and fractional factorial design.

In this research, the main parameters such as resin, pigment and filler were selected at different levels, and different samples were prepared by combination of additives and other required reagents. The properties of wet and dry films of the samples were determined using ASTM test methods. Different responses such as pigment volume concentration (PVC), latex critical pigment volume concentration (LCPVC), abrasion resistance, hardness, gloss, no pick up time and surface drying time, were selected as the objective functions of this study. By running DX6 software, using special cubic model and selection of desired range of end-use properties, the region of optimum paint formula was determined.

The accuracy of the model was examined by preparing a sample in optimized region and by determining its final properties, experimentally. The results exhibit a good agreement between the model and experimental measurements. This product was compared with commercial solvent based traffic paint and good quality was reported in end-use properties.     

A Proteomic Analysis of Human Follicular Fluid: Comparison between Younger and Older Women with Normal FSH Levels

The follicular fluid (FF) is produced during folliculogenesis and contains a variety of proteins that play important roles in follicle development and oocyte maturation. Age-related infertility is usually considered as a problem that can be solved by assisted reproduction technology. Therefore, the identification of novel biomarkers that are linked to reproductive aging is the subject of this study. FF was obtained from healthy younger (20–32 years old) and older (38–42 years old) women undergoing intracytoplasmic sperm injection (ICSI) due to male factor infertility. The FF was analyzed by two-dimensional gel electrophoresis (2-DE). The power of two-dimensional gel electrophoresis and the identification of proteins were exploited using matrix-assisted laser desorption-ionization time-of-flight/time-of-flight (MALDI-TOF-TOF) mass spectrometry. Twenty three protein spots showed reproducible and significant changes in the aged compared to the young group. Of these, 19 protein spots could be identified using MALDI-TOF-TOF-MS. As a result of MASCOT search, five unique downregulated proteins were identified in the older group. These were identified as serotransferrin, hemopexin precursor, complement C3, C4 and kininogen. A number of protein markers were found that may help develop diagnostic methods of infertility.     

An ultra low-voltage low power PSK backscatter modulator for passive UHF RFID tags compatible with C1 G2 EPC standard protocol

Reducing the power consumption of a passive radio frequency identification (RFID) tag is the key in many applications. As the modulator is usually the most power-hungry block in an RFID tag, this paper proposes a power-saving modulator. The proposed modulator uses phase shift keying (PSK) backscatter modulation which allows tag to communicate data from its memory to a reader by PSK modulation. The proposed modulator uses a MOSCAP as a variable impedance and is designed in a new one-inverter structure in compare to the conventional varactor-based modulators designed in two-inverter structure, as this modulator needs just a low voltage swing to drive its MOSCAP. Using MOSCAP as the variable capacitance leads to a low voltage design. Also, the fundamental equations required for determination of the capacitive impedance seen by the antenna is presented. This impedance is the master key in modulator design. The modulator has been designed, simulated and optimized in 0.18 μm CMOS technology. All possible simulation results are presented to approve its compatible operation with C1 G2 EPC global standard. The power consumption of less than 46 nW is achieved in all process corner cases at 0.8 V power supply.     

Effects of Modified Atmosphere Packaging with Various Carbon Dioxide Composition on Biogenic Amines Formation in Indian Mackerel (Rastrelliger kanagurta) stored at 5 ± 1°C

The profile of major biogenic amines was investigated in Indian mackerel packed in modified atmosphere for up to 12 days at 5 ± 1°C. Beheaded and gutted Indian mackerel was packed under different carbon dioxide compositions to study the effects on biogenic amines formation. The treatments were control air (C), vacuum packaging (VP), 30% CO₂/65% N₂/5% O₂ (M30C), 60% CO₂/35% N₂/5% O₂ (M60C), 80% CO₂/15% N₂/5% O₂ (M80C) and 100% CO₂ (M100C). Each amine responded differently to different CO₂ levels. After 12 days of storage, concentrations of histamine were reduced by 6.4%, 8.5%, 70.3%, 78.8% and 90.2% in fish packed under VP, M30C, M60C, M80C and M100C, respectively as compared with control air. Changes in putrescine and cadaverine showed a similar pattern. Gas mix of M30C and VP stimulated the formation of tyramine reaching 203 and 172 ppm, respectively. Higher composition of CO₂ had a significant inhibitory effect on tyramine concentration (p < 0.05). There were parallel increases of putrescine and spermidine in C, VP and M30C. No significant effect of CO₂ was observed on spermine (p > 0.05). After 9 days of storage, more than 300 ppm of histamine was detected in mackerel packed in VP and M30C; therefore, these atmospheres pose a histamine intoxication risk. Copyright © 2013 John Wiley & Sons, Ltd.