Solvent modification effect on the physical and chemical extraction of acetic acid

Combined use of inert diluents with polar modifiers enables former to be utilized for the recovery of polar value-added chemicals. The results show that polarities of both solvent and modifier are critical for efficient separations. Thus, K_D values with 1-octanol were higher than those with 1-decanol; however, those with xylene were superior to those with hexane and toluene. Increasing the amine concentrations increased the K_D values, in contrast to the trends with pH and temperature. About 33%, 79% and 67% of acetic acid was recovered using 25% (v/v) Alamine 336 in xylene, 1-octanol and 30% 1-octanol-modified xylene, respectively. Therefore, solvent modification positively affects the extraction power of inert diluents for acetic acid recovery.     

Comparison of the effects of different retention appliances on the oxidant–antioxidant system

The aim was to compare oxidative stress (OS) levels with different types of retention appliance. Thirty orthodontic patients were divided into three groups: Group 1 (Essix retainer), Group 2 (lingual retainer with stainless steel retainer wire), and Group 3 (lingual retainer with fiber-reinforced material). OS was assessed in the subjects’ saliva. Saliva samples were taken from the patients at T₀ (before using the retention appliance), T₁ (first month of retention), and T₂ (third month of retention). The specimens were investigated to detect changes in total antioxidant status (TAS), total oxidant status (TOS), and oxidative stress index (OSI). TAS values in Group 2 were significantly higher than in Group 3. TOS values in Group 3 were significantly lower than in the other groups. TOS values in Group 2 were lower than in Group 1. OSI values of Group 1 were higher than those in Group 2 or 3. There was no statistically significant difference among the time periods. The type of retention appliance affected OS values. A fiber-reinforced material may have a lower OSI. OS or products can affect some systemic disease; therefore, the selection of the retainer will be important on these patients.     

Quinoxaline derivatives as long wavelength photosensitizers in photoinitiated cationic polymerization of diaryliodonium salts

The present paper is focused on visible light initiated cationic polymerizations. Photoinitiated polymerization of representative vinyl ether and oxirane monomers using two quinoxaline derivatives; namely (2-(2,3-dihydrobenzo [b][1,4]dioxin-6-yl)-3-(2,3-dihydrobenzo[b]-[1,4]dioxin-7-yl)-5-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-8-(2,3-dihydrothieno[3,4-b][1,4]dioxin-7yl) quinoxaline) (DBQEd) and 2,3,5,8-tetra(thiophen-2-yl)quinoxaline (TTQ) are studied. Novel dyes based on the quinoxaline skeleton are employed as efficient photosensitizers in cationic photopolymerizations. Polymerizations were initiated at room temperature upon irradiation with long-wavelength UV and visible lights in the presence of diphenyliodonium hexafluorophosphate (Ph₂I⁺PF₆^?). The progress of the polymerizations was monitored by optical pyrometry (OP). Solar irradiation is also employed to carry out the cationic polymerization of a diepoxide monomer in the presence of air.     

A Novel Approach for Bolted T-Stub Connections

This paper reports an investigation into new connection types and their behaviors determined using full-scale experiments. T-shaped connections were created using the IPE standard profile. The aim of this study was to analyze the influence of T connections based on the IPE standard profile, height of beam to height of T-stub joint (H) of T-stub joints, and lengths (X) of T-stub joints on the behavior of steel connections, in order to provide the necessary data for improving Eurocode 3 and enable efficient use of residue IPE standard profiles and back to the consumption cycle. While the moment resistance values increased with an increase in H from H_min to H_max in model groups with X of 126 mm, and the energy dissipation increased with an increase in H from H_min to H_max and also with an increase in the lengths (X) of T-stub joints from 54 to 126 mm.     

Thermal performance of a solar cooker integrated vacuum-tube collector with heat pipes containing different refrigerants

A solar cooking system using vacuum-tube collectors with heat pipes containing a refrigerant as working fluid has been fabricated, and its performance has been analysed experimentally. The experiments were conducted during clear days in July and August of 2002 in Elazı , Turkey under similar meteorological conditions for three refrigerants and water. Detailed temperature distributions and their time dependences were measured. The maximum temperature obtained in a pot containing 7 l of edible oil was 175 °C. Also, the cooker was successfully used to cook several foods. The cooking processes were performed with the cooker in 27–70 min periods.     

Temperature distributions in boreholes of a vertical ground-coupled heat pump system

The objective of this study is to show the temperature distribution development in the borehole of the ground-coupled heat pump systems (GCHPs) with time. The time interval for the study is 48 h. The vertical GCHP system using R-22 as refrigerant has a three single U-tube ground heat exchanger (GHE) made of polyethylene pipe with a 40 mm outside diameter. The GHE was placed in a vertical borehole (VB) with 30 (VB1), 60 (VB2) and 90 (VB3) m depths and 150 mm diameters. The experimental results were obtained in cooling and heating seasons of 2006–2007. A two-dimensional finite element model (FEM) was developed to simulate temperature distribution development in the soil surrounding the GHEs of GCHPs operating in the cooling and the heating modes. The finite element modelling of the GCHP system was performed using the ANSYS code. The FEM incorporated pipes, the grout and the surrounding formation. From the cases studied, this approach appears to be the most promising for estimation the temperature distribution response of GHEs to thermal loading.     

Penetration Depth in Nanoparticles Incorporated Radiofrequency Hyperthermia into the Tissue: Comprehensive Study with Histology and Pathology Observations

In present study, the effective penetration of radiofrequency (RF) induced gold decorated iron oxide nanoparticles (GS@IONPs) hyperthermia was investigated. The effective penetration depth of RF also the damage potency of hyperthermia was evaluated during histopathology observations which were done on the chicken breast tissue and hepatocellular carcinoma (HCC) models. The thermal damages are well‐ documented in our previous cellular study which was engaged with potency of RF hyperthermia in Epithelial adenocarcinoma (MCF‐7) and fibroblast (L‐929) cells deaths [1]. In recent work, PEGylated iron oxide nanoparticles (IONPs) were used as base platform for gold magnetic nanoparticles (GS@IONPs) formation. The 144.00015 MHz, 180W RF generator was applied for stimulating the nanoparticles. The chicken breast tissue and the hepatocellular tumor model was considered in the experimental section. In histology studies, the structural changes also the effective penetration depth of RF induced nanoparticles was observed through microscopic monitoring of the tissue slices in histology observations (Gazi medical school). The highest damage level was seen in 8.0 µm tissue slices where lower damages were seen in depth of 1.0 cm and more inside tissue. The histology observations clarified the effective penetration depth of RF waves and irreversible damages in the 2.0 cm inside the tissue.Inspec keywords: nanomedicine, tumours, biomedical materials, cellular biophysics, nanoparticles, gold, cancer, hyperthermia, magnetic particles, iron compounds, radiation therapyOther keywords: Au‐Fe₃ O₄ , depth 1.0 cm, depth 8.0 mum, power 180.0 W, size 2.0 cm, frequency 144.00015 MHz, microscopic monitoring, structural changes, hepatocellular tumour model, standing wave ratio, propylene glycol, thermal damages, hepatocellular carcinoma models, radiofrequency hyperthermia, nanoparticle dispersion, tissue alterations, modified tissues, gold shell magnetic nanoparticles, chicken breast tissue, gold‐coated iron oxide nanoparticles, pathology observations, effective penetration depth, histology observations, tissue slices     

Modeling a ground-coupled heat pump system by a support vector machine

This paper reports on a modeling study of ground coupled heat pump (GCHP) system performance (COP) by using a support vector machine (SVM) method. A GCHP system is a multi-variable system that is hard to model by conventional methods. As regards the SVM, it has a superior capability for generalization, and this capability is independent of the dimensionality of the input data. In this study, a SVM based method was intended to adopt GCHP system for efficient modeling. The Lin-kernel SVM method was quite efficient in modeling purposes and did not require a pre-knowledge about the system. The performance of the proposed methodology was evaluated by using several statistical validation parameters. It is found that the root-mean squared (RMS) value is 0.002722, the coefficient of multiple determinations (R²) value is 0.999999, coefficient of variation (cov) value is 0.077295, and mean error function (MEF) value is 0.507437 for the proposed Lin-kernel SVM method. The optimum parameters of the SVM method were determined by using a greedy search algorithm. This search algorithm was effective for obtaining the optimum parameters.The simulation results show that the SVM is a good method for prediction of the COP of the GCHP system. The computation of SVM model is faster compared with other machine learning techniques (artificial neural networks (ANN) and adaptive neuro-fuzzy inference system (ANFIS)); because there are fewer free parameters and only support vectors (only a fraction of all data) are used in the generalization process.