Gel permeation chromatography: Automatic data acquisition and reduction in real-time with a process computer

A real-time computer system is described which minimizes the total analysis time in gel permeation chromatography by automatically acquiring the data, performing the necessary calculations and displaying the molecular weight distribution and molecular weight averages as soon as the polymer peak has eluted. The calculation method described here is valid for linear homopolymers only, and does not include corrections for instrumental peak broadening. The experimental results show good reproducibility and precision. On-line changes of the constants and other parameters may be implemented by means of an auxiliary program which runs in parallel with the data analysis program. A system such as that described here is suitable for utilization as a measurement technique in process control applications. The programs are written in CORAL 66 for a Ferranti Argus 700 E computer.     

The contact of elastic regular wavy surfaces

A complete solution in closed form to the elastic contact of a one-dimensional sinusoidal surface with a flat surface was presented by Westergaard in 1939. This paper is concerned with the elastic contact of a two-dimensional sinusoidal surface with a flat. In this case the stress distribution within the elastic solids is three-dimensional. As the load is increased the contact areas change in shape from being circular to square and finally leave a circular region of no contact when the waves are almost squashed flat. The problem is solved in general using a numerical method due to Kalker, but asymptotic solutions in closed form have been found for light loads and also for heavy loads at which contact is almost complete. The variation of the mean separation with load, which determines the volume of the space trapped between the two surfaces, is also found.     

Optimal ensemble construction via meta-evolutionary ensembles

In this paper, we propose a meta-evolutionary approach to improve on the performance of individual classifiers. In the proposed system, individual classifiers evolve, competing to correctly classify test points, and are given extra rewards for getting difficult points right. Ensembles consisting of multiple classifiers also compete for member classifiers, and are rewarded based on their predictive performance. In this way we aim to build small-sized optimal ensembles rather than form large-sized ensembles of individually-optimized classifiers. Experimental results on 15 data sets suggest that our algorithms can generate ensembles that are more effective than single classifiers and traditional ensemble methods.     

Admiral John A. B. Dahlgren (1809–1870): His life, times and technical work in U.S. naval ordnance

John Dahlgren served in the U.S. Navy for nearly 35 years, sometimes in a sea-keeping capacity but mostly developing large naval artillery. To-day, his name, when recognised by students of naval ordnance, is associated with teh Dahlgren or ‘soda bottle shaped’ gun of 9 to 11 inch calibre. He designed, developed and lived to see his guns installed aboard warships and used to considerable effect, especially in the American Civil War. However, a nearly indistinguishable external design of gun was developed for the Army by T. J. Rodman, an officer now even less known than Dahlgren and whose researches and contributions are virtually forgotten. This paper and that in Ref. [1] attempt to appreciate (along with other technical questions of the period) the different ways pursued by these men towards the final development of the ‘soda bottle shaped’ gun, though it is a matter still not entirely understood.

Both names are totally omitted from several ‘classic’ books on artillery and this is a grave misfortune. Besides trying to throw factual light on the Dahlgren-Rodman controversy and the priority issue (though not one pursued with acrimony by the men themselves at the time), the paper describes Admiral Dahlgren's general career, the books he wrote, the technical problems he attacked and the problematic ordnance discussions of his day, to which he gave his life.

The work of Dahlgren and Rodman, in particular, saw the elevation of American gun design from the level of mere copying (of early Columbiads in the first decades of the century) to that which compelled attention from, and study by, the super-powers of the day, Great Britain, France and Russia.     

Current and future water issues in the Oldman River Basin of Alberta, Canada.

Long-term trends in alpine and prairie snow pack accumulation and melt are affecting streamflow within the Oldman River Basin in southern Alberta, Canada. Unchecked rural and urban development also has contributed to changes in water quality, including enhanced microbial populations and increased waterborne pathogen occurrence. In this study we look at changing environment within the Oldman River Basin and its impact on water quality and quantity. The cumulative effects include a decline in net water supplies, and declining quality resulting in increased risk of disease. Our data indicates that decreases in the rate of flow of water can result in sedimentation of bacterial contaminants within the water column. Water for ecosystems, urban consumption, recreation and distribution through irrigation is often drawn from waterholding facilities such as dams and weirs, and concern must be expressed over the potential for contaminate build-up and disproportionate potential of these structures to pose a risk to human and animal health. With disruption of natural flow rates for water resulting from environmental change such as global warming and/or human intervention, increased attention needs to be paid to use of best management practices to protect source water supplies.     

Origin and practical significance of the sticky dough factor in 1BL/1RS wheats

When translocated into wheat, the short arm of the 1R chromosome of rye carries with it linked resistance genes to powdery mildew, stripe rust, leaf rust and stem rust. The translocation is also reported to increase yield potential of hard wheats. However, many doughs made from some 1BL/1RS hard wheats are unacceptable for breadmaking purposes because of excessive stickiness and mixing intolerance. 1BL/1RS wheats may be sticky because of: the inheritance of secalin proteins from rye and absence of key glutenin subunits; higher amounts and/or differences in the composition of cell wall polysaccharides, β‐glucans and pentosans; and/or the presence of a ferulic acid ester moiety residing with the water‐soluble fraction of 1BL/1RS flours. None of these hypotheses has been proven or disproven, to date, as a cause of excessive stickiness. Investigators have found that 1BL/1RS doughs are not uniformly sticky and are in some instances less sticky than non‐1BL/1RS doughs. Significant genotype–environment interactions have been reported for dough stickiness and flour quality characteristics of 1BL/1RS wheats. Investigators have generally failed to find significant differences in the breadmaking performance of 1BL/1RS and non‐1BL/1RS hard wheats despite a report that 1BL/1RS doughs break down and soften during high‐speed mixing. The 1BL/1RS translocation has been shown to reduce cookie spread of soft wheat flours but has no deleterious effects on cake volume or texture. © 2002 Society of Chemical Industry