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111.
Rachel Passos de Oliveira Santos Daniele Oliveira Castro Adhemar Coll Ruvolo‐Filho Elisabete Frollini 《应用聚合物科学杂志》2014,131(12)
This investigation focuses on the preparation of bio‐based composites from recycled poly (ethylene terephthalate) (PET) and sisal fibers (3 cm, 15 wt %), via thermopressing process. Plasticizers derived from renewable raw materials are used, namely, glycerol, tributyl citrate (TBC) and castor oil (CO), to decrease the melting point of the recycled PET (Tm ∼ 265°C), which is sufficiently high to initiate the thermal decomposition of the lignocellulosic fiber. All used materials are characterized by thermogravimetric analysis and differential scanning calorimetry, and the composites are also characterized via dynamic mechanical thermal analysis. The storage modulus (30°C) and the tan δ peak values of CT [PET/sisal/TBC] indicate that TBC also acts as a compatibilizing agent at the interface fiber/PET, as well as a plasticizer. To compare different processing methods, rheometry/thermopressing and compression molding are used to prepare the recycled PET/sisal/glycerol/CO composites. These two different methods of processing show no significant influence on the thermal properties of these composites. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40386. 相似文献
112.
113.
Wright Kathleen M.; Cabrera Oscar A.; Bliese Paul D.; Adler Amy B.; Hoge Charles W.; Castro Carl A. 《Canadian Metallurgical Quarterly》2009,6(2):108
The present study examined the effects of leadership and unit cohesion on mental health stigma and perceived barriers to care. A sample of 680 soldiers from combat support units were surveyed 3 months after their return from combat operations in Iraq. The survey included scales on psychological symptoms and perceptions of leader behaviors and unit cohesion, as well as items assessing stigma and barriers to care. The sample was used to test the independent and interactive effects of leadership and unit cohesion on soldiers’ perceptions of stigma and barriers to care. Analyses yielded significant interaction effects between leadership and cohesion in predicting stigma and barriers to care, while controlling for the effects of mental health symptoms. Soldiers who rated their leaders more highly and who reported higher unit cohesion also reported lower scores on both stigma and perceived barriers to care. Thus, positive leadership and unit cohesion can reduce perceptions of stigma and barriers to care, even after accounting for the relationship between mental health symptoms and these outcomes. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
114.
Tíffany Marín Daniela Ortega Paula Montoya Oscar Arnache Jorge Calderón 《Journal of Applied Electrochemistry》2014,44(12):1401-1410
This paper shows how magnetic nanoparticles are produced by electrochemical synthesis using a low carbon steel bar as an anode and 100 mA cm?2 electric perturbations at room temperature. Two different kinds of salts, (CH3)4NCl and NaCl, were used to prepare the supporting electrolyte solutions. This allowed a comparison to be made between a surfactant and common salt, and allowed their influence on particle size to be analyzed. Additionally, mixtures of water and ethanol were added to the electrolyte solution in order to improve particle size distribution. The nanoparticle samples were characterized by X-ray diffraction, TEM, magnetization measurements, and Raman and Mössbauer spectroscopy. The results showed that after an optimized time of 10 min, the nanoparticles obtained in all the evaluated electrolytes were mainly magnetite (Fe3O4). The particles were between 8 and 10 nm in size. Depending on the nature of the electrolyte, the magnetite nanoparticles exhibited high purity and stoichiometry. The presence of ethanol in the electrolyte avoided particle agglomeration during the formation of magnetite. When the magnetic nanoparticles were exposed to an external magnetic field they showed superparamagnetic behavior and negligible coercivity. Such qualities are extremely useful for applications like ferrofluid precursors. 相似文献
115.
Current advances in the non‐chromatographic fractionation and characterization of PEGylated proteins
Oscar Aguilar Jorge Benavides Marco Rito‐Palomares 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2011,86(1):18-25
For more than 30 years, PEGylation has been used to improve the physicochemical properties of several proteins and therapeutic drugs having a major impact in the biopharmaceutical industry. The purification of PEGylated proteins usually involves two basic challenges: (1) the separation of PEG‐proteins from other reaction products; and (2) the sub‐fractionation of PEG‐proteins on the basis of their degree of PEGylation and positional isomerism. Currently, most PEGylated protein purification processes are based on chromatographic techniques, especially size exclusion chromatography (SEC) and ion exchange chromatography (IEX). Nonetheless, other less frequently used strategies based on non‐chromatographic techniques such as ultrafiltration, electrophoresis, capillary electrophoresis, and aqueous two‐phase systems have been developed in order to fractionate and analyze PEGylated derivates. This review presents current advances in some of the most widely used non‐chromatographic strategies for the fractionation and analysis of PEG‐protein conjugates. Copyright © 2010 Society of Chemical Industry 相似文献
116.
Oscar Björklund Alexander GovikLarsgunnar Nilsson 《Journal of Materials Processing Technology》2014,214(11):2748-2758
In this work, selected fracture criteria are applied to predict the fracture of dual-phase steel subjected to non-linear strain paths. Furthermore, the effects of manufacturing history are studied. Four fracture criteria were calibrated in three tests using standard specimens. The fracture criteria were first validated in the circular Nakajima test. A second validation test case was included in order to validate fracture prediction for non-linear strain paths. In this test a sheet metal component was manufactured and subsequently stretched until it fractured. All fracture criteria included in this study predict fracture during the Nakajima test with reasonable accuracy. In the second validation test however, the different fracture criteria show considerable diversity in accumulated damage during manufacturing which caused substantial scatter of the fracture prediction in the subsequent stretching. This shows that manufacturing history influences the prediction of fracture. 相似文献
117.
Luca Consolini Oscar Gerelli Corrado Guarino Lo Bianco Aurelio Piazzi 《Mechatronics》2009,19(3):348-356
The paper proposes a linear programming approach to the feed-forward minimum-time control of flexible joints. Taking into account both input and output constraints, the optimal bang–bang control is computed by discretizing a continuous-time joint model and by solving a sequence of linear programming feasibility problems. The resulting joint motion is a smooth rest-to-rest motion without oscillations. Theoretical analysis is presented and proof of convergence is given. Experimental results illustrate the proposed open-loop technique. Comparisons are made with inversion-based techniques. 相似文献
118.
Aliphatic [n]‐polyurethanes have recently been synthesized from ω‐isocyanato‐α‐alkanols or, more traditionally, by cationic ring‐opening polymerization of cyclourethanes or by the Bu2Sn(OMe)2‐promoted polycondensation of ω‐hydroxy‐α‐O‐phenylurethane alkanes. For the latter procedures, the conditions employed do not seem to be suitable for highly functionalized monomers. In contrast, the polymerization of ω‐amino‐α‐phenylcarbonate alkanes is expected to occur under milder conditions. ω‐Amino‐α‐phenylcarbonate alkanes have been synthesized from 6‐aminohexanol (1) and 3‐aminopropanol (6). The procedure involves the N‐Boc protection of the amino group, followed by activation of the alcohol. Removal of the N‐Boc affords the corresponding ω‐amino‐1‐O‐phenyloxycarbonyloxyalkane hydrochlorides. Other oligomeric comonomers between 1 and 6 have been prepared. The polymerization of these precursors takes place in the absence of metal catalysts to afford the corresponding linear and regioregular [n]‐polyurethanes. The procedure described is useful for the preparation of stable ω‐amino‐α‐phenylcarbonate alkane derivatives, which possess varied chain lengths between the terminal functions. These monomers yield [n]‐polyurethanes having various structures starting from just two aminoalkanols. The polyurethanes were obtained in high yields, with reasonable molecular weight and polydispersity values, and they were characterized spectroscopically and thermally. These studies reveal constitutionally uniform structures that are free of carbonate or urea linkages. Copyright © 2010 Society of Chemical Industry 相似文献
119.
Oscar Pieiro Carlos Fernndez Mercedes Medrano Macarena Liniers Jose Botija Javier Alonso Xabier Sarasola Carlo Damiani 《Fusion Engineering and Design》2009,84(7-11):1515-1520
The maintenance operations of ITER NB components inside the vessel - Beam Line Components (BLC's) involve the removal of the faulty component, its transport to the hot cell as well as the reverse operations of transport of the repaired/new component and its reinstallation inside the vessel. Prior to the removal of the BLC's the cooling pipes must be detached from the component following a procedure that applies to the cutting of the pipes and subsequent welding when the component is re-installed. The purpose of this study, conducted in the framework of EFDA, is to demonstrate the feasibility of the cut and weld operations on the water pipes of the BLC's using fully remote handling techniques. Viable technologies for the cut and weld operations have been identified within the study; in particular the following aspects will be presented in the paper:
- • Different strategies can be pursued in the detachment of the components depending on the number of cut and weld operations to be performed on the pipes. The selected strategy will impact on the procedure to be followed likewise on important aspects as the requirements of the flexible joints assembled on the pipes.
- • The existing cutting techniques have been examined in the light of the remotely performed pipe cutting at the NB cell. Modifications of commercial tools have been proposed in order to adapt them to the BLC's pipes requirements. The debris produced during the cutting process must be controlled and collected, therefore a cleaning system has been integrated in the adapted cutting tool referred above.
- • The existing welding techniques have been also examined and compared based on different criteria such as complexity, reliability, alignment tolerances, etc. TIG welding is the preferred technique as it stands out for its superior performance. The commercial tools identified need to be adapted to the NB environment.
- • The alignment of the pipes is a critical issue concerning the remote welding. A proper alignment system has been proposed taking into account the pre-selected welding technique.
Keywords: Remote handling; NBI; Cut and weld 相似文献
120.
Geraldo Lúcio Tiago Filho Camila Rocha Galhardo Adriana de Cássia Barbosa Regina Mambeli Barros Fernando das Graças Braga da Silva 《Energy Policy》2011
This article presents the main regulatory changes that occurred in the Brazilian power sector in 2009, along with the impacts these changes caused on the market, especially related to small hydropower (<30 MW). This study addresses regulatory issues based on inventory studies and records of basic projects, changes related to the compensation of the assured energy of SHPs in the Brazilian energy reallocation market, the socio-economic impact resulting from the construction of SHPs, SHPs in alternative resource auctions and finally the general outlook for the growth scenario for SHPs in Brazil according to the ten-year plan (2010–2019). The overall conclusions of this investigation were that the 2008/2009 biennium was a period of great changes in the regulation of small hydropower plants in Brazil, and the SHP market has shown maturity. Additionally, despite SHP being a type of technology that is completely dominated by domestic industry, in recent years, they have experienced policy disincentives caused by changes to rules that inhibit their growth. 相似文献