Synthesis,characterization, and thermal and antimicrobial studies of newly developed transition metal–polychelates derived from polymeric Schiff base

Monomeric Schiff base derived from salicylaldehyde and 1,3‐diaminopropane was subjected to polycondensation reaction with formaldehyde and piperazine in basic medium. The resin was found to form polychelates readily with Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) metal ions. The materials were characterized by elemental analysis, spectral studies (IR, ¹H‐NMR, ¹³C‐NMR, and UV–visible), magnetic moment measurements, and thermal analysis. The electronic spectra and magnetic moment measurements of the synthesized polychelates confirmed the geometry of the central metal ion. Metal–resin bonds were registered in the IR spectra of the polychelates. The thermogravimetric analysis data indicated that the polychelates were more stable than the corresponding polymeric Schiff base. All the synthesized metal–polychelates showed excellent antibacterial activities against the selected bacteria. The antimicrobial activities were determined by using the shaking flask method, where 25 mg/mL concentrations of each compound were tested against 10⁵ CFU/mL bacteria solutions. The number of viable bacteria was calculated by using the spread‐plate method, where 100 μL of the incubated antimicrobial agent in bacteria solutions were spread on agar plates, and the number of bacteria was counted after 24 h of incubation period at 37°C. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Spinodal Decomposition in Tellurite-Based Glasses Induced by Excimer Laser Irradiation

Tellurite-based glasses in the TeO₂–K₃Li₂Nb₅O₁₅, TeO₂–Ba₅Li₂Ti₂Nb₈O₃₀, and V₂Te₂O₉ were fabricated by the conventional melt-quenching technique. Amorphous and glassy characteristics of the as-quenched samples were established via the X-ray powder diffraction technique and differential thermal analysis, respectively. The as-quenched samples were irradiated by an excimer laser (248 nm). The effect of laser power, duration of irradiation, and the frequency of the laser pulses on the surface features of the above glasses were studied. The optical microscopic studies carried out on the above systems revealed the presence of quasi-periodic and periodic structures on their surfaces. The local compositional variations of these structures were confirmed by back-scattered electron imaging using scanning electron microscope accompanied by energy-dispersive X-ray analysis. These results were convincing enough to state that the glasses in the present investigations had undergone spinodal decomposition on laser irradiation. The incidence of the interconnected texture of two different phases was observed owing to the quenching effect produced by the heating and cooling cycle of the successive laser pulses. Ring- and line-shaped patterns were also observed, respectively, when the pulse frequency of the laser and the duration of irradiation were increased.     

Bis (benzimidazol-2-yl) disulphide: An efficient water soluble inhibitor for corrosion of mild steel in acid media

The inhibition effect of Bis (benzimidazol-2-yl) disulphide (BIMDS) on corrosion behavior of mild steel (MS) in 1.0 M HCl and 0.5 M H₂SO₄ was studied using different techniques. These studies have shown that studied compound is a good inhibitor for MS in 1.0 M HCl and 0.5 M H₂SO₄ solutions. Inhibitor showed better performance in 0.5 M H₂SO₄ solutions than 1.0 M HCl. Polarization measurements indicated that BIMDS is a mixed-type inhibitor in both acid media. Adsorption of inhibitor molecules on the mild steel surface showed Langmuir isotherm model in both acid media.     

Optimizing vote and quorum assignments for reading and writingreplicated data

In the weighted voting protocol which is used to maintain the consistency of replicated data, the availability of the data to ready and write operations not only depends on the availability of the nodes storing the data but also on the vote and quorum assignments used. The authors consider the problem of determining the vote and quorum assignments that yield the best performance in a distributed system where node availabilities can be different and the mix of the read and write operations is arbitrary. The optimal vote and quorum assignments depend not only on the system parameters, such as node availability and operation mix, but also on the performance measure. The authors present an enumeration algorithm that can be used to find the vote and quorum assignments that need to be considered for achieving optimal performance. When the performance measure is data availability, an analytical method is derived to evaluate it for any vote and quorum assignment. This method and the enumeration algorithm are used to find the optimal vote and quorum assignment for several systems. The enumeration algorithm can also be used to obtain the optimal performance when other measures are considered     

Resource finding in store-and-forward networks

We present a model of searching for a resource in a distributed system whose nodes are connected through a store-and-forward network. Based on this model, we show a lower bound on the number of messages needed to find a resource when nothing is known about the nodes that have the current location of the resource. The model also helps us to establish results about the time complexity of determining a message optimal resource finding algorithm when the probability distribution for the location of the resource in the network is known. We show that the optimization problem is NP-hard for general networks. Finally we show that optimal resource finding algorithms can be determined in polynomial time for a class of tree networks and bidirectional rings. The polynomial algorithms can be used as a basis of heuristic algorithms for general networks.This work was supported in part by NSF grants CCR-8806358 and NCR-8604850     

Countering security information overload through alert and packet visualization

This article presents a framework for designing network security visualization systems as well as results from the end-to-end design and implementation of two highly interactive systems. In this article, we provide multiple contributions: we present the results of our survey of security professionals, the design framework, and lessons learned from the design of our systems as well as an evaluation of their effectiveness. Our results indicate that both systems effectively present significantly more information when compared to traditional textual approaches. We believe that the interactive, graphical techniques that we present will have broad applications in other domains seeking to deal with information overload.     

THE EFFECT OF ENVIRONMENTALLY BENIGN FRUIT EXTRACT OF SHAHJAN (MORINGA OLEIFERA) ON THE CORROSION OF MILD STEEL IN HYDROCHLORIC ACID SOLUTION

The inhibition of the corrosion of mild steel in hydrochloric acid solution by the fruit extract of shahjan (Moringa oleifera) was studied using weight loss, electrochemical impedance spectroscopy (EIS), linear polarization, and potentiodynamic polarization techniques (Tafel). Inhibition was found to increase with increasing concentration of the extract. The effect of temperature, immersion time, and acid concentration on the corrosion behavior of mild steel in hydrochloric acid solutions with addition of extract was also studied. The inhibition occurred via adsorption of the inhibitor molecules on the mild steel surface obeying the Langmuir adsorption isotherm. Thermodynamic activation parameters such as activation energy, enthalpy (ΔH*), and entropy (ΔS*) of activation for corrosion process were calculated and discussed. The results obtained show that both chemical and physical adsorption of inhibitor molecules occur simultaneously and the fruit extract of shahjan (Moringa oleifera) could serve as an effective inhibitor of the corrosion of mild steel in hydrochloric acid media.     

Scalable consistency protocols for distributed services

A common way to address scalability requirements of distributed services is to employ server replication and client caching of objects that encapsulate the service state. The performance of such a system could depend very much on the protocol implemented by the system to maintain consistency among object copies. We explore scalable consistency protocols that never require synchronization and communication between all nodes that have copies of related objects. We achieve this by developing a novel approach called local consistency (LC). LC based protocols can provide increased flexibility and efficiency by allowing nodes control over how and when they become aware of updates to cached objects. We develop two protocols for implementing strong consistency using this approach and demonstrate that they scale better than a traditional invalidation based consistency protocol along the system load and geographic distribution dimensions of scale     

Plausible clocks: constant size logical clocks for distributed systems

Summary. In a Distributed System with N sites, the precise detection of causal relationships between events can only be done with vector clocks of size N. This gives rise to scalability and efficiency problems for logical clocks that can be used to order events accurately. In this paper we propose a class of logical clocks called plausible clocks that can be implemented with a number of components not affected by the size of the system and yet they provide good ordering accuracy. We develop rules to combine plausible clocks to produce more accurate clocks. Several examples of plausible clocks and their combination are presented. Using a simulation model, we evaluate the performance of these clocks. We also present examples of applications where constant size clocks can be used. Received: January 1997 / Accepted: January 1999     

CoSe2@N-Doped Graphene Nanocomposite High-Efficiency Counter Electrode for Dye-Sensitized Solar Cells

Journal of Inorganic and Organometallic Polymers and Materials - In present study, CoSe2, and CoSe2@N-doped graphene nanocomposite has been prepared in an inert atmosphere and used as a DSSC...