Investigation on hydrophilicity of micro-arc oxidized TiO2 nano/micro-porous layers

Titania porous layers with a rough surface were synthesized via micro-arc oxidation (MAO) and the effect of the applied voltage and electrolyte concentration on surface structure, and chemical composition of the layers was studied. Morphological and topographical investigations, performed by SEM and AFM, revealed that pore size and surface roughness of the layers increased with the applied voltage and the electrolyte concentration. Based on the XRD and XPS results, the grown layers consisted of anatase and rutile phases with varying fractions depending on growth conditions. It was found that anatase/rutile relative content reached its maximum value at medium applied voltages or electrolyte concentrations. Finally, hydrophilicity of the grown layers was determined using a water contact angle apparatus, and a correlation between measured contact angles and MAO-parameters was suggested. It was observed that the layers synthesized under the applied voltage of 400 V in the electrolytes with a concentration of 10 g l⁻¹ exhibited the highest hydrophilicity.     

Senior managers’ perception on green information systems (IS) adoption and environmental performance: Results from a field survey

Based on a Belief-Action-Outcome framework, we produced a model that shows senior managers’ perception of both the antecedents to and the consequences of Green IS adoption by a firm. This conceptual model and its associated hypotheses were empirically tested using a dataset generated from a survey of 405 organizations. The results suggest that coercive pressure influences the attitude toward Green IS adoption while mimetic pressure does not. In addition, we found that there was a significant relationship between Green IS adoption, attitude, and consideration of future consequences. Finally, we found that only long term Green IS adoption was positively related to environmental performance.     

Green information systems use in social enterprise: the case of a community-led eco-localization website in the West Midlands region of the UK

This study examines the intention of environmentally-oriented social enterprises to continue using Green IS (an eco-localization website here) in Herefordshire located in the West Midlands region of the United Kingdom. The Herefordshire Greenlinks (HGL) Association is a local business community that operates primarily through the HGL Website in order to help local social enterprises find and trade local eco-friendly goods and services. It is an example of a “market-based” approach to solving social and environmental issues that is inspired by a bottom-up view of community development and eco-localization. Based on the theory of uses and gratification of media use and the new environmental paradigm, we propose a research model that outlines the various factors contributing to intention to continue using an eco-localization website. The research model and its associated hypotheses were empirically tested using a dataset generated from a survey of 83 small social enterprises. The results demonstrate the importance of three different types of gratification – content, social and performance gratification as well as users’ environmental concerns in determining the intention to continue using an eco-localization website. This study contributes to the Green IS literature by extending research to the social sector environment, and it also provides practical insight for designers of such community-led eco-localization websites.     

Simultaneous determination of pyruvate and acetate levels in xanthan biopolymer by infrared spectroscopy: effect of spectral pre-processing for solid-state analysis

A rapid, direct, and reagent-free procedure based on solid-state Fourier transform infrared spectroscopy (FT-IR) coupled with partial least squares (PLS) data analysis has been developed for simultaneous determination of pyruvate and acetate levels in a microbial xanthan biopolymer. The influences of various spectral pre-processing procedures were studied in order to eliminate effects caused by sample preparation. It was determined that the combination of first derivative and orthogonal signal correction pre-processing contributes to a significant increase in the predictive performance of PLS-1 regression models. By employing the wavenumber region 1320–1350 cm⁻¹ for pyruvate determination and 1500–1600 cm⁻¹ for acetate determination, the root mean square error of cross-validation (RMSECV) for pyruvate and acetate contents were obtained 0.13% and 0.29% w/w, respectively. Results of the proposed procedure for different real samples and those obtained by their reference methods were compared.     

Effect of temperature on in-use stiction of cantilever beams coated with perfluorinated alkysiloxane monolayers

The effect of annealing (for temperatures up to 300 /spl deg/C) on the antistiction performance of perfluorinated self-assembled monolayers (SAMs) is characterized using polycrystalline Si cantilever beam arrays. The monolayers 1H,1H,2H,2H, perfluorodecyltrichlorosilane (FDTS) and 1H,1H,2H,2H, perfluorodecyldimethylchlorosilane (FDDMCS) deposited from both liquid and vapor phase are investigated. It is observed that stiction decreases upon annealing for both monolayers and for both types of deposition. FDTS, however, displays greater temperature stability than FDDMCS regardless of the mode of deposition. The higher thermal resistance of the FDTS underscores the importance of monolayer crosslinking since unlike FDDMCS, FDTS forms a siloxane network on the surface. Further vacuum annealing and X-ray photoelectron spectroscopy experiments are performed to identify chemical changes in the monolayer during annealing. Incipient monolayer degradation is observed, with loss of the whole fluorinated monolayer chain. This process appears drastically different from the decomposition mechanism of hydrogenated alkylsiloxane monolayers such as octadecyltrichlorosilane (OTS).     

Recent progress toward a manufacturable polycrystalline SiC surface micromachining technology

In this paper, we present results of recent research from our laboratory directed toward a manufacturable SiC surface micromachining technology for microelectromechanical systems (MEMS) applications. These include the development of a low-pressure chemical vapor deposition and in situ doping processes for silicon carbide (SiC) films at relatively low temperatures, as well as the development of selective dry etching processes for SiC using nonmetallic masking materials. Doped polycrystalline SiC films are deposited at 800/spl deg/C by using a precursor 1,3-disilabutane and dopant gas NH/sub 3/, with the minimum resistivity of 26 m/spl Omega//spl middot/cm. Dry etching for SiC and its selectivity toward silicon dioxide and silicon nitride masking materials are investigated using SF/sub 6//O/sub 2/, HBr, and HBr/Cl/sub 2/ transformer coupled plasmas. The etch rate, etch selectivity, and etch profile are characterized and compared for each etch chemistry. By combining the LPCVD and dry etching process with conventional microfabrication technologies, a multiuser SiC MEMS process is developed.     

Additives to prevent the formation of surface defects during poly(vinyl chloride) calendering

Gas checks are visible fleck-shaped defects that occur on the surface of poly(vinyl chloride) (PVC) films during industrial calendering. Films containing these surface defects often do not meet minimum product specifications and therefore must be disposed of or recycled, resulting in increased cost and material waste. Currently, gas checks are controlled by keeping film gauge low and through trial-and-error modifications of processing parameters by calender operators. In this work, our group developed a series of chemical additives that can be blended with PVC to prevent the formation of gas check defects. We found that a series of poly(caprolactone) (PCL)-based compounds with diester linkers and alkyl chain cappers were all effective at preventing the formation of gas checks during calendering, with additive concentrations as low as 8 phr producing films with no gas checks. We found that the blends produced with our additives had higher melt viscosities than those produced with additives that do not remove gas checks, suggesting that viscosity plays an important role in preventing gas check defects.     

Removal of toxic nitrate ions from drinking water using conducting polymer/MWCNTs nanocomposites

New application of conducting polymers as stable nanocomposites for nitrate ion exchange materials in water and wastewater treatment and for environmental protection is introduced in this work. The nanocomposites of multi-walled carbon nanotubes (MWCNTs) with different polymers such as: polyaniline (PANI), polypyrrole (PPY), poly(1,8-diaminonaphthalene) [P(1,8-DAN)] and poly(2-vinylpyridine) (P2VP) were synthesized with different dopants as effective and reusable nanocomposites for nitrate removal from drinking water. Nitrate anions at toxic concentrations were removed from water using ion exchange mechanism without any toxic byproducts. The obtained results demonstrate that effective ion exchange occurs between NO₃ ^? and Cl^?. There are some protonated heteroatoms in polymer chains that are bonded with anions of dopants and their counter ions in nanocomposites. These dopant anions on the =NH⁺– groups of polymers can be exchanged with NO₃ ^? in water. Adsorption of NO₃ ^? on polymer/MWCNTs nanocomposites showed dependency to some parameters. Different experimental parameters such as pH and temperature of the sample, polymers dopant, and the ratio of polymer to MWCNTs in nanocomposites affect the amount of nitrate removal. The highest removal efficiency was achieved at 1.20 g L^?1 of PANI/MWCNTs (3:1) nanocomposite, pH = 6.5 and ambient temperature. After five successive cycles of nitrate removal, this parameter was still up to 70 % compared to the first run (up to 80 %).