Effect of the ZrO<Subscript>2</Subscript> concentration on the crystallization behavior and the mechanical properties of high-strength MgO–Al<Subscript>2</Subscript>O<Subscript>3</Subscript>–SiO<Subscript>2</Subscript> glass–ceramics

High-strength, colorless glass–ceramics in the MgO/Al₂O₃/SiO₂ system with high concentrations of ZrO₂ and a great potential for technical application, e.g., as high-performance hard disc substrates, are investigated. ZrO₂ concentrations from 6 to 9 mol% are added to a stoichiometric cordierite glass to investigate the influence of the concentration of the nucleating agent on the crystallization behavior and the mechanical properties. The phase formation and the microstructure of the glass–ceramics are studied using X-ray diffraction and scanning electron microscopy including electron backscatter diffraction. It is shown that the volume crystallization of ZrO₂, a low-/high-quartz solid solution (low-/high-QSS), and spinel is accompanied by the surface crystallization of indialite. This phase offers a much smaller coefficient of thermal expansion than the other crystal phases, which may induce high compressive stresses in the surface layer of the glass–ceramics after cooling and seems to result in excellent mechanical properties of the material. Biaxial flexural strengths of up to 1 GPa were measured. Higher ZrO₂ concentrations reduce the surface crystallization of indialite and decrease the mean size of the crystals resulting in a higher translucency. The volume-crystallizing phases and the mechanical properties of the glass–ceramics do not seem to be significantly affected by the analyzed ZrO₂ concentrations.     

Stimulated Transitions of Directed Nonequilibrium Self‐Assemblies

Near‐equilibrium stimulus‐responsive polymers have been used extensively to introduce morphological variations in dependence of adaptable conditions. Far‐less‐well studied are triggered transformations at constant conditions. These require the involvement of metastable states, which are either able to approach the equilibrium state after deviation from metastability or can be frozen on returning from nonequilibrium to equilibrium. Such functional nonequilibrium macromolecular systems hold great promise for on‐demand transformations, which result in substantial changes in their material properties, as seen for triggered gelations. Herein, a diblock copolymer system consisting of a hydrophilic block and a block that is responsive to both pressure and temperature, is introduced. This species demonstrates various micellar transformations upon leaving equilibrium/nonequilibrium states, which are triggered by a temperature deflection or a temporary application of hydrostatic pressure.     

Fracture toughness characterisation of a glass fibre‐reinforced plastic composite

By examining the state of the art, it can be realised that few research works have been done on the fracture behaviour of plastic composites reinforced with continuous glass fibres. Therefore, the present paper deals with the fracture toughness of a unidirectional glass fibre‐reinforced plastic (GFRP), such a parameter being analytically determined by means of the modified two‐parameter model (MTPM). The input data of the MTPM are obtained from an experimental campaign related to three‐point bending tests on single edge‐notched specimens characterised by different sizes. The novelty of this research work is that the MTPM, originally proposed for isotropic materials, is here employed to estimate the fracture toughness of GFRPs characterised by orthotropic mechanical properties.     

A new inhomogeneous partially reflecting surface for Fabry‐Perot antenna to reduce side lobe level

In this article, an extension of the spatial filter method to study Fabry‐Perot antennas with homogeneous or inhomogeneous partially reflecting surface (PRS) of finite size is proposed. This tool was subsequently validated through the study of different Fabry‐Perot antennas, with homogeneous PRS and inhomogeneous GRadient‐INdex (GRIN) PRS that present very high side lobe level (SLL). Since they are due to structure truncation, a new inhomogeneous PRS to reduce the SLL is designed with the new analytical tool. The new inhomogeneous PRS for Fabry‐Perot antenna is characterized by simulations and measurements. Compared to the homogeneous PRS antenna, the proposed PRS allows a SLL reduction of 5 dB without decreasing the 14 dBi directivity.     

Broadband Forward Light Scattering by Architectural Design of Core–Shell Silicon Particles

A goal in the field of nanoscale optics is the fabrication of nanostructures with strong directional light scattering at visible frequencies. Here, the synthesis of Mie-resonant core–shell particles with overlapping electric and magnetic dipole resonances in the visible spectrum is demonstrated. The core consists of silicon surrounded by a lower index silicon oxynitride (SiO_xN_y) shell of an adjustable thickness. Optical spectroscopies coupled to Mie theory calculations give the first experimental evidence that the relative position and intensity of the magnetic and electric dipole resonances are tuned by changing the core–shell architecture. Specifically, coating a high-index particle with a low-index shell coalesces the dipoles, while maintaining a high scattering efficiency, thus generating broadband forward scattering. This synthetic strategy opens a route toward metamaterial fabrication with unprecedented control over visible light manipulation.     

Speech emotion recognition using optimized genetic algorithm-extreme learning machine

Multimedia Tools and Applications - Automatic Emotion Speech Recognition (ESR) is considered as an active research field in the Human-Computer Interface (HCI). Typically, the ESR system is...     

An Efficient Approach for Big Data Aggregation Mechanism in Heterogeneous Wireless Connected Sensor Networks

Recently and due to the impressive growth in the amounts of transmitted data over the heterogeneous sensor networks and the emerged related technologies especially the Internet of Things in which the number of the connected devices and the data consumption are remarkably growing, big data has emerged as a widely recognized trend and is increasingly being talked about. The term big data is not only about the volume of data, but also refers to the high speed of transmission and the wide variety of information that is difficult to collect, store and process using the available classical technologies. Although the generated data by the individual sensors may not appear to be significant, all the data generated through the many sensors in the connected sensor networks are able to produce large volumes of data. Big data management imposes additional constraints on the wireless sensor networks and especially on the data aggregation process, which represents one of the essential paradigms in wireless sensor networks. Data aggregation process can represent a solution to the problem of big data by allowing data from different sources to be combined to eliminate the redundant ones and consequently reduce the amounts of data and the consumption of the available resources in the network. The main objective of this work is to propose a new approach for supporting big data in the data aggregation process in heterogeneous wireless sensor networks. The proposed approach aims to reduce the data aggregation cost in terms of energy consumption by balancing the data loads on the heterogeneous nodes. The proposal is improved by integrating the feedback control closed loop to reinforce the balance of the data aggregation load on the nodes, maintaining therefore an optimal delay and aggregation time.

     

Sol–Gel Synthesis of λ–Na2O·xAl2O3 Films

Na₂O· x Al₂O₃ ( x = 9, 11)films have been obtained by sol–gel method. Crystallization processes during heat treatments have been investigated by X–ray diffraction analysis. A metastable phase with the mullite structure, λ–Na₂O· x Al₂O₃, has been observed starting from 800°C. Films remained stable after a heat treatment at 1000°C for 250 h. Impedance spectroscopy measurements showed that the films of λ-Na₂O· x Al₂O₃ possess a large three–dimensional ionic conductivity at 400°C.