Performance and emission study in manifold hydrogen injection with diesel as an ignition source for different start of injection

Over the past two decades there has been a considerable effort to develop and introduce alternative transportation fuels to replace conventional fuels, gasoline and diesel. Environmental issues are the principal driving forces behind this effort. To date the bulk of research has focused on the carbon-based fuels such as reformulated gasoline, methanol and natural gas. One alternative fuel to carbon-based fuels is hydrogen which is considered to be low polluting fuel. In the present experimental investigation hydrogen was injected into the intake manifold by using an injector. Using an electronic control unit (ECU) the injection timing and the duration were controlled. From the results it is observed that the optimum injection timing is at gas exchange top dead center (GTDC). The efficiency improved by about 15% with an increase in NO_X emission by 3% compared to diesel. The smoke emission decreased by almost 100%. A net reduction in carbon emissions was also noticed due to the use of hydrogen. By adopting manifold injection technique the hydrogen–diesel dual fuel engine operates smoothly with a significant improvement in performance and reduction in emissions.     

Corrosion behavior of Cr electrodeposited from Cr(VI) and Cr(III)-baths using direct (DCD) and pulse electrodeposition (PED) techniques

A comparison was made between the electrochemical corrosion behaviors of chromium deposited from hexavalent [Cr(VI)] and trivalent [Cr(III)] chromium baths using direct current (DCD) and pulse electro deposited (PED) techniques. Chromium coatings were deposited on mild-steel (MS) substrate. The corrosion behavior of both DCD and PED chromium from Cr(VI) and Cr(III)-baths in 3.5%NaCl solution was studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results indicated that PED chromium from Cr(VI) and Cr(III)-baths have higher charge-transfer resistance R_ct and very low I_corr than that of DCD chromium on mild-steel substrate.     

Surface chemistry and adsorption mechanism of cadmium ion on activated carbon derived from Garcinia mangostana shell

A detailed surface characterizations and adsorption mechanism of Cd²⁺ on chemical activated carbon (CAC) prepared from Garnicia mangostana shell were investigated. The activation is accomplished in self-generating atmosphere using phosphoric acid as activating agent. The characterizations performed are elemental analysis, functional group identification, N₂ adsorption isotherm and surface charges. Adsorption mechanism of metal ion was tested using Cd²⁺ as model ion. CAC achieved BET surface area of 1,498 m²/g with a mixture of micro and mesopores. The point of zero charge is observed to be at pH 2.8 and the optimum pH for Cd²⁺ adsorption on CAC is 12. The adsorption isotherm followed the Freundlich model, and the adsorption kinetics was explained by pseudo-second order kinetic model. From thermodynamic studies, the adsorption was found to be physical adsorption. X-ray photoelectron spectroscopy (XPS) confirmed the adsorption of Cd²⁺ onto CAC as +2 oxidation state.     

Experimental investigation on a DI dual fuel engine with hydrogen injection

Over the past two decades considerable efforts have been undertaken to develop and introduce new alternative fuels for the conventional gasoline and diesel. Many alternative fuels, both liquid and gaseous, have been experimented and some have even been commercialized such as ethanol, natural gas, etc. Hydrogen has been considered as an excellent fuel to replace the petroleum‐based fuels due to its clean burning characteristics. In the present experimental investigation, hydrogen was injected in the intake manifold and diesel fuel was injected inside the engine cylinder in the conventional manner. Hydrogen injection parameters such as injection timing, injection duration and quantity of hydrogen injected were optimized based on the performance and emission characteristics. Exhaust gas recirculation (EGR) technique was adopted to reduce the oxides of nitrogen emission. From the results it was observed that for hydrogen diesel dual fuel (DF) engine, the optimal operating parameters for hydrogen injection were start of injection at gas exchange top dead centre with injection duration of 30° crank angle with the hydrogen flow rate of 7.5 litres per minute (lpm). With EGR the optimized condition was found to be 20% for the entire load. The brake thermal efficiency with 20% EGR increases by 16% at 75% load as compared with diesel, while at full load it reduces by 8% due to the recirculation of exhaust gases that results in a reduction of intake oxygen concentration compared with part load. NO_X emission decreases by five and half times, while other emissions increase by 1.4 times as compared with DF engine. Copyright © 2008 John Wiley & Sons, Ltd.     

Polynorbornene/fluorosilica hybrids for hydrophobic and oleophobic coatings

Polynorbornene dicarboxylic anhydride (PNA)/fluorosilica hybrid coating materials with good hydrophobicity, oleophobicity, transparency, thermal stability, and hardness were synthesised using a sol–gel method. The surface structure, transparency, hydrophobicity, oleophobicity, and surface free energy of the coating could be controlled by adjusting the fluorosilane ratio. The maximum static water and oil contact angles of films were 112° and 87°, respectively. The PNA/fluorosilica hybrid films exhibited good transparency and colourlessness. The marks written using water and oil-based pens on the films could be erased with a tissue even after eight times. In addition, the hardness of the hybrid films was enhanced to 4H with increasing fluorosilane content.     

Simple synthesis of ZnS nanoparticles in alkaline medium

ZnS nanoparticles were successfully synthesized by reflux under an alkaline medium. The nanoparticles were characterized by using X-Ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The optical properties of ZnS nanoparticles were examined by photoluminescence (PL) spectrum. The result shows that the as-synthesized ZnS nanoparticles had a cubic phase. SEM image shows that ZnS nanoparticles are basically in spherical shape and are homogeneous. The particle size was found to be in the range of 18 nm.     

Evaluation of connection flexibility in cold formed steel racks

Steel storage racks are three-dimensional framed structures fabricated from cold formed steel sections, wherein hook-in end connectors are used to make beam-column connections which are basically boltless and semi-rigid in nature. Different types of beam end connectors with different geometry of the connected members are available, making it impossible to develop a generalized analytical model. Only very few theoretical models are available to evaluate the performance of the joints for some typical connectors. More often experimental evaluation and numerical studies are needed to predict the behaviour of every different type of connectors. In the present study eighteen experiments were conducted on a commercially available pallet rack connection by varying the most influencing parameters such as thickness of the column, depth of the connector and the depth of the beam. The main objective of this work is to quantify the beam to column joint, flexibility of commonly used pallet rack frame and to develop a general Frye-Morris type/three parameter power model type moment versus relative rotation relationship. A companion finite element shell model that simulates the experimental behaviour closely is developed using ABAQUS finite element software, which is also used for further parametric studies. Using the three major variables as size parameters, a Frye-Morris type of equation has been proposed. Some calibration studies have also been carried out. Using the ultimate moment capacity, initial connection stiffness and the shape parameter obtained, a three parameter power model has also been proposed to represent the moment-rotation behaviour of the boltless connections.     

Hydrogen Generation from CO2 Reforming of Biomass-Derived Methanol on Ni/SiO2 Catalyst

Topics in Catalysis - CO2 reforming of methanol for producing hydrogen was experimentally carried out in a fixed-bed reactor on 10%Ni/SiO2. The 10%Ni/SiO2 was completely reduced during H2...     

Effect of silane functionalized alumina on poly(vinyl butyral) nanocomposite films: Thermal,mechanical, and moisture barrier studies

In this work, a hybrid‐polymer nanocomposite film, based on polyvinyl butyral/amino‐silane functionalized nano alumina, was fabricated by melt processing. The calcium degradation measurements suggest the functionalized nanocomposite films exhibit higher resistance towards moisture penetration as compared to the neat alumina loaded films. Thermal stability, mechanical strength, and contact angle studies of the composites were also conducted to evaluate the performance of the functionalized alumina loaded films. These nanocomposite films were encapsulated over Al/P3HT/ITO Schottky structured device. The changes observed in the current density of the devices to the applied voltage before and after accelerated aging conditions are presented. The nanocomposite with functionalized alumina films exhibits 50% change in current density, which is superior to that attained with neat and non‐functionalized films. POLYM. COMPOS., 35:1426–1435, 2014. © 2013 Society of Plastics Engineers     

Natural convection in an enclosure with a localized nonuniform heat source on the bottom wall

Natural convection in an air filled enclosure with a localized nonuniform heat source mounted centrally on the bottom wall is numerically investigated. The vertical walls are cooled while the top wall and the remaining portions of the bottom wall are insulated. The heat source is assumed to be isothermal with a linearly varying temperature. The governing equations were solved using finite volume method on a uniformly staggered grid system. The computational results are presented in the form of isotherm and streamline plots and Nusselt numbers. The effects of the source nonuniformity parameter, λ and the line source length, ε are investigated for the Grashof numbers Gr = 10⁶ and 10⁷. It is found that for Gr = 10⁶ nonuniform heating of the line source enhances the overall heat transfer rate markedly compared to uniform heating of the heat source whereas for Gr = 10⁷ its effect is marginal.