DESORPTION OF ETHYL ACETATE-WATER MIXTURE BY USING CROSS-LINKED POLY(VINYLALCOHOL) MEMBRANE AND COMPARISON OF RESULTS WITH PERVAPORATION

In this study using poly(vinylalcohol) (PVOH) membranes cross-linked with tartaric acid (Tac) desorption experiments were performed for selected concentrations of binary ethyl acetate (EtAc)-water mixture at temperatures of 30°, 40°, and 50°C to determine sorption of components. Sorption values measured were compared with those estimated by the Flory-Huggins approach. Additionally, desorption results were compared with pervaporation results of another study in terms of solution-diffusion theory, and the effect of thermodynamic interactions on selective transport of the binary mixture and membrane system was investigated. The results obtained show that selective transport of EtAc-water mixture was influenced by increasing temperature and water content in the feed. It is shown that preferential sorption is more effective for pervaporation selectivity than diffusion selectivity.     

Cost assessment of concrete and steel types for office buildings: An exploratory study

This paper presents a set of regression models which incorporates concrete and steel types in modeling the costs of office buildings. To these ends, three typical office buildings with seven and 15 stories have been designed by the help of a commercial software taking into account the Turkish practice. In each project C-16, C-20, C-25, C-30 and C-35 concrete classes and S-220 and S-420 steel types were used for dimensioning purposes. Rough construction costs were then calculated for different combinations of concrete classes and steel types. The findings of the study revealed that column dimensions decrease following an increase in a particular concrete class. However, this decrease stops after C-30. Furthermore, an average cost difference of 16% was observed between the steel types S-220 and S-420.     

Efficient multiframe Wiener restoration of blurred and noisy imagesequences

Computationally efficient multiframe Wiener filtering algorithms that account for both intraframe (spatial) and interframe (temporal) correlations are proposed for restoring image sequences that are degraded by both blur and noise. One is a general computationally efficient multiframe filter, the cross-correlated multiframe (CCMF) Wiener filter, which directly utilizes the power and cross power spectra of only NxN matrices, where N is the number of frames used in the restoration. In certain special cases the CCMF lends itself to a closed-form solution that does not involve any matrix inversion. A special case is the motion-compensated multiframe (MCMF) filter, where each frame is assumed to be a globally shifted version of the previous frame. In this case, the interframe correlations can be implicitly accounted for using the estimated motion information. Thus the MCMF filter requires neither explicit estimation of cross correlations among the frames nor matrix inversion. Performance and robustness results are given.     

Cost effect of earthquake region and soil type for office buildings in Turkey

In this study, the change in the load-bearing system cost of a reinforced concrete office building has been investigated in relation to the earthquake regions and soil types. Three different office projects each with five stories were investigated. The structural design calculations have been made according to four different soil types and four different earthquake regions. According to each combination, concrete, steel and formwork adopted approximations were calculated to reach the rough cost of each office building. The changes in the cost of projects according to the soil type and earthquake region were examined with multiple regression analysis and analysis of variance. In general, the change in cost has been observed around 22% between first and fourth soil type and 14% between first and fourth earthquake region.     

The strength, elongation and toughness of fresh and weathered bituminous roofing membranes

The author describes in detail, complete with diagrams and test data, the procedures adopted and results obtained. The main problem involving the elongation of the membranes is the large difference between the elongation of the polyester-fibre-based modified bituminous membranes, and the elongation of the glass-fibre-based oxidized bitumen membranes.     

Efficacy of lodoxamide 0.1% versus N-acetyl aspartyl glutamic acid 6% ophthalmic solutions in patients with vernal keratoconjunctivitis

The purpose of this study was to investigate environmental lead exposure in the general Taiwanese population. A total of 8828 Taiwanese adults selected by a multistage sampling method were investigated. Characteristics of the participants were ascertained by questionnaire and 10 ml venous blood was drawn by public health nurses. The blood specimens were distributed to six laboratories for blood lead level (BLL) measurement. A quality control program was applied during the analysis of the BLLs in order to improve precision and accuracy. The arithmetic mean BLL of the 8828 Taiwanese adults was 7.70 +/- 5.23 micrograms/dl, with a maximal level of 69.1 micrograms/dl. The median was 6.5 micrograms/dl and the 90th percentile was 14.0 micrograms/dl. After logarithmic transformation, the geometric mean was 1.84 +/- 0.67 microgram/dl. This study also found that elevated BLLs were associated with certain personal characteristics, i.e., gender, ethnic group, and education level; life-style factors, such as smoking, alcohol consumption, Chinese herbal drug consumption, milk consumption, and sources of drinking water; residential location, i.e., level of urbanization; and occupational history of lead exposure. However, age, floor level of residence, distance from house to road, and betel nut consumption were not associated with elevated BLLs. These results showed that BLLs in the Taiwanese population were not higher than those in developed and developing countries. Most of the influencing factors were also found in other studies; however, local factors such as ethnic group, Chinese herbal drug consumption, and sources of drinking water are important considerations in Taiwan when examining ways to prevent overexposure to lead in the general population.     

Hard iron boride (Fe2B) on 99.97 wt% pure iron

Some properties such as hardness and fracture toughness of boride formed on the 99.97 wt% pure iron were investigated. Boronizing was carried out in a solid medium, consisting of Ekabor powders of 5% B₄C as donor, 5% KBF₄ as an activator and 90% SiC as diluent at 800 °C for 2, 4 and 8 h. The dominant phase formed on the substrate was found to be Fe₂B that had a finger-like shape morphology. The hardness of boride on the 99.97% pure iron was over 1700HVN, while the hardness of pure iron was about 130HVN. It was found that the fracture toughness of boride formed on surfaces of 99.97% pure iron, depending on the process time, ranged from 3.59 to 3.83 MPa m^1/2. Depending on process time and temperature, the depth of the boride layer ranges from 22 to 43 μm, leading to a diffusion-controlled process.     

Study on chemical composition and biological activities of essential oil and extract from Salvia pisidica

In this study, total contents of phenolic, flavanol and flavonol, antioxidant activities and antimicrobial activities of the Turkish endemic Salvia pisidica Boiss. & Heldr. ex Bentham (Lamiaceae) extract and essential oil were assessed in vitro. Total phenolic, flavanol and flavonol contents in the extract were 54.57 mg gallic acid equivalents (GAE)/g, 16.70 mg catechine equivalents (CE)/g and 18.19 mg rutin equivalents (RE)/g, respectively. Antioxidant activities (IC₅₀ value) of the extract and essential oil were determined as 4.88 and 6.41 mg/mL by DPPH assay, respectively. 31 compounds were determined in the essential oil using GC-MS and the major compounds (%) were camphor (23.76), sabinol (19.2), α-thujone (14.2) and eucalyptol (1.8-cineole) (5.8).The antimicrobial activity of the methanolic extract and the essential oil against 13 bacterial and two yeast strains was determined. The extract (concentration 5 g/100 ml or 10 g/100 ml) was effective against most of the strains tested, yet not against Bacillus cereus, Staphylococcus aureus, Aeromonas hydrophila and the two yeast strains tested. The essential oil (2 g/100 ml) showed an antimicrobial effect against all the gram (+) bacteria tested, against Saccharomyces cerevisiae, but was not effective against all gram (−) bacteria and Candida albicans. These results show that S.piscidica essential oil and extract could be considered as a natural alternative to traditional food preservatives and be used to enhance food safety and shelf life.     

Adsorption of cationic polyacrylamide onto sepiolite

The adsorption of PAM onto sepiolite from aqueous solutions has been investigated systematically as a function of some parameters such as calcination temperature of sepiolite, pH, ionic strength and temperature. The adsorption of cationic polyacrylamide (PAM) increases with pH from 5.50 to 11.00, temperature from 25 to 55 degrees C and ionic strength from 0 to 0.1molL(-1). The sepiolite sample calcined at 200 degrees C has a higher adsorption capacity than the other calcined samples. Adsorption isotherms of PAM onto sepiolite have been determined and correlated with common isotherm equations such as Langmuir and Freundlich isotherm models. The Langmuir isotherm model appeared to fit the isotherm data better than the Freundlich isotherm model. The physical properties of this adsorbent are consistent with the parameters obtained from the isotherm equations. The zeta potentials of sepiolite suspensions have been measured in aqueous solutions of NaCl and different PAM concentrations and pH. From the experimental results: (i) pH strongly alters the zeta potential of sepiolite, (ii) sepiolite has an isoelectric point at about pH 6.6 in water and about pH 8 in 250mgL(-1) PAM concentration, (iii) PAM changes the interface charge from negative to positive for sepiolite. Effect of temperature on adsorption has been quantified by calculating various thermodynamic parameters such as Gibbs free energy, enthalpy and entropy. The dimensionless separation factor (R(L)) has shown that sepiolite can be used for adsorption of PAM from aqueous solutions.     

Prediction of the pipe buckling by using broadening factor with distributed Brillouin fiber sensors

We successfully measured longitudinal strains in two full-scale steel pipe specimens subjected to loading combinations of internal pressure, axial tensile force and bending moments undergoing local buckling under controlled laboratory conditions. Carbon-coated fibers, for the first time, and standard communication fibers were used. By using the broadening factor of the Brillouin spectrum width, we can successfully predict the location and progression sequence of buckling patterns, prior their visual detection in the laboratory. The broadening factor processing time is more efficient than multiple-peak fitting of the Brillouin spectrum method. Thus, it is capable of proving real-time deformation progression in structural health monitoring applications. High strength carbon-coated fibers are found to be superior to standard communication fibers in two respects: they provide more accurate readings and are able to measure significantly larger strains.