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101.
Rohit R. Shahi Ashish Bhatnagar Sunita K. Pandey Viney Dixit O.N. Srivastava 《International Journal of Hydrogen Energy》2014
The present investigations are focused on the effect of different Ti-based catalysts (Ti, TiO2, TiCl3 and TiF3) on de/re-hydrogenation characteristics of nanocrystalline MgH2. Desorption temperature of milled MgH2 lowers from 380 to 350, 340, 310 and 260 °C with the addition of Ti, TiO2, TiCl3 and TiF3 respectively. The rehydrogenation characteristics are also improved through the deployment of Ti-based catalysts. Among all Ti based additives, TiF3 is found to be the most effective catalyst for hydrogen sorption from nano MgH2. The better catalytic effect of TiF3 over other Ti-based catalyst can be explained on the basis of temperature programmed reduction (TPR) studies. TPR experiments performed for different Ti additives, reveals that there is no oxidation/reduction reaction below 400 °C except for TiF3. The TPR profile of TiF3 shows some oxidation/reduction reaction exhibits at 200 °C. In order to further improve the sorption characteristics and cyclability of TiF3 catalyzed nano MgH2, we have investigated the effect of SWCNTs in MgH2+TiF3 sample. De/rehydrogenation characteristics reveal the synergistic effect of SWCNTs and TiF3 in MgH2+TiF3 sample. The details of the improvement in sorption behavior of MgH2–TiF3 in presence of SWCNTs are described and discussed. 相似文献
102.
G. Dixit P. Negi J. P. Singh R. C. Srivastava H. M. Agrawal 《Journal of Superconductivity and Novel Magnetism》2013,26(4):1015-1019
In the present work, effect of different concentration of Ce ions on the magnetic properties of nickel ferrite nanoparticles is discussed. A series of NiCe x Fe2?x O4 (x=0.0–0.10) samples were prepared by a chemical route. XRD patterns show that all the samples are in pure spinel phase except that with x=0.10. This indicates that rare earth ions have limited solubility in the spinel lattice. Magnetic properties are studied by electron paramagnetic resonance spectroscopy (EPR) and the results are explained in terms of a magnetic moment obtained by a vibrating sample magnetometer. Mössbauer spectroscopy was performed to have an idea about the distribution of ions between the tetrahedral and octahedral sites. Magnetic moment is found to decrease after doping with Ce ions. It was found that the samples show mixed spinel nature rather than the pure inverse character. Doping with Ce ions reduces the EPR linewidth of pure nickel ferrite, which indicates that eddy current losses are reduced. 相似文献
103.
104.
Renlong Gao Mingqiang Zhang Ninad Dixit Robert B. Moore Timothy E. Long 《Polymer》2012,53(6):1203-1211
Poly(ethylene glycol) (PEG)-based sulfonated polyurethanes bearing either sulfonated soft segments (SSSPU) or sulfonated hard segments (SHSPU) were synthesized using sulfonated monomers. Differential scanning calorimetry (DSC) revealed that sulfonate anions either in the soft segments or hard segments both increased the glass transition temperatures (Tg’s) of the soft segments and suppressed their crystallization. Moreover, dynamic mechanical analysis (DMA) and tensile analysis demonstrated that SSSPU possessed a higher modulus and tensile strength relative to SHSPU. Fourier transform infrared (FTIR) spectroscopy revealed that hydrogen bonding interactions in SHSPU were suppressed compared to SSSPU and noncharged PU. This observation suggested a high level of phase-mixing for SHSPU. In addition, atomic force microscopy (AFM) phase images revealed that both SSSPU and noncharged PU formed well-defined microphase-separated morphologies, where the hard segments phase-separated into needle-like hard domains at the nanoscale. However, SHSPU showed a phase-mixed morphology, which was attributed to increased compatibility of polar PEG soft segments with sulfonated ionic hard segments and disruption of hydrogen bonds in the hard segment. The phase-mixed morphology of SHSPU was further demonstrated using small angle X-ray scattering (SAXS), which showed a featureless X-ray scattering profile. In contrast, SAXS profiles of SSSPU and noncharged PU demonstrated microphase-separated morphologies. Moreover, SSSPU also displayed a broad ionomer peak ranging in q = 1–2 nm?1, which resulted from the sodium sulfonate ion pair association in the polar PEG soft phase. Morphologies of sulfonated polyurethanes correlated well with thermal and mechanical properties. 相似文献
105.
Kumar Naveen Bharti Ajaya Dixit Manish Nigam Abhishek 《Powder Metallurgy and Metal Ceramics》2020,59(7-8):401-410
Powder Metallurgy and Metal Ceramics - As the world is shifting towards renewable sources of energy, the demand for copper is increasing due to its excellent electrical and corrosion resistance... 相似文献
106.
Apoptosis induction by caspase-8 is amplified through the mitochondrial release of cytochrome c 总被引:1,自引:0,他引:1
T Kuwana JJ Smith M Muzio V Dixit DD Newmeyer S Kornbluth 《Canadian Metallurgical Quarterly》1998,273(26):16589-16594
Apoptosis often involves the release of cytochrome c from mitochondria, leading to caspase activation. However, in apoptosis mediated by CD95 (Fas/APO-1), caspase-8 (FLICE/MACH/Mch5) is immediately activated and, in principle, could process other caspases directly. To investigate whether caspase-8 could also act through mitochondria, we added active caspase-8 to a Xenopus cell-free system requiring these organelles. Caspase-8 rapidly promoted the apoptotic program, culminating in fragmentation of chromatin and the nuclear membrane. In extracts devoid of mitochondria, caspase-8 produced DNA degradation, but left nuclear membranes intact. Thus, mitochondria were required for complete engagement of the apoptotic machinery. In the absence of mitochondria, high concentrations of caspase-8 were required to activate downstream caspases. However, when mitochondria were present, the effects of low concentrations of caspase-8 were vastly amplified through cytochrome c-dependent caspase activation. Caspase-8 promoted cytochrome c release indirectly, by cleaving at least one cytosolic substrate. Bcl-2 blocked apoptosis only at the lowest caspase-8 concentrations, potentially explaining why CD95-induced apoptosis can often evade inhibition by Bcl-2. 相似文献
107.
Bharat Chandrashekhar Dixit Ritu B. Dixit Dhirubhai J. Desai 《Journal of Polymer Research》2010,17(4):481-488
Novel ion-exchange resin (PBMDDMCMHQ polyimide) having 8-hydroxyuinoline as a pendent groups was prepared using phenylenebismaleimide-diamine polyimide (PBMDDM) and 5-chloromethyl-8-hydroxyquinoline hydrochloride (CMHQ). Phenylenebismaleimide-diamine polyimide (PBMDDM) was prepared by Michael addition reaction of 1,3-phenylenebismaleimide (PBM) and 4,4’-diaminodiphenyl methane (DDM). The resulting ion-exchange resin was characterized by spectral techniques. Polymeric metal chelates of ion-exchange resin were also prepared using transition metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II), and were duly characterized. Ion-exchange properties of ion-exchange resin (PBMDDMCMHQ) for Fe(III), Zn(II), Ni(II) and Cu(II) metal ions were also studied by batch-equilibration method. The produced ion-exchange resin (PBMDDMCMHQ) has thermal stability up to 220°C and can be used over a wide pH range. It has good metal up take capacity at varying pH range and can be recycled. 相似文献
108.
Effect of heat treatment on the sliding wear behaviour of aluminium alloy hard particle composite was studied under varying applied load and sliding speed, giving emphasis on the parameters such as wear rate, temperature rise, coefficient of friction and seizure pressure. Hardness is improved due to heat treatment irrespective of the material. Maximum hardness is noted when the materials are aged for 6 h. These facts have been discussed on the basis of nature of worn surface produced after wear. In the present investigation, aging time has been varied from 4 to 10 h at a regular increment of 2 h. 相似文献
109.
All-optical packet switching for metropolitan area networks:opportunities and challenges 总被引:10,自引:0,他引:10
The fast evolution of networks has been continuously driven by new advances in enabling technologies, as well as the growth of Internet traffic. All-optical packet switching provides high throughput, rich routing functionalities, and excellent flexibility. These characteristics make it an excellent candidate for next-generation metropolitan area networks, which will be much more dynamic and demanding than today's networks. In this article we not only discuss some of the architectural challenges involved in the design of all-optical packet switched networks, but also present the reader a high-level picture of how such future networks could be integrated with other network segments, to provide users end-to-end connectivity with performance and simplicity 相似文献
110.
Designing of multilayer coatings of poly(styrene)-tetrahydrofuran and poly(methyl methacrylate)-tetrahydrofuran has been studied. Multilayers were prepared by layer-by-layer and simultaneous methods. Several binary polymeric coatings of poly(styrene)-tetrahydrofuran and poly(methyl methacrylate)-tetrahydrofuran systems have been dried under quiescent drying conditions. Gravimetric analyses were performed using an analytical weighing balance. The initial amount of polymer was kept constant in both solution coatings. Coating which is likely to go through the glass transition temperature should be applied on the bottom side in order to minimize the residual solvent. For instance, residual solvent content is high in multilayer coating having poly(methyl methacrylate)-tetrahydrofuran coating on the top and poly(styrene)-tetrahydrofuran coating on the bottom, as compared to multilayer coatings having poly(styrene)-tetrahydrofuran on the top of poly(methyl methacrylate)-tetrahydrofuran coating. 相似文献