Tetrabutyl-tetraphenyl-diindenoperylene derivatives as alternative green donor in bulk heterojunction organic solar cells

We present the material 2,3,10,11-tetrabutyl-1,4,9,12-tetraphenyl-diindeno[1,2,3-cd:1′,2′,3′-lm] perylene (Bu4-Ph4-DIP) as alternative green donor for bulk heterojunction small molecule organic solar cells (SMOSC). It is shown that Bu4-Ph4-DIP exhibits suitable absorption characteristics to be a potential material to fill the absorption gap between the commonly used standard absorbers ZnPc and C₆₀.Devices with bulk heterojunctions of Bu4-Ph4-DIP:C₆₀ display very high open circuit voltages of 0.99 V, high fill factors of up to 57%, and experiments yield promising efficiencies of η>2%. Such green-blue absorbing SMOSC are characterized by current voltage and external quantum efficiency measurements, and material properties are studied. It is shown that the devices are responsive to substrate heating, and that different donor-acceptor mixing ratios can increase device performance. Possible influences of mixing ratio and heating on device morphology and electrical properties are discussed.     

The Effect of Gradual Fluorination on the Properties of FnZnPc Thin Films and FnZnPc/C60 Bilayer Photovoltaic Cells

Motivated by the possibility of modifying energy levels of a molecule without substantially changing its band gap, the impact of gradual fluorination on the optical and structural properties of zinc phthalocyanine (F_nZnPc) thin films and the electronic characteristics of F_nZnPc/C₆₀ (n = 0, 4, 8, 16) bilayer cells is investigated. UV–vis measurements reveal similar Q‐ and B‐band absorption of F_nZnPc thin films with n = 0, 4, 8, whereas for F₁₆ZnPc a different absorption pattern is detected. A correlation between structure and electronic transport is deduced. For F₄ZnPc/C₆₀ cells, the enhanced long range order supports fill factors of 55% and an increase of the short circuit current density by 18%, compared to ZnPc/C₆₀. As a parameter being sensitive to the organic/organic interface energetics, the open circuit voltage is analyzed. An enhancement of this quantity by 27% and 50% is detected for F₄ZnPc‐ and F₈ZnPc‐based devices, respectively, and is attributed to an increase of the quasi‐Fermi level splitting at the donor/acceptor interface. In contrast, for F₁₆ZnPc/C₆₀ a decrease of the open circuit voltage is observed. Complementary photoelectron spectroscopy, external quantum efficiency, and photoluminescence measurements reveal a different working principle, which is ascribed to the particular energy level alignment at the interface of the photoactive materials.     

Fire‐retardant hybrid thermosetting resins from unsaturated polyesters and polysilazanes

This introduces an organic–inorganic thermosetting hybrid resin system based on unsaturated polyester and polysilazanes. It shows the chemical modification of unsaturated polyester structures by end capping to enable the combination of both components. In general, halogen‐free unsaturated polyesters are not fire‐retardant and have to be equipped with additives. Fillers and intumescent additives are preponderantly used in today's fire‐retardant formulations. In contrast to these fire‐retardants, polysilazanes act as ceramizing agents. Polysilazanes are suitable fire‐retardants for resin transfer molding due to their low viscosity. Both burning behavior and glass transition temperature (T_g) are investigated as important application properties. In contrast to state‐of‐the‐art fire‐retardant formulations polysilazane‐based thermosetting hybrid resins burn with high intensity and fast extinction. Therefore, total heat and smoke emission is decreased. The formation of ceramic structures during burning results in high residual mechanical properties and a low mass loss. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40375.     

Chemikalienfreie Bekämpfung von Holzschädlingen durch dielektrische Erwärmung mit Radiowellen und Mikrowellen

Thermal pest control requires long treatment times due to the low thermal conductivity of wood and may lead to the formation of cracks. Here, the thermal treatment with radio waves as well as microwaves has been studied. The direct dielectric heating has the advantage of a good homogeneity. The obtained temperature profiles for radio waves were more homogeneous compared to microwaves. Detailed studies showed that elimination of pests was not related to the application of the electromagnetic field itself, but due to the temperature increase.     

Fractional derivatives and recurrent neural networks in rheological modelling – part I: theory

The aim of this paper was to develop a general approach based on fractional time derivatives and recurrent neural networks to model the rheological behaviour of asphalt materials. The paper focuses on elastic and viscoelastic material characteristics. It consists of two parts. In this first part, the theoretical aspects of modelling are discussed. A brief introduction into the theory of rheological elements based on fractional time derivatives is provided. The fractional differential equation of a general rheological element (base element) is developed from which a huge variety of other rheological elements can be derived, e.g. fractional Newton, Kelvin and standard solid elements. A new approach is presented for solving the fractional differential equations. Artificial neural networks are developed to compute the stress–strain–time behaviour of fractional rheological elements in a numerical efficient way. The approach is tested and verified. The second part of this work will appear later. It will be focused on applications of the new theoretical work to pavement engineering problems.     

Comments on solid state hydrogen storage systems design for fuel cell vehicles

In recent years, significant research and development efforts were spent on hydrogen storage technologies with the goal of realizing a breakthrough for fuel cell vehicle applications. This article scrutinizes design targets and material screening criteria for solid state hydrogen storage. Adopting an automotive engineering point of view, four important, but often neglected, issues are discussed: 1) volumetric storage capacity, 2) heat transfer for desorption, 3) recharging at low temperatures and 4) cold start of the vehicle. The article shall help to understand the requirements and support the research community when screening new materials.     

Public acceptance for environmental taxes: Self-interest,environmental and distributional concerns

While strongly recommended by economists, it has often been politically difficult to impose taxes on externalities. There is a substantial literature on public attitudes towards environmental taxes. There has, however, been few comprehensive attempts to understand attitudes towards environmental taxes.     

Parameter-study on the influence of steel fibers and coarse aggregate content on the fresh properties of self-compacting concrete

Self-compacting concrete (SCC) offers several economic and technical benefits; the use of steel fibers extends its possibilities. Steel fibers bridge cracks, retard their propagation, and improve several characteristics and properties of the concrete. Fibers are known to significantly affect the workability of concrete. Therefore, an investigation was performed to compare the properties of plain SCC and SCC reinforced with steel fibers. Two mixtures of SCC with different aggregate contents were used as reference. Each of the concretes was tested with four types of steel fibers at different contents in order to answer the question to what extent the workability of SCC is influenced. The slump flow, a fiber funnel and the J-ring test were used to evaluate the material characteristics of the fresh concrete. This paper discusses the suitability of the applied test methods and the effect of the coarse aggregate content, the content and type of steel fibers on the workability of SCC.     

Continuous Model-Driven Engineering

CMDE has been successfully applied in several industrial projects, including telecommunication services, supply-chain management, bioinformatics, logistics, and healthcare. In all these cases, agility at the customer, user, and application level proved key to aligning and linking business and IT. We now expect an additional boost when integrating this approach into a processor project-management environment that oversees development and evolution. This environment will include deadline management and progress reports, automatically informing all relevant parties when certain actions are required, managing different versions and product lines, and automatically steering the build and quality-management process. Perhaps not surprisingly, the development of this management environment proved to be a prime application of CMDE.     

Factorial interlaboratory tests for microbiological measurement methods

This paper presents a validation approach for microbiological methods based on a combination of interlaboratory tests and factorial experiments. It requires not more than 4 participants but is achieving comparable statistical confidence as in method validation studies with 8–12 participants, if properly designed. The approach is illustrated by a comprehensive validation of the Arxula adeninivorans yeast estrogen screen (A-YES) assay for the detection of estrogenic activity in mineral water.