Variation of Intumescent Coatings Revealing Different Modes of Action for Good Protection Performance

Thermal insulation and mechanical resistance play a crucial role for the performance of an intumescent coating. Both properties depend strongly on the morphology and morphological development of the foamed residue. Small amounts (4 wt%) of fiberglass, clay and a copper salt, respectively, are incorporated into an intumescent coating to study their influence on the morphology and performance of the residues. The bench scale fire tests were performed on 75 × 75 × 2 mm³ coated steel plates according to the standard time–temperature curve in the Standard Time Temperature Muffle Furnace⁺ (STT Mufu⁺). It provided information about foaming dynamics (expansion rates) and thermal insulation. Adding the copper salt halved the expansion height, whereas the clay and fiberglass change the height of the residue only moderately. The time to reach 500°C was improved by 31% for clay and 15% for the other two fillers. Nondestructive micro computed tomography is used to assess the inner structure of the residues. A transition of the residue from a black, carbonaceous foam with closed cells into an inorganic, residual open cell sponge occurs at high temperatures. This transition is due to a loss of carbon; the change in microstructure is analyzed by scanning electron microscopy. Additional mechanical tests are performed and interpreted with respect to the results of the morphology analysis. Adding clay or copper salt improved the mechanical resistance tested by a factor 4. The additives significantly influence the thickness and foaming dynamics as well as the inner structure of the residues, whereas their influence on insulation performance is moderate. In conclusion, different modes of action are observed to achieve similar insulation performance during the fire test.     

Occurrence of perfluoroalkyl compounds in surface waters from the North Pacific to the Arctic Ocean

Perfluoroalkyl compounds (PFCs) were determined in 22 surface water samples (39-76°N) and three sea ice core and snow samples (77-87°N) collected from North Pacific to the Arctic Ocean during the fourth Chinese Arctic Expedition in 2010. Geographically, the average concentration of ∑PFC in surface water samples were 560 ± 170 pg L(-1) for the Northwest Pacific Ocean, 500 ± 170 pg L(-1) for the Arctic Ocean, and 340 ± 130 pg L(-1) for the Bering Sea, respectively. The perfluoroalkyl carboxylates (PFCAs) were the dominant PFC class in the water samples, however, the spatial pattern of PFCs varied. The C(5), C(7) and C(8) PFCAs (i.e., perfluoropentanoate (PFPA), perfluoroheptanoate (PFHpA), and perfluorooctanoate (PFOA)) were the dominant PFCs in the Northwest Pacific Ocean while in the Bering Sea the PFPA dominated. The changing in the pattern and concentrations in Pacific Ocean indicate that the PFCs in surface water were influenced by sources from the East-Asian (such as Japan and China) and North American coast, and dilution effect during their transport to the Arctic. The presence of PFCs in the snow and ice core samples indicates an atmospheric deposition of PFCs in the Arctic. The elevated PFC concentration in the Arctic Ocean shows that the ice melting had an impact on the PFC levels and distribution. In addition, the C(4) and C(5) PFCAs (i.e., perfluorobutanoate (PFBA), PFPA) became the dominant PFCs in the Arctic Ocean indicating that PFBA is a marker for sea ice melting as the source of exposure.     

Effect of Sediment Size Scaling on Physical Modeling of Bridge Pier Scour

Local pier scour experiments were performed in the laboratory to investigate the effect of relative sediment size on pier scour depth using three uniform sediment sizes and three bridge pier designs at different geometric model scales. When the data from a large number of experimental and field investigations are filtered according to a Froude number criterion, the effect of relative sediment size on dimensionless pier scour depth is brought into focus. The choice of sediment size in the laboratory model distorts the value of the ratio of pier width to sediment size in comparison with the prototype which in turn causes larger values of scour depth in the laboratory than in the field. This model distortion due to sediment size is shown to be related to the scaling of the large-scale unsteadiness of the horseshoe vortex by studying the relevant time scales of its coherent structure upstream of a bridge pier using acoustic Doppler velocimeter measurements. Observations of sediment movement, probability distributions of velocity components, and phase-averaging of velocity measured upstream of a bridge pier reveal properties of coherent motions that are discussed in terms of their contribution to the relationship between dimensionless pier scour depth and the ratio of pier width to sediment size over a large range of physical scales.     

The behaviour of WB 35 piping material under dynamic loading in the high speed tensile test

For the determination of the strength-, deformation- and fracture behaviour of the material 17 MnMoV 6 4 (WB 35) which is used for piping components, tensile tests were carried out at different loading rates (monotonic and impact-type) on smooth and notched pipe strip specimens over a temperature range extending from − 30°C to 250°C.For the conduct of the tests a hydraulic high speed tensile machine having a free motion device was used; the velocity of impact was preset at ca. 7 m/s.With impact-type (dynamically) loaded specimens in general higher strength and deformation values were obtained than with monotonic (statically) loaded ones. In all of the specimens having low deformation values which were investigated microfractographically, ductile portions were found adjacent to the notch on the fracture surface.     

The psychologist in the Problem-Oriented Record (POR).

The Problem-Oriented Record is a system developed by L. L. Weed for rendering the patient's treatment record more powerful and professionally useful. The POR can be seen as (a) fostering a continuing scientific and educative attitude in clinical work (a summary of the POR is provided), and (b) facilitating adherence to formal standards of record keeping in mental health and psychological practice. The POR may be considered (a) adaptable not only to behavioral methods but to other theoretical approaches (examples from psychological reports are provided) and (b) able to demonstrate its adequacy in the face of several kinds of inquiry. Consideration of the POR by applied psychologists is recommended. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Family planning services in developing countries: an opportunity to treat asymptomatic and unrecognised genital tract infections?

OBJECTIVE: To determine the prevalence of asymptomatic and unrecognised genital tract infections among women attending a family planning clinic in rural South Africa. METHODS: 189 consecutive women had genital samples taken to diagnose infection with Neisseria gonorrhoeae, Chlamydia trachomatis, Trichomonas vaginalis, Candida albicans, Treponema pallidum, and HIV, and to diagnose bacterial vaginosis. RESULTS: Mean age was 25 years; 155 (82%) were unmarried, 156 (83%) were currently using contraception, and 41 (22%) reported having an STD treated in the preceding 12 months. Although none volunteered abnormal urogenital symptoms, 74 (39%) had at least one elicited by direct questioning. 119 women (63%) had at least one genital infection: N gonorrhoeae (eight; 4%), C trachomatis (14; 8%), T vaginalis (26; 14%), C albicans (56; 30%), active syphilis (15; 8%), HIV (44; 24%), and bacterial vaginosis (29; 15%). 49 women (26%) had multiple infections. Most infections (71; 60%) were asymptomatic. Symptomatic women failed to recognise and report their symptoms, and routine services failed to detect the infections. CONCLUSION: Prevalence of genital tract infection is high among these women, most infections are asymptomatic, and symptomatic infections are frequently not recognised. Women attending family planning clinics in such settings should be screened for syphilis and offered testing for HIV infection. Strategies to detect and treat other genital infections need to be developed.     

Material surfaces for electron-optical equipment

Electron-beam inspection systems for VLSICs and electron-beam pattern generation require exact positioning of the electron beam on the specimen. In this connection the question arises as to what properties the walls and diaphragms in the ambience of the path of the electron beam are required to have with respect to material, surface layers and cleanness in order to exclude their collecting electric charges that will undesirably influence the electron beam. Experimental investigations of this problem by means of electron-shadow projection show that the conductivity of a material should not be the sole criterion for its choice, but that its behavior under exposure to backscattered electrons and secondary electron emission must also be taken into account. Graphite of poor conductivity was found to be particularly favorable. Electroplated surfaces are often less favorable than untreated surfaces. Magnetic materials always exhibit minor defects. For cleaning, a carefully controlled ultrasonic technique using conventional cleaning agents is necessary and sufficient.     

Symbiosis of Silica Biomorphs and Magnetite Mesocrystals

Silica biomorphs are extraordinary inorganic superstructures formed via autocatalytic co‐precipitation and bottom‐up self‐assembly of alkaline‐earth carbonates and silica. However, they show no inherent functionality except for their striking textural motifs and curved morphologies. This work presents strategies to magnetize silica biomorphs, thus creating thermally stable ceramic microswimmers with unique elaborate shapes. This is achieved by growing super paramagnetic magnetite mesocrystals on and around the complex curved surfaces of biomorphs, while keeping their morphology and maintaining mesocrystal integrity. Selective mesocrystal formation on certain parts of the substrates is induced by chemical modification of the biomorph surface, increasing the loading of magnetite on the silica–carbonate structures and, in suitable cases, rendering them able to respond to external magnetic fields and move as microswimmer entities. In this way, the complex ultrastructure of silica biomorphs is successfully used as a template for functional ceramics. Furthermore, selective dissolution of the carbonate core from the biomorphs leads to hollow magnetic structures that could be filled with actives, thus serving as microcarriers with considerable loading capacity.     

Magnetic Nanoparticle Chains in Gelatin Ferrogels: Bioinspiration from Magnetotactic Bacteria

Inspired by chains of ferrimagnetic nanocrystals (NCs) in magnetotactic bacteria (MTB), the synthesis and detailed characterization of ferrimagnetic magnetite NC chain‐like assemblies is reported. An easy green synthesis route in a thermoreversible gelatin hydrogel matrix is used. The structure of these magnetite chains prepared with and without gelatin is characterized by means of transmission electron microscopy, including electron tomography (ET). These structures indeed bear resemblance to the magnetite assemblies found in MTB, known for their mechanical flexibility and outstanding magnetic properties and known to crystallographically align their magnetite NCs along the strongest <111> magnetization easy axis. Using electron holography (EH) and angular dependent magnetic measurements, the magnetic interaction between the NCs and the generation of a magnetically anisotropic material can be shown. The electro‐ and magnetostatic modeling demonstrates that in order to precisely determine the magnetization (by means of EH) inside chain‐like NCs assemblies, their exact shape, arrangement and stray‐fields have to be considered (ideally obtained using ET).     

TRANSPARENTE POLYMERE MEHRPHASENSYSTEME

Usually two phase polymer blends are not transparent because of differences in the refractive indices of their components and the resulting light scattering. By means of model calculations on the basis of the Mie-theory, the conditions for transparency in two-phase polymer blends are investigated. The models used are homogeneous spheres or spheres with a core-shell morphology imbedded in the polymer matrix. The light scattering of these particles is calculated as a function of diameter, refractive index, wavelength and particlecomposition. Results are presented that show the limits of diameter and difference in the refractive indices between matrix and particle for homogeneous particles to obtain transparency. In the case of large differences in the refractive indices or of large diameters the use of spheres with a core-shell morphology is favourable. Depending on the refractive indices of the respective phases, there exists an optimal composition of these spheres to obtain transparent polymer-blends. Another way to transparency is the minimization of light scattering by interparticle interferences, which can be achieved by special types of block-copolymers.