Photophysical and photochemical investigations on triazole ring linked chalcone containing polymethacrylates

A series of polymethacrylates containing triazole ring linked chalcone were designed and synthesized. These conjugated chalcone polymers are modulate under the light depending on the pendant substituents (–N(CH₃)₂, CH₃, OCH₃, Br, H & NO₂). The steady-state absorption and emission spectroscopic techniques have been used to investigate intramolecular charge transfer (ICT) behaviour of the polymers. Absorption spectra in different organic solvents demonstrate the presence of ICT in polymer 5a. On the other hand, its excited singlet state exhibits high ICT characters as manifested by polarity of solvents. Interestingly, ICT emission maximum is strongly red shifted (53 nm). The emission intensities of fluorophore are compared with those measured after crosslinking, suggesting that the statically quenched fluorophores are entirely non-emissive. The emission decay of polymer 5a displays bi-exponentially with life time of 0.52 and 1.62 ns ascribed to presence of locally excited ICT state. Cyclic voltammogram demonstrates irreversible oxidation potential at 0.9 V indicates formation mono-radical cation.     

Preparation of the Sb-containing purple conversion coating on brass

A new chemical method for preparing a purple conversion coating on brass was developed. The effect of antimonous oxide concentration and temperature on color and corrosion resistance of the conversion coating, and the change of electric potential with time on coating forming process were studied. The optimum technological conditions were 10?g/L antimonous oxide, 20?g/L copper acetate, 200?mL/L hydrochloric acid at 65°C for 3?min. Results of electrochemical and dropping experiments showed that the brass with purple conversion coating presents better corrosion resistance than bare brass. The scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) results showed that the conversion coating mainly comprising copper and antimony was uniform and compact.     

A fast IP lookup scheme for high speed routers

Abstract

One of the key design issues for the next generation of IP routers is the IP lookup mechanism. IP lookup is an important action in a router, that is, to find the next hop for each incoming packet with a longest‐prefix‐match address in the routing table. In this paper, we propose an IP lookup mechanism with the number of memory accesses for an IP lookup being one in the best case and being four in the worst case. The forwarding table needed by our mechanism is small enough to fit in the SRAM. For example, a large routing table with 40000 routing entries can be compacted to a forwarding table of 260KBytes in our scheme.     

新型刀具用钢的热处理工艺及微观组织

采用不同淬回火工艺系统地研究了一种高碳高铬马氏体刀具用钢—SIMR的热处理工艺和微观组织,通过XRD、SEM和TEM等表征方法,分析测试了不同淬火温度和回火温度下SIMR刀具用钢的微观组织、碳化物形貌与分布和显微硬度等,获得了SIMR的最佳热处理工艺。结果表明,SIMR刀具用钢的晶粒尺寸随着淬火温度的升高而逐渐增大,冶炼凝固过程中析出的富铬M₇C₃型一次碳化物随着淬火温度的提高而逐渐回溶,显微硬度总体上呈现先升高后降低的趋势,回火温度在150~300 ℃间,SIMR刀具用钢的最佳热处理工艺为在1050 ℃淬火处理20 min,油冷,然后在150 ℃回火处理90 min,空冷。     

Modeling of a membrane reactor system for crude palm oil transesterification. Part II: Transport phenomena

The mechanistic modeling of biodiesel production process in membrane reactor with the consideration of chemical reaction, phase equilibrium, and ultrafiltration is important for the membrane reactor design. In part II of this work, the chemical and phase equilibrium (CPE) model for crude palm oil transesterification reaction in the membrane reactor developed in part I is extended to an integration of CPE with modified Maxwell–Stefan model, which considers multicomponent mass transport phenomena of concentration polarization and intramembrane. A good fit of simulated permeate fluxes and apparent solute rejection to the experimental data shows that the model has a good prediction capability. Reversible fouling was found to be the major fouling and no pore plugging was observed. Simulation results verified that micelles were retained by the membrane at CPO:MEOH molar ratio of 1:24 and catalyst concentration of 0.5 wt %. However, phase inversion happened when catalyst concentration of 0.05 and 0.1 wt % were used. © 2015 American Institute of Chemical Engineers AIChE J, 61: 1981–1996, 2015     

Topology optimization of transient problem with maximum dynamic response constraint using SOAR scheme

Frontiers of Mechanical Engineering - This paper proposes a novel method for the continuum topology optimization of transient vibration problem with maximum dynamic response constraint. An...     

一种基于增强现实的高精度自动配准和追踪技术

针对医学中现有手动配准技术精度不高和视角不足问题,提出一种新的配准与追踪的方法。基于Hololens眼镜、采用双目相机摄影测量获取真实空间坐标点帮助自动配准,使用Vuforia进行关联虚拟现实之间坐标系,提高虚实配准精度,采用空间映射转换以及旋转矩阵与欧拉角转换实现虚实坐标配准。Vuforia中制作的Cylinder Target识别在虚实配准过程中不易受到遮挡的影响,且自动配准精度较高。其优点表现在:利用增强现实技术将真实空间信息与虚拟空间信息融合叠加,使真实模型与虚拟模型叠加精度达到1.004mm,允许医生可360度视角操作,并可在测试区域内走动,在医学中具有一定的先进性和参考应用价值。