三维泡沫石墨烯在抗坏血酸的干扰下检测尿酸

该文采用化学气相沉积法在泡沫镍上生长石墨烯,通过扫描电镜、X射线衍射、拉曼光谱对生成产物的形貌和结构分别进行了表征。结果表明：所制得的石墨烯为具有三维网状结构且层数较少的石墨烯。将三维泡沫石墨烯转移到ITO玻璃上制成生物传感器的工作电极,利用电化学工作站对尿酸和抗坏血酸进行检测．电化学测试结果表明：三维泡沫石墨烯修饰电极在抗坏血酸的干扰下可以准确的检测尿酸,其灵敏度为0．274μA／（μmol／L）,线性范围为10-100μmol／L。     

Energy criterion for modelling creep rupture of high-density polyethylene

A technique involving the use of a three-element mechanical model with a critical stored energy criterion modelled accurately the creep rupture time of two types of high-density polyethylene (HDPE) specimens. The upper stress limit where the specimen ruptured immediately on application of load and the lower stress limit where the specimen sustained the load indefinitely were also features of the model. These two limits were found to depend on the resilience, elastic modulus and anelastic modulus of the HDPE.     

Study on antibacterial O-carboxymethylated chitosan/cellulose blend film from LiCl/N, N-dimethylacetamide solution

Two types of O-carboxymethylated chitosan (O-CMCh)/cellulose polyblends were prepared by mixing cellulose LiCl/N,N-dimethylacetamide (DMAc) solution with O-CMCh aqueous solution (I) or DMAc emulsion (II) and their corresponding films (I and II) were regenerated in water. The (O-CMCh)/cellulose films obtained were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and wide-angle X-ray-scattering (WAXS). FTIR analyses showed that amino groups of O-CMCh were not affected during the film formation. SEM observations indicated that the O-CMCh/cellulose polyblend displayed a heterogeneous microstructure. O-CMCh microdomains dispersed in the cellulose matrix of the blend film. Blend film I showed a better dispersion of the O-CMCh microdomains than blend film II did. DSC and WAXS analyses suggested that, for both two kinds of the blend films, the addition of O-CMCh did not significantly influence the crystallinity and thermal properties of cellulose. The antibacterial activity of the films against Escherichia coli (E. coli) was also measured via optical density method. Both blend films I and II exhibited satisfying antibacterial activity against E. coli, even the O-CMCh concentration was only 2 wt%. Due to the coagulation effect of water on the polyblend, O-CMCh water solution is suitable for the preparation of the blend film with low O-CMCh concentration, while O-CMCh DMAc emulsion should be selected when high O-CMCh concentration is needed.     

Acidic hydrolysis of a poly(vinyl acetate) matrix by the catalytic effect of Ag nanoparticles and the micellization of Ag‐metal‐containing polymer

In this study, we conveniently obtained Ag(0)–polymer nanocomposites by reacting AgNO₃ with commercial poly(vinyl acetate) (PVAc) in the absence of a special reducing agent. The formation of Ag(0) metal was detected after formic acid (HCOOH) was added to a PVAc–AgNO₃ complex system, and some of the acetate groups of the PVAc backbone were hydrolyzed to form hydroxyl groups (OH) under the catalytic effect of the reduced Ag(O) metal. Here, the structure of the partially hydrolyzed PVAc backbone was represented as PVOH‐PVAc. X‐ray diffraction spectra showed that the Ag(0) metal generated in this method was in the form of Ag crystals. The structure of the Ag(0)–polymer was analyzed by ¹H‐NMR and ¹³C‐NMR spectroscopy. The micellization of the Ag(0)–polymer was also investigated by the addition of an inducing solvent to the formic acid solution of Ag(0)–polymer. The image showed that the morphology of the Ag micelles in the H₂O‐induced solvent was a Ag corona with a Ag shell, and that in the p‐xylene induced solvent showed a Ag cluster core structure. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1457–1464, 2006     

Strength development of high strength concretes with and without silica fume under the influence of high hydration temperatures

High performance concretes of high compressive strength are finding increasing applications in many fields of construction such as core walls and columns in tall buildings, long-span bridges and marine structures. In thick cross-sections, the high binder contents of some high strength concretes can result in the development of high in-situ temperatures. The combined influence of limited moist curing and high hydration temperatures may significantly influence the progress of hydration. This can affect the long-term development of in-situ strength and other engineering properties. Knowledge of in-situ strength development under these conditions is needed to ensure safe utilisation of this new generation of construction materials.

This paper presents results of an investigation on the strength development of high strength concretes with and without silica fume subjected to high in-situ temperature conditions. A temperature match conditioning (TMC) system was developed and used to simulate the semi-adiabatic temperature development within medium sized high strength concrete columns. The results of this investigation show that in-situ temperatures of up to 70 °C significantly increased the 7-day strength of a high strength silica fume concrete. Although no strength regression was observed up to 1 year, the silica fume concrete subjected to high early temperatures showed significantly lower strengths when compared to concrete cured at standard temperature. For the silica fume concrete subjected to high early temperatures, non-evaporable water contents suggest little additional hydration beyond 3 days.     

微型轴流风扇优化设计系统的设计实现

设计高性能的微型轴流风扇,同时降低设计成本、缩短设计周期,是轴流风扇研究的主要目标.采用孤立叶型法、计算流体动力学技术和遗传算法相结合的策略,构建微型轴流风扇优化设计系统.该系统采用面向对象的设计方法和模块化的构造方法,采用C++及Open GRIP语言编写,并提供开放式接口,使系统易于完善和扩充.在此系统下可以实现微...     

略论企业档案管理人员岗位价值提升

企业档案管理工作者所承担的日常工作,就其性质而言是一项很琐碎的基础性工作,但是这些貌似简单的工作其内涵却相当的丰富。不同档案从业人员的素质,要求是不同的,是由企业档案工作的性质、任务、目的和内容所决定的。本文结合笔者多年工作实践,具体分析了提升企业档案管理人员岗位价值的几条措施。     

A new calculation method for the number of radial slots of a Terfenol rod

Terfenol is an ideal choice for medium to high power low frequency sonar. It can offer the transducer designer higher strain, higher power density, but the designer must be aware of the eddy current. To enhance efficiency of the barrel-stave transducer powered by a Terfenol rod, radial slots rather than laminations were used to control eddy currents in the Terfenol drive rod, and the effectiveness and the number of these slots were studied experimentally and calculated by finite element modeling. Based on the characteristic of vortex path, a new simple geometrical method to calculate the number of the radial slots of a Terfenol rod at the operating frequency is put forward in this paper. Moreover, the calculated results are in good agreement with those of using the finite element method (FEM) for the slotted Terfenol rod given by the literature. The method will save much cost to design Terfenol rod transducers.     

基于秩-1矩阵摄动的递归主元分析算法

针对传统主元分析（PCA）算法仅适用于定常系统监测的不足,提出了一种基于秩-1矩阵摄动的递归主元分析（RPCA）算法以适应实际工业过程的时变特性.RPCA算法首先对初始化样本协方差矩阵进行特征值分解,得到特征向量矩阵与特征值矩阵;然后在各时刻采用秩-1矩阵摄动算法对这两个矩阵递归更新并对其各向量与各元素排序,同时以累计方差百分比（CPV）为标准选取主元数目,从而显著降低了运算复杂度,节省了存储量.青霉素间歇发酵过程在线监测的仿真结果表明,RPCA算法大大降低了系统的误警率,并及时监测出过程中存在的故障.     

基于Pro/Engineer的数控加工与后置处理技术

论述了基于Pro／Engineer的注射模数控加工技术，并介绍了Pro／Engineer通用后置处理软件包(NC Psot Processor的功能和内容。后置处理软件包进行的后置处理技术，此后置处理技术较好地应用于MV-610加工中心的加工。