Phase behavior and mechanical properties of poly-p-phenylene terephthalamide/amorphous nylon molecular composites

Poly(p-phenylene terephthalamide) (PPTA)/amorphous nylon (AN) molecular composites were prepared from sulfuric acid solution by rapidly coagulating in distilled water. The regenerated films appear homogeneous and transparent. However, the rod-like and flexible macromolecules are probably entrapped in a single phase during rapid coagulation, thus thermodynamically unstable and undergoing phase segregation upon thermal treatment. The miscibility between PPTA/AN was identified by a dielectric relaxation method. Phase behavior and kinetics of phase separation in PPTA/AN mixtures were thoroughly investigated by time-resolved light scattering as well as optical microscope. A pseudo phase diagram reminiscent of a lower critical solution temperature (LCST) was established by a cloud point measurement. Several temperature-jump experiments were undertaken from ambient to a two-phase temperature region. The low PPTA content molecular composites were prepared by coagulating in a non-solvent, then by compression molding below the phase separation temperatures. The 30 wt% PPTA molecular composite exhibits over three-fold increase in tensile modulus relative to that of the neat AN, however, there is little or no improvement in the tensile strength. On the other hand, by a slight addition of AN into PPTA, the tensile and compressive failures of spun fibers may be improved.     

Hydrophilic and adhesive properties of methacrylic acid-grafted polyethylene plates

Methacrylic acid (MAA) was grafted onto polyethylene (PE) surfaces by simultaneous irradiation with UV rays in the liquid phase to estimate hydrophilic and mechanical properties for MAA-grafted PE plates. The amount of grafted MAA increased sigmoidally with UV irradiation time, and the higher grafted amount was obtained at higher monomer concentrations. With an increase in grafting of MAA, the wettabilities from the contact angles of water were enhanced and the refractive indices from the ellipsometry decreased. Though the contact angles remained constant above the grafted amount of 0.02 mmol/cm², the refractive indices approached the value of PMAA around 0.009 mmol/cm², indicating that the PE surfaces were fully covered with grafted PMAA chains. Then, at a fixed grafted amount, the grafted layer can absorb more water and the grafted PE plates possessed higher tensile shear adhesive strength, in case grafting was carried out at lower monomer concentrations. Surface properties depended on the density of carboxyl group at the surfaces of grafted layers, whereas adhesive properties depended on the structural properties of grafted chains as well as on the density of carboxyl group of the whole grafted layers.     

Chemical composition of 14C in airborne release from the Tokai reprocessing plant, Japan

Fuel reprocessing plant is one of the most important sources of anthropogenic (14)C in the environment. A method was developed to determine the amount and chemical composition of airborne (14)C release from the Tokai reprocessing plant, Japan. Effluent monitoring using this method showed most of the (14)C is released in CO(2) form and the ratio of (14)C in hydrocarbons to the total is less than 3%, not depending on the type of fuel reprocessed. This finding would provide improved understanding on dynamical behaviour of (14)C in the environment and assessment of radioecological impact from nuclear fuel cycle.     

Interaction model between elastic objects for haptic feedback considering collisions of soft tissue

The simulation of organ–organ interaction is indispensable for practical and advanced medical VR simulator such as open surgery and indirect palpation. This paper describes a method to represent real-time interaction between elastic objects for accurate force feedback in medical VR simulation. The proposed model defines boundary deformation of colliding elements based on temporary surface forces calculated by temporary deformation. The model produces accurate deformation and force feedback considering collisions of objects as well as prevents unrealistic overlap of objects. A prototype simulator of rectal palpation is constructed on general desktop PC with a haptic device, PHANToM. The system allows users to feel different stiffness of a rear elastic object located behind another elastic object. The results of experiments confirmed the method expresses organ–organ interaction in real-time and produces realistic and perceivable force feedback.     

Coherence and polarization of electromagnetic beams modulated by random phase screens and their changes on propagation in free space

The spectral degree of coherence and of polarization of some model electromagnetic beams modulated by a polarization-dependent phase-modulating device, such as a liquid-crystal spatial light modulator, acting as a random phase screen are examined on the basis of the recent theory formulated in terms of the 2 x 2 cross-spectral density matrix of the beam. The phase-modulating device is assumed to have strong polarization dependence that modulates only one of the orthogonal components of the electric vector, and the phase of the phase-modulating device is assumed to be a random function of position imitating a random phase screen and is assumed to obey Gaussian statistics with zero mean. The propagation of the modulated beam is also examined to show how the spectral degrees of coherence and of polarization of the beam change on propagation, even in free space. The results are illustrated by numerical examples.     

Effect of non-aqueous phase liquid on biodegradation of PAHs in spilled oil on tidal flat

Biodegradation rates of polycyclic aromatic hydrocarbons (PAHs) in spilled oil stranded on tidal flats were evaluated using model reactors to clarify the effects of non-aqueous phase liquid (NAPL) on the biodegradation of PAHs in stranded oil on tidal flat with special emphasis on the relationship between dissolution rates of PAHs into water and viscosity of NAPL. Biodegradation of PAHs in NAPL was limited by the dissolution rates of PAHs into water. Biodegradation rate of chrysene was smaller than that of acenaphtene and phenanthrene due to the smaller dissolution rates. Dissolution rates of PAHs in fuel oil C were smaller than those in crude oil due to high viscosity of fuel oil C. Hence, biodegradation rates of PAHs in fuel oil C were smaller than those in crude oil. Biodegradation rates of PAHs in NAPL with slow rate of decrease like fuel oil C was slower than those in NAPL with rapid rate of decrease like crude oil. The smaller rate of decrease of fuel oil C than crude oil was due to the higher viscosity of fuel oil C. Therefore, not only the dissolution rate of PAHs but also the rates of decrease of NAPL were important factors for the biodegradation of PAHs.     

Multiphoton ionization mass spectrometry of chlorophenols as indicators for dioxins

Mono-, di- and trichlorophenols were measured using resonance-enhanced multiphoton ionization mass spectrometry (MPI-MS) combined with supersonic jet (SSJ) or effusive molecular beam (EMB) spectrometry. All mono- and dichlorophenols, except 2,6-dichlorophenol, provided sharp and structured MPI spectra for the S1 <-- S0 transition. Selectivity and sensitivity were both enhanced when SSJ spectrometry was used, compared with EMB spectrometry, because of a narrower linewidth in the MPI spectrum, given by molecular cooling by supersonic jet expansion. The ionization efficiency decreased with increasing number of chlorine substituents for the chlorophenols, since they have shorter excited-state lifetimes and require three photons for ionization. Some of the chlorophenols, which are toxic themselves, have the potential for use as indicators for analysis of polychlorinated dibenzo-p-dioxin/dibenzofurans in flue gases emitted from an incinerator.     

Efficient Verification of Parallel Real–Time Systems

This paper presents an efficient model checking algorithm for one–safe time Petri nets and a timed temporal logic. The approach is based on the idea of (1) using only differences of timing variables to be able to construct a finite representation of the set of all reachable states and (2) further reducing the size of this representation by exploiting the concurrency in the net. This reduction of the state space is possible, because the considered linear–time temporal logic is stuttering invariant. The firings of transitions are only partially ordered by causality and a given formula; therefore the order of firings of independent transitions is irrelevant, and only one of several equivalent interleavings has to be generated for the evaluation of the given formula. In this paper the theory of timing verification with time Petri nets and temporal logic is presented, a concrete model checking algorithm is developed and proved to be correct, and some experimental results demonstrating the efficiency of the method are given.     

Development of advanced power system analog simulator

The digital simulation method has been utilized to analyze phenomena in power systems. Since different algorithms can be applied, depending on the phenomena to be analyzed, digital simulation allows for high-precision analysis. However, it also has a disadvantage: it produces continuous phenomena which occur in actual systems only fragmentarily. Thus, when discussing important projects at research centers such as IREQ in Canada, an analog simulator issued to continuously analyze the phenomena from the moment the fault occurs until steady state. These analog simulators, however, consist of only a few generator models. They are only effective for analyzing phenomena in small-scale systems and do not allow for analysis of phenomena in large-scale systems over a long period of time. For this reason, the Kansai Electric Power Company (KEPCO) in cooperation with Hitachi, Ltd., and Fuji Electric Co., Ltd., has developed the world's largest power system simulator (APSA: Advanced Power System Analyzer). The simulator will be used to analyze the evolution of accidents in actual systems and to analyze continuous system phenomena over a long period. This paper describes an outline of the simulator.