Deflection of wafers and cantilevers with Pt/LNO/PZT/LNO/Pt/Ti/SiO2 multilayered structure

The present paper describes a Pt/LNO/PZT/LNO/Pt/Ti/SiO₂ multilayers deposited on 4-inch Si wafers. We have evaluated the variation of the deflection of the Si wafers with deposition of each of the thin films. The deposition of the multilayers has resulted in downward deflection (center is higher than edge) of the Si wafers. The multilayers have been also deposited onto SOI wafers and fabricated into piezoelectric micro cantilevers through MEMS bulk micromachining. The micro cantilevers have shown the upward deflection. We have characterized the ferroelectric and piezoelectric properties of the PZT thin films through electrical tests of the micro cantilevers. The dielectric constant, saturation polarization, remanent polarization and coercive field were measured to be 1050, 31.3 μC/cm², 9.1 μC/cm² and 21 kV/cm, respectively. The transverse piezoelectric constant, d₃₁, was measured to be − 110 pm/V from the DC response of the micro cantilevers.     

Spark plasma sintering technique for reaction sintering of Al2O3/Ni nanocomposite and its mechanical properties

Al₂O₃/Ni nanocomposites were prepared by spark plasma sintering (SPS) using reaction sintering method and the mechanical properties of the obtained nanocomposites are reported. The starting materials of Al₂O₃–NiO solid solution were synthesized from aluminum sulfate and nickel sulfate. These Al₂O₃–NiO powders were changed into Al₂O₃ and Ni phases during sintering process. The obtained nanocomposites showed high relative densities (>98%). SEM micrographs showed homogeneously dispersed Ni grains in the matrix. The 3-point strength and the fracture toughness of the composites significantly improved from 450 MPa in the monolithic α-Al₂O₃ to 766 MPa in the 10 mol% (2.8 vol.%) Ni nanocomposite and from 3.7 to 5.6 MPa m^1/2 in 13 mol% (3.7 vol.%) Ni nanocomposite. On the other hand, Young's modulus and Vickers hardness of the nanocomposites were mostly same as those of the monolithic α-Al₂O₃.     

在线超临界流体萃取-超高效液相色谱-光电二极管检测器联用分析胡椒粉中的胡椒碱

本文介绍的联用分析系统是将超临界流体萃取（SFE）系统与超高效液相色谱（UHPLC）系统联用。使用在线SFE-UHPLC系统,可以完成对胡椒粉中胡椒碱成分的高速萃取和分析。整个分析过程包括萃取时间在内只需要7min。将此方法的萃取回收率与其他萃取方法进行比较,SFE方法得到的回收率与其他方法相当。这种在线SFE-UHPLC方法操作简单,分析速度快。这一方法对于分析固体样品中的化合物组分非常有用,可以有效避免繁琐的样品预处理过程。     

Real-time photodisplacement microscope for high-sensitivity simultaneous surface and subsurface inspection

We have developed a new photodisplacement microscope system for practical use that achieves high-sensitivity simultaneous real-time imaging of surface and subsurface structures from a single space-frequency multiplexed interferogram. In this system a linear region of photothermal displacement is excited on the sample surface for subsurface imaging by a line-focused intensity-modulated laser beam. Surface information such as reflectivity and topography along with the displacement is detected with a charge-coupled device sensor-based parallel heterodyne interferometer. Surface and subsurface information components are space-frequency multiplexed into the sensor signal as orthogonal functions based on a frequency-optimized undersampling scheme, allowing each to be discretely reproduced by using a real-time Fourier analysis technique. Preliminary experiments demonstrate that this system is effective, simultaneously imaging reflectivity, topography, and photodisplacement for the detection of subsurface lattice defects in silicon, at a remarkable speed of only 0.26 s/256x256 pixel area. This new microscope is promising for nondestructive hybrid surface and subsurface inspection and other applications.     

Grinding-induced residual stress estimation by indentation-fracture method in ground silicon nitrides

An estimating procedure for grinding-induced residual stress based on the indentation-fracture (IF) method was proposed by considering a nonuniform distribution of residual stress in the specimen depth. The proposed procedure was applied to gas pressure sintered and pressureless sintered silicon nitride ceramics, which were ground under different grinding conditions. The estimated residual stress was found to be compressive for both materials. The residual stress was dominantly affected by the grit size of the grinding wheel rather than the cutting depth. Although the dependency of the estimated residual stress on the grit size was different between the two materials, it was revealed that the estimated residual stress in both materials qualitatively corresponded with the stress measured by the x-ray diffraction method. In both materials, the bending strength was reasonably correlated with the estimated residual stress. It was elucidated that the proposed procedure was applicable to a relative evaluation of the grinding-induced residual stress in machined silicon nitride ceramics.     

In Situ Measurements of Frictional Bridging Stresses in Alumina Using Fluorescence Spectroscopy

Fracture of a large-grained alumina polycrystal has been examined in situ by optical microscopy. Concurrently, local bridging stresses, as generated by friction or tension of unbroken ligaments in the wake of the crack path, were measured by piezospectroscopy. Stress measurements were performed both at fixed sites as a function of the external load and at a fixed external load along the crack profile. Frictional stresses were similar/congruent50 MPa, while unbroken ligaments between the crack faces were found to support tensile stresses up to similar/congruent100 MPa. The maximum bridging stress was dictated by the weak (intrinsic) interface bonding of the polycrystal. Average bridging stresses, either theoretically calculated from R -curve data or experimentally measured by piezospectroscopy on frictional/bridging sites, were similar. Such a circumstance enables us to explain the fracture behavior of polycrystalline alumina by considering crack-wake shielding as the main micromechanism contributing to toughening.     

Mechanical properties of ultrahigh-molecular-weight polyethylene fiber-reinforced PE composites

Three types of high-strength polyethylene (PE) fiber-reinforced composite sheets were made by compression molding at the vicinity of melting point of the fiber. Sheet I was molded from only PE fibers. Sheets II and III were prepared by the compression molding of PE fiber with conventional high- and low-density polyethylene films, respectively. The mechanical properties, thermal behavior, and morphologies of the sheets have been investigated and compared with each other. The tensile strength and elastic modulus of sheet III are 660 MPa and 14 GPa, respectively, which were 60 and 30 times higher than those of typical low-density PE film. Although the elastic modulus of sheet III is 6 GPa less than that of sheet II, the tensile strength of 660 MPa is highest in the three types of sheets prepared in this study. The mechanical properties of sheets II and III were about half of predicted theoretical ones. It was concluded that the interfacial adhesion between PE fiber and PE matrix was an important factor to improve the mechanical properties of this PE sheet. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 68: 1431–1439, 1998     

Quick-response torque control of induction motor with robustness against variations of primary and secondary resistances

This paper proposes a novel quick-response torque control strategy of an induction motor, which is robust against variations of primary and secondary resistances. Conventional field-oriented control originally is robust against the variation of the primary resistance, but has very high parameter sensitivity of the secondary resistance. To compensate for its effect, considerable research has been conducted by using a stator voltage model, a low-sensitivity flux observer, an adaptive system, and so on. It is assumed that successful results have not been made in practice because each method requires not only complicated configurations but also motor parameters. Therefore its compensation has to be carried out with no relation to the motor parameter, especially the primary resistance. In this paper, a robust parameter-identification technique is applied to a field-oriented control system with a flux simulator as a means to solve the problem. The technique is based on instantaneous reactive power which is never affected by the primary resistance. The authors describe the aforementioned control theory and practical implementation. As a result, excellence performance was confirmed by some computer simulations and experimental tests. © 1997 Scripta Technica, Inc. Electr Eng Jpn, 118 (2): 30–40, 1997     

Characteristics of Introduction of Fatty Acids into Gajutsu (Curcuma zedoaria Roscoe) and Teppǒ-yuri (Lilium longiflorum Thunb.) Starches

Starch granules, normally, contain naturally occurring lipids which are firmly embraced in starch granules and hardly extractable with Et₂O. In this paper, the characteristics of introduction of free fatty acids (FFAs) into Gajutsu (Curcuma zedoaria), Teppǒ-yuri (Lilium longiflorum) and potato starches, being very low in the above “embraced lipids” contents (9.2-25.6 mg%), were investigated. It was found that the saturated FFAs were more abundantly introduced into them (41.2-174.7 mg%) than the unsaturated ones (15.9-46.5 mg%), and the respective starches differed from one another in capacity of introducing each FFA. There was also found some characteristic changes in pasting feature after introduction of FFAs depending upon the respective starches. Furthermore, their Nägeli-amylodextrins were prepared as a model of their crystalline protion and were subjected to introduction of FFAs. On these results, a possible distributing diagram of the introduced FFAs in a granule of the respective starch was proposed.