不同有机物对硝酸盐氮测试的影响

研究了红糖、葡萄糖、乙酸钠、甲醇、乙醇、乙酸、丙酸、丁酸、正戊酸、混合有机溶剂等10种不同有机物对麝香草酚光谱法和离子色谱法测试硝酸盐氮的影响。结果表明,溶液中含有红糖或葡萄糖时,均会对麝香草酚法测试硝酸盐氮造成影响,使得测试结果偏大;在无硝酸根离子存在时,红糖和葡萄糖的质量浓度与硝酸盐氮的测试浓度非线性相关;而乙酸钠、甲醇、乙醇、乙酸、丙酸、丁酸、正戊酸和混合有机溶剂则对麝香草酚法测试硝酸盐氮没有影响。实验发现,红糖和葡萄糖在浓硫酸的作用下与麝香草酚发生Molisch反应,形成有色复合物和红棕色不溶性沉淀。实验采用离子色谱法测试硝酸盐氮时,红糖和葡萄糖等糖类有机物对测试结果均无影响。     

Personality expression and recognition in Chinese language usage

User Modeling and User-Adapted Interaction - Personality plays a pivotal role at work. Many scholars have investigated the association between personality and language usage habits in the English...     

Unveiling the role of Fe3O4in polymer spin valve near Verwey transition

The spinterface formed between ferromagnetic(FM)electrode and organic materials is vital for performance optimization in organic spin valve(OSV).Half-metallic Fe₃O₄with drastic change in structure,conductivity and magnetic property near Verwey transition can serve as an intrinsic spinterface regulator.However,such modulating effect of Fe₃O₄in OSV has not been comprehensively investigated,especially below the Verwey transition temperature(Tv).Here,we highlight the important role of Fe₃O₄electrode in reliable-working and controllable Fe₃O₄/P3HT/Co polymer spin valves by investigating the magnetoresistance(MR)above and below 7V.In order to distinguish between different contributions to charge transport and related MR responses,the systematic electronic and magnetic characterizations were carried out in full temperature range.Particularly,the first-order metal-insulator transition in Fe₃O₄has a dramatic effect on the MR enhancement of polymer spin valves at 7V.Moreover,both the conducting mode transformation and MR line shape modulation could be accomplished across 7V.This research renders unique scenario to multimodal storage by external thermodynamic parameters,and further reveals the importance of spin-dependent interfacial modification in polymer spin valves.     

Anchoring single Pt atoms on hollow Ag3VO4 spheres for improved activity towards photocatalytic H2 evolution reaction

The high cost of noble metal catalysts has been a great bottleneck for the catalyst industry. Using the noble metal at a single-atom level for catalytic applications could dramatically decrease the cost. The impacts of single Pt atoms on the photocatalytic performance of Ag₃VO₄ have been investigated and reported. In this report, single Pt atoms were anchored on the surface of Ag₃VO₄ (AVO) as a cocatalyst, and the resultant composite photocatalyst has been studied for photocatalytic H₂ production from water driven by visible light. The as-prepared AVO particles are hollow nanospheres in the monoclinic phase with a bandgap of 2.20 eV. The light absorption edge of AVO/Pt is slightly red-shifted compared to that of the pristine AVO, indicating more visible light absorption of AVO/Pt. The XPS peaks of Ag, V, and Pt exhibit a significant shift after AVO and Pt get into contact, suggesting the strong interaction between the surface Ag and V atoms, and single Pt atoms. After 3-h illumination, the photocatalytic H₂ evolution amount from AVO/Pt is improved up to 1400 μmol, which is 2.8 times that on the bare AVO. Such efficient photocatalytic H₂ evolution on AVO/Pt is still maintained after five reaction cycles. The better photocatalytic performance of AVO/Pt has been attributed to the more efficient visible light utilization and the lower interfacial charge transfer resistance, as demonstrated in the DRS and EIS spectra. The presence of the surface Pt atoms also leads to a higher amount of reactive radicals, which could efficiently promote the surface redox reactions.     

一种基于Spark的不确定数据集频繁模式挖掘算法

如何在海量不确定数据集中提高频繁模式挖掘性能是目前研究的热点.传统算法大多是以期望、概率或者权重等单一指标为数据项集支持度，在大数据背景下，同时考虑概率和权重支持度的算法难以兼顾其执行效率.为此，本文提出一种基于Spark的不确定数据集频繁模式挖掘算法（UWEFP），首先，为了同时兼顾数据项的概率和权重，计算一项集的最大概率权重值并进行剪枝；然后，为了减少对数据集的多次扫描，结合Spark框架的优点，设计了一种具有FP-tree特征的新颖的UWEFP-tree结构进行模式树的构建及挖掘；最后在Spark环境下，以UCI数据集进行实验验证.实验结果表明本文的方法在保证挖掘结果的同时，提高了效率.     

基于机器视觉技术的古陶瓷器型三维还原算法

器型研究对于古陶瓷的真伪鉴别、价值认知和其文化类型与传播途径的研究具有重要的意义.本文在研究和解决了复杂背景下旋转体古陶瓷轮廓提取、图像畸变校正、轮廓线非线性建模等一系列技术难题的基础上,研究并实现了一套古陶瓷器型三维还原算法.通过该算法利用旋转体古陶瓷的二维图像建立了精确的轮廓模型,进而实现器型的三维建模.最终试验结果表明,该三维建模算法可以精确获取旋转体古陶瓷三维器型模型,对探索古陶瓷器型研究发展新方向有一定意义.     

智能型电子式变频电动执行器及其应用

针对原有电动执行器只有以低速运行，通过极强的微调才能修正微小偏差这一缺点，提出智能型电动执行器与各种阀体譬合，利用数字化变频技术，改造目前采用模拟技术的电动执行器，使之具有变速运行、动态响应块，调节定位精度高、稳定性好，故障率低、使用寿命长和应用场合广泛的特点。     

IDS告警融合与关联模型的研究

入侵检测是保障网络安全的重要手段,针对现有入侵检测系统中告警数量多、协调性差等问题,论文提出了一种具有告警融合与关联功能的告警处理系统模型,该模型冗余告警量少、整体检测能力强,并能进行攻击企图的预测,能有效提高入侵检测的效率,有助于进一步增强网络的健壮性。