Copolymerization of phenylacetylene with various acetylenes by W- and Mo-based catalysts

In the copolymerization of phenylacetylene with various acetylenes catalysed by WCl₆·Ph₄Sn, the relative reactivity of monomer decreased with increasing steric effect of monomer, e.g. HC  Cn-Bu, HC  Cn-Hex > HC  CPh, HC  Cs-Bu > HC  Ct-Bu, MeCCPh, CICCPh. While 1-chloro-2-phenylacetylene (a disubstituted acetylene) showed high reactivity in the homopolymerization by Mobased catalysts, the reactivity was remarkably depressed in the presence of phenylacetylene as comonomer. Based on these results, the relative reactivity of the acetylenic monomers in copolymerization was explained in terms of competitive coordination of monomers to the propagating end.     

Estimating potential disaster waste generation for pre-disaster waste management

The paper discusses development of a method for estimating disaster waste that can be potentially generated by a natural disaster in the future for pre-disaster waste management. In particular, this research focuses on micro-disaster waste originating from household consumer durables. We documented the number of household consumer durables and built a mass per unit database of major consumer durables using web-based and statistical surveys. We also estimated present and future figures of disaster waste that can be generated in the study area. The estimated total amount of disaster waste that could be generated in 2015 was 24.1 kt (18.1–29.8 kt) and 108 kt (81.8–133 kt) for Kobe City and Ise-Shima region, respectively. The total quantities of TV sets, air conditioners, refrigerators, and washing machines generated in Kobe and Ise-Shima will range between 10.9 and 22.8 kt (247,000–545,000 units) in 2015, and 10.7 kt to 22.8 kt (249,000–550,000 units) in 2035. The quantity estimated for 2015 is equal to 61 % of the annual processing capacity of Plant A, Japan’s leading home appliances recycling plant. Finally, we discussed the contribution of the estimation results and geographic information systems in future recycling planning.     

Interference suppression with adaptive multipath control technique for broadband private wireless access systems

Proposed is an adaptive multipath control technique to suppress interference radiation from a transmitter to the non-target receivers for broadband private wireless access systems. In the proposed scheme, deep and wide creation techniques are employed in the adaptive array antenna to effectively use a limited number of antenna degrees of freedom under rich scattering indoor channel conditions. Computer simulation confirms that the proposed scheme is very effective in control of the transmit antenna directivity to suppress interference radiation, thereby the interference to the non-target receivers is largely reduced, and BER performance is greatly improved with low outage probability.     

Discrete finger and palmar feature extraction for personal authentication

A practical method for a noncontacting and real-time feature extraction for personal authentication is proposed. The finger geometry and feature extraction of the palmar flexion creases are integrated into a small number of discrete points based on the anatomical observation. For a video image of either palm, a palm placed freely facing toward a video camera is acquired. The fingers are brought together, and the palm is straightened out to eliminate any constraints. The discrete feature points for the fingers involve intersection points of the three finger (digital) flexion creases on the four finger skeletal lines. The feature points for the palm involve intersection points of the major palmar flexion creases and/or prominent creases of the palm on the extended finger skeletal lines. The orientations of the creases at the intersection points are also extracted features to be matched. The matching results are perfect for about 500 palm samples from 50 subjects so far. This discrete point processing, requiring no time-consumptive palmprint image analysis and requiring less than one second processing time, will contribute to a noncontacting, real-time and reliable feature extraction, easily combinable with other traits, for the personal authentication.     

Impact of Multimedia Traffic Characteristics on ATM Network Configuration

This paper proposes a new topological designmethod, named BXCQ, which optimizes logical networkconfiguration while guaranteeing Quality-of-Service(QoS) requirements for each service class in an ATMnetwork. The BXCQ method determines the optimum logicalnetwork topology associated with each service class soas to minimize network cost. In our previously proposedFull-Net architecture these different logical topologies can be suitably mapped at the sametime on the same ATM physical network by using theVirtual Channel Handler (VCH) to create differentlogical interconnection networks. The BXCQ method allows us to clarify the relations between multimediatraffic characteristics and desirable logical networkconfigurations in Full-Net. Evaluation results suggestthat a service class that is bursty, delay tolerant, and cell loss sensitive with small demandshould be supported by a loop-like topology. This studywill be useful for designing flexible and cost-effectivemultimedia networks that can also adapt to not-yet-known services.     

Applications of Thermoelectric Power Measurement to Deterioration Diagnosis of Nuclear Material and Its Principle

In order to non-destructively evaluate changes in toughness of cast duplex stainless steel, which is frequently used in main coolant pipes of PWR type nuclear power plants, due to thermal aging, we tried to apply thermoelectric power (TEP) measurement. because TEP is sensitive to microstructural material changes, and to clarify the mechanism behind TEP changes due to thermal aging. As a result, TEP of cast duplex stainless steel increased with aging time, and good correlations were found between TEP and toughness. Concerning the mechanism, TEP of high and low Cr content alloys was higher than that of intermediate Cr content alloys. Because high and low Cr areas are created in the ferrite phase due to thermal aging. TEP of the entire material increased. Furthermore, when each Cr fluctuating area acted in parallel, the increase in TEP became larger. According to the Mott-Jones theory, TEP is largely related to the electron density of states at the Fermi level. The electron density of states of Fe–Cr–Ni alloys in the valence band was measured with X-ray photoelectron spectroscopy (XPS). As a result, there was a high correlation between the TEP calculated from the XPS spectrum and the measured TEP. Therefore, we showed experimentally that the electron density of states changed due to variations in Cr concentration, which also affect TEP.     

Diphenyl Carbonate Synthesis by Homogeneous Pd Electrocatalyst

Electrochemical carbonylation of phenol with CO to diphenyl carbonate (DPC) using Pd electrocatalyst was studied at P(CO) = 1 atm and room temperature. Electrochemical carbonylation was conducted by galvanostatic electrolysis at 1 mA in electrolyte solutions containing phenol, sodium phenoxide and CH₃CN. It was found that electrochemical carbonylation by Pd was promoted by using 1,3-dimesitylimidazol-2-ylidene (IMes) ligand of a N-heterocyclic carbene. The current efficiency of DPC increased more than 3.4 times using the IMes ligand. The maximum current efficiency of DPC formation was 45 %.     

Production of thin graphite sheets for a high electrical conductivity film by the mechanical delamination of ternary graphite intercalation compounds

Herein we propose a production scheme for conductive films composed of thin graphite sheets with high crystallinity and polymeric resin. The crystalline graphite sheets were successfully produced from natural graphite powder by solution-phase synthesis of graphite intercalation compounds (GICs), following a wet planetary-ball milling under mild conditions. The shear forces in the milling pot lead to a peeling of graphite flakes. Taking into consideration the interlayer bonding force, the delamination should be preferentially done from the expanded GICs interlayer rather than intrinsic graphite one. Some composite films derived from the phenolic resin and flaky graphite sheets displayed much higher electrical conductivities compared to the film from the feed graphite particles. We also demonstrate the stage structure of synthetic GICs affected the film conductivity. The composite films made from exfoliated products of ground (around stage IV) GICs exhibited high electrical conductivity with a small amount of the graphite sheets.