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随着油田投入生产,许多油田基本上已进入中后期阶段,特点是高含水率、高采出率,开发难度变大,但大量剩余油依然存在于地下,并且分布更加零碎和繁琐,现在油田勘探的主要目的便是为了精确地呈现出剩余油的分布,进而提高采收率。为了实现这个目标,需要开展精细油藏描述,为勘探开发决策提供有力支持。根据王龙庄断块已有的井位、井斜、测井、录井等资料,以储层综合评价为基础,建立了王龙庄断块的三维地质模型,运用了比传统方法更先进的细分层方法进行建模,形成了精细油藏描述的三维可视化,最后对模型中5个主要的含油小层进行储量计算,再与原始测量得到的储量对比。王龙庄断块原始储量为116×104 t,拟合储量为121.11×104 t,拟合相对误差4.2%。计算结果表明,王龙庄断块储量拟合误差在允许范围之内。 相似文献
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针对核电厂运行期间核一级手动截止阀唇边焊易发生泄露的风险,要求阀门需要进行整体更换,分别对核级阀门两种规格的接头开展自动脉冲TIG焊接工艺研究,并对焊后的试件进行渗透、X射线探伤等无损检验和拉伸、弯曲、金相、化学分析和晶间腐蚀等破坏性检验。试验结果表明,壁厚2.77 mm的焊接接头拉伸力平均值为564 MPa,断后伸长率平均值为39.25%;壁厚8.7 mm的焊接接头拉伸力平均值为612 MPa,断后伸长率平均值为46.75%,两种壁厚的焊接接头均具有良好的力学性能,面弯试验和背弯试验均未发现裂纹,弯曲性能良好;壁厚2.77 mm接头的金相组织主要是板条状铁素体,壁厚8.7 mm接头的金相组织主要以树枝状铁素体为主;两种壁厚的焊接接头中熔敷金属的化学成分经检验均满足技术条件的规定;采用弯曲法进行晶间腐蚀试验,经检验两种规格的接头均无晶间腐蚀倾向。 相似文献
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Extending the metal to insulator transitions of rare-earth nickelates towards low temperature ranges
Jian Zhong Ziang Li Yunqi Zheng Peiheng Jiang Fang Zhang Ting Zhang Yuchen Cui Zhicheng Zhong Nuofu Chen Jikun Chen 《Journal of the American Ceramic Society》2023,106(8):5067-5077
Although the d-band correlated rare-earth nickelates (ReNiO3) exhibit broadly adjustable metal to insulator transitions (MIT) that enables emerging correlated electronic applications, it is yet difficult to regulate their associated critical temperature (TMIT) below 100 K. Herein, we extend the lower limit in TMIT of ReNiO3 down to 83 K while maintaining an abrupt switch in resistivity via partial La-substitution of PrNiO3. The near edge X-ray fine structure analysis and density function theory calculations indicate the strengthening in the metallic orbital configuration and reduction in the ground state band gap via La-substitution of Re in NdNiO3 and PrNiO3. In contrast, analogous Ce substitution cannot reduce the TMIT of ReNiO3 owing to its valance variability toward +4, while La partial substitution of ReNiO3 with middle or heavy rare-earth (e.g., Sm) easily disturb the co-occupation of the Re-site by the two rare-earths as one dispersive phase. 相似文献
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Li Liu Ziang Meng Xiaoning Wang Hongyu Chen Zhiyuan Duan Xiaorong Zhou Han Yan Peixin Qin Zhiqi Liu 《Advanced functional materials》2023,33(48):2308938
The recent claim on the discovery of ambient-pressure room-temperature superconductivity in Cu-doped lead-apatite has attracted sensational attention. The intriguing compound has been fabricated by sintering lanarkite (Pb2SO5) and copper(І) phosphide (Cu3P). To verify this exciting claim, Pb2SO5, Cu3P, and finally the modified lead-apatite Pb10−xCux(PO4)6O have been successfully synthesized. Detailed electrical transport and magnetic properties of these compounds are systematically analyzed. It turns out that Pb2SO5 is a highly insulating diamagnet and Cu3P is a paramagnetic metal. The obtained nominal Pb10−xCux(PO4)6O compound sintered from Pb2SO5 and Cu3P exhibits semiconductor-like transport behavior with a large room-temperature resistivity of ≈1.94 × 104 Ω·cm, although the major phase of the compound shows consistent X-ray diffraction spectrum with the previously reported structure data. In addition, when a Pb10−xCux(PO4)6O pellet pressed from uniformly ground powder is located on top of a commercial Nd2Fe14B magnet at room temperature, no repulsion can be felt and no magnetic levitation is observed either. The large difference in electrical and magnetic properties between the compounds and the previously reported compounds might be induced by distinct fine crystallographic structures, diverse multi-phase distributions, and different concentrations of impurity phases such as Cu2S, all of which deserve further study. 相似文献
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Ziang Meng Han Yan Peixin Qin Xiaorong Zhou Xiaoning Wang Hongyu Chen Li Liu Zhiqi Liu 《Advanced functional materials》2023,33(46):2305225
Topotactic transition is a structural phase change in a matrix crystal lattice mediated by the ordered loss/gain and rearrangement of atoms, leading to unusual coordination environments and metal atoms with rare valent states. As early as in 1990s, low temperature hydride reduction is utilized to realize the topotactic transition. Since then, topological transformations are developed via multiple approaches. Especially, the recent discovery of the Ni-based superconductivity in infinite-layer nickelates has greatly boosted the topotactic transition mean to synthesizing new oxides for exploring exotic functional properties. In this review, a detailed and generalized introduction is provided to oxygen-related topotactic transition. The main body of the review includes four parts: the structure-facilitated effects, the mechanism of the topotactic transition, some examples of topotactic transition methods adopted in different metal oxides (V, Mn, Fe, Co, Ni) and the related applications. This study is to provide timely and thorough strategies to successfully realize topotactic transitions for researchers who are eager to create new oxide phases or new oxide materials with desired functions. 相似文献