Theoretical calculation of product contents: battery and cathode ray tube examples

Most product environmental assessments are based on manufacturer-supplied data on the material content of the product. This paper explores the potential for the material content of key components to be estimated with theoretical calculations. Two examples, the amount of cadmium in a nickel-cadmium battery and the amount of lead in a TV or computer CRT monitor, are developed. Both an upper and a lower limit on the amount of cadmium in a nickel-cadmium battery are calculated on the basis of the battery's chemical reaction. The amount of lead shielding needed in a TV or CRT computer monitor is estimated on the basis of the potential difference through which electrons are accelerated and the absorption length of photons in lead. Such calculations can be used as benchmarks in product environmental assessments, providing validation of manufacturer-supplied data and providing insight into the composition and design of products.     

Chemical Defenses of the Sacoglossan Mollusk Elysia rufescens and Its Host Alga Bryopsis sp.

Sacoglossans are a group of opisthobranch mollusks that have been the source of numerous secondary metabolites; however, there are few examples where a defensive ecological role for these compounds has been demonstrated experimentally. We investigated the deterrent properties of the sacoglossan Elysia rufescens and its food alga Bryopsis sp. against natural fish predators. Bryopsis sp. produces kahalalide F, a major depsipeptide that is accumulated by the sacoglossan and that shows in vitro cytotoxicity against several cancer cell lines. Our data show that both Bryopsis sp. and Elysia rufescens are chemically protected against fish predators, as indicated by the deterrent properties of their extracts at naturally occurring concentrations. Following bioassay-guided fractionation, we observed that the antipredatory compounds of Bryopsis sp. were present in the butanol and chloroform fractions, both containing the depsipeptide kahalalide F. Antipredatory compounds of Elysia rufescens were exclusively present in the dichloromethane fraction. Further bioassay-guided fractionation led to the isolation of kahalalide F as the only compound responsible for the deterrent properties of the sacoglossan. Our data show that kahalalide F protects both Bryopsis sp. and Elysia rufescens from fish predation. This is the first report of a diet-derived depsipeptide used as a chemical defense in a sacoglossan.     

An additional antecedent of empathic concern: Valuing the welfare of the person in need.

Two experiments examined the role of valuing the welfare of a person in need as an antecedent of empathic concern. Specifically, these experiments explored the relation of such valuing to a well-known antecedent--perspective taking. In Experiment 1, both perspective taking and valuing were manipulated, and each independently increased empathic concern, which, in turn, increased helping behavior. In Experiment 2, only valuing was manipulated. Manipulated valuing increased measured perspective taking and, in part as a result, increased empathic concern, which, in turn, increased helping. Valuing appears to be an important, largely overlooked, situational antecedent of feeling empathy for a person in need. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The validity of a game-based assessment of persistence

In this study, 154 students individually played a challenging physics video game for roughly 4 h. Based on time data for both solved and unsolved problems derived from log files, we created a game-based assessment of persistence that was validated against an existing measure of persistence. We found that the game-based assessment of persistence predicted learning of qualitative physics after controlling for gender, video game experience, pretest knowledge and enjoyment of the game. These findings support the implementation of a real-time formative assessment of persistence to be used to dynamically change gameplay.     

What kind of #conversation is Twitter? Mining #psycholinguistic cues for emergency coordination

The information overload created by social media messages in emergency situations challenges response organizations to find targeted content and users. We aim to select useful messages by detecting the presence of conversation as an indicator of coordinated citizen action. Using simple linguistic indicators drawn from conversation analysis in social science, we model the presence of coordination in the communication landscape of Twitter¹ using a corpus of 1.5 million tweets for various disaster and non-disaster events spanning different periods, lengths of time, and varied social significance. Within replies, retweets and tweets that mention other Twitter users, we found that domain-independent, linguistic cues distinguish likely conversation from non-conversation in this online form of mediated communication. We demonstrate that these likely conversation subsets potentially contain more information than non-conversation subsets, whether or not the tweets are replies, retweets, or mention other Twitter users, as long as they reflect conversational properties. From a practical perspective, we have developed a model for trimming the candidate tweet corpus to identify a much smaller subset of data for submission to deeper, domain-dependent semantic analyses for the identification of actionable information nuggets for coordinated emergency response.     

Predicting missing contacts in mobile social networks

Experimentally measured contact traces, such as those obtained in a conference setting by using short range wireless sensors, are usually limited with respect to the practical number of sensors that can be deployed as well as the number of available human volunteers. Moreover, most previous experiments in this field can report only partial contact information since not everyone participating in the experiment carries a sensor device. Previously collected contact traces have significantly contributed to the development of more realistic human mobility models. This in turn has influenced proposed routing algorithms for Delay Tolerant Networks where human contacts play a vital role in message delivery. By exploiting time-spatial properties of contact graphs as well as the popularity and social information of mobile nodes, we propose a novel method to reconstruct the missing parts of contact graphs where only a subset of nodes are able to sense contacts.     

Guest Editor's Introduction

Journal of Signal Processing Systems -     

Aminofunctional polyethers: smart materials for applications in solution and on surfaces

In recent years, biocompatible polyethers with multi‐aminofunctionality have been used for a variety of applications in different fields. Both established and recently developed synthesis strategies for such polymers and applications as stimuli‐responsive materials, non‐viral vectors, shell crosslinked micelles and for surface functionalization are reviewed. The intriguing potential of such materials is due to both polyether and polyamine components and can thus be readily tuned by the copolymer microstructure and composition. © 2013 Society of Chemical Industry     

Luminescent Conjugated Oligothiophenes for Sensitive Fluorescent Assignment of Protein Inclusion Bodies

Small hydrophobic ligands identifying intracellular protein deposits are of great interest, as protein inclusion bodies are the pathological hallmark of several degenerative diseases. Here we report that fluorescent amyloid ligands, termed luminescent conjugated oligothiophenes (LCOs), rapidly and with high sensitivity detect protein inclusion bodies in skeletal muscle tissue from patients with sporadic inclusion body myositis (s‐IBM). LCOs having a conjugated backbone of at least five thiophene units emitted strong fluorescence upon binding, and showed co‐localization with proteins reported to accumulate in s‐IBM protein inclusion bodies. Compared with conventional amyloid ligands, LCOs identified a larger fraction of immunopositive inclusion bodies. When the conjugated thiophene backbone was extended with terminal carboxyl groups, the LCO revealed striking spectral differences between distinct protein inclusion bodies. We conclude that 1) LCOs are sensitive, rapid and powerful tools for identifying protein inclusion bodies and 2) LCOs identify a wider range of protein inclusion bodies than conventional amyloid ligands.     

Use of dairy proteins in lean poultry meat batters – a comparative study

The use of dry whole milk, skimmed milk, caseinate, regular and modified whey, at 2% level (w/w) and with 2% additional protein level was studied in a chicken breast meat system with 51% water addition. At the 2% (w/w) level, all dairy proteins significantly reduced cooking loss compared with the control, with caseinate showing the best results. When compared on an equal protein level (2% total protein), the best performing ingredients were the whole milk and modified whey. A similar observation was made in their effect on the products’ hardness and fracturability. A cost analysis revealed that modified whey provided the most economical ingredient even when used in quantities three times greater than that of as caseinate. Microscopy results showed the formation of larger fine‐protein‐matrix regions in the treatments that provided higher fracturability values.