Castor oil-based polyurethane coatings containing benzyl triethanol ammonium chloride: synthesis,characterization, and biological properties

In the present work, benzyl triethanol ammonium chloride (BTEAC) was employed as a reactive bactericidal additive for preparing of polyurethane coatings. In this regard, castor oil as a renewable resource-based polyol, polyethylene glycol (PEG1000), and BTEAC were reacted with toluene diisocyanate. Physical, mechanical, and thermal characteristics as well as biocompatibility and antibacterial properties of polyurethanes were evaluated. The prepared polyurethanes showed two-phase structure with soft and hard segments glass transition temperature transitions in the range of 18–70 and 85–153 °C, respectively. Initial modulus and tensile strength were improved for coatings with higher BTEAC content, while elongation at break and thermal stability were decreased. Hydrophilicity of coatings was increased for polyurethanes based on higher content of BTEAC and PEG1000. Polyurethanes with higher BTEAC content showed better cytocompatibility for mouse L929 fibroblast cells. Moreover, coatings with higher hydrophilicity and BTEAC content displayed superior antibacterial activity against both Escherichia coli and Staphylococcus aureus bacteria.     

Memory-efficient real-time map building using octree of planes and points

This paper presents an octree-based map building algorithm for mobile home-service robots. The robot is equipped with a time-of-flight camera, which produces point clouds of the environment surfaces. Given the successive input of point clouds, a 3D map is incrementally computed in real time. The map is accurate and memory-efficient because the octree nodes containing points on a plane are merged and represented simply by an index to the plane. The real-time performance is achieved largely due to the parallel processing capability of the many-core Graphics Processing Unit used for plane extraction.     

Design equations for prediction of pressuremeter soil deformation moduli utilizing expression programming systems

Providing precise estimations of soil deformation modulus is very difficult due to its dependence on many factors. In this study, gene expression programming (GEP) and multi-expression programming (MEP) systems are presented to derive empirical equations for the prediction of the pressuremeter soil deformation modulus. The employed expression programming (EP) systems formulate the soil deformation modulus in terms of the soil physical properties. Selection of the best models is on the basis of developing and controlling several models with different combinations of the affecting parameters. The proposed EP-based models are established upon 114 pressuremeter tests on different soil types conducted in this study. The generalization capabilities of the models are verified using several statistical criteria. Contributions of the variables influencing the soil modulus are evaluated through a sensitivity analysis. The GEP and MEP approaches accurately characterize the soil deformation modulus resulting in a very good prediction performance. The result indicates that moisture content and soil dry unit weight can efficiently represent the initial state and consolidation history of soil for determining its modulus.     

A new mathematical model for integrating all incidence matrices in multi-dimensional cellular manufacturing system

In the past several years, many studies have been carried out on cellular manufacturing based on a two-dimensional machine–part incidence matrix. Since workers have important role in doing jobs on machines, assignment of workers to cells becomes a crucial factor for fully utilization of cellular manufacturing systems. In this paper, an attempt is made to solve cell formation problem and minimize the number of voids and exceptional elements in a three dimensional (cubic) machine–part–worker incidence matrix. The proposed mathematical model captures the capability of workers in doing different jobs. To demonstrate the effectiveness of the proposed model, the solution of some test problems is compared with the literature method.     

Trapping of Free Electrons in Multipole System

In this paper, the effective Parameters in the confinement and trapping of fast electrons in plasma source Such as; plasma pressure, wall material of plasma chamber and magnetic mirror rate have been investigated with using Comsol & Geant4 code. The calculations are shown that the Multicusp magnetic field was effective the pressure less than 5?mTor, and the confinement effect becomes stronger with decreasing pressure. It is equivalent to a higher yield of output ions of plasma source. The number of fast electrons trapped in the magnetic field increases with increasing magnetic field intensity and using aluminum for wall material. Optimum conditions of confinement plasma, leading to increased the hot electron density, and ionization efficiency is increased. The results of investigations have demonstrated good correspondence with theoretical calculations, therefore there is the adequacy of the developed approach and the possibility to build more effective source ion on this basis.     

Energy performance of traditional bath buildings

This paper presents the results of a recent research effort to collect and analyze data pertaining to traditional bath buildings (“hammams”) in Egypt, Turkey, Morocco, Syria, and Algeria. Thereby, the energy performance of and the thermal comfort conditions in five such buildings were studied. Moreover, empirically calibrated building performance simulation models of a number of objects were generated in order to predict the consequences of alternative thermal retrofit measures. The results provide the opportunity for an objective assessment of the actual energy and indoor environmental performance of these buildings.     

Failure of silver nanowire transparent electrodes under current flow

Silver nanowire transparent electrodes have received much attention as a replacement for indium tin oxide, particularly in organic solar cells. In this paper, we show that when silver nanowire electrodes conduct current at levels encountered in organic solar cells, the electrodes can fail in as little as 2 days. Electrode failure is caused by Joule heating which causes the nanowires to breakup and thus create an electrical discontinuity in the nanowire film. More heat is created, and thus failure occurs sooner, in more resistive electrodes and at higher current densities. Suggestions to improve the stability of silver nanowire electrodes are given.     

Study of inhibition effect of carboxylic salt derivative on corrosion of C1010 carbon steel in saline solution

In the present work, sodium 4-[(4-formylbenzylidene) amino] benzoiate (4) was synthesized and its structure was confirmed using spectroscopic techniques. Prepared compound was successfully applied as a corrosion inhibitor for C1010 carbon steel in 3.5% NaCl solution at 25°C. Different electrochemical measurements such as linear polarization resistance (LPR), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) were used to evaluate the suggested inhibitor (4). The results of different electrochemical measurements show that inhibition efficiencies obtained from EIS curves are in consistence with the results of potentiodynamic polarization and LPR measurements due to increase corrosion inhibition efficiency by increasing the concentration of organic inhibitor (4). Semi-empirical calculations with PM3 method were used to find relationship between molecular structure and inhibiting effect of suggested inhibitor (4).     

Preparation of novel 2-(2-oxo-2H-chromen-4-yl)-3- arylthiazolidin-4-one derivatives using an efficient ionic liquid catalyst

An eco-friendly procedure for synthesis of 2-(2-oxo-2H-chromen-4-yl)-3-arylthiazolidin-4-one derivatives by three-component reaction of 2-oxo-2H-chromene-4-carbaldehydes, aromatic amines and thioglycolic acid, with tetramethylbutane-1,4-diammonium acetate as a low-cost ionic liquid catalyst under reflux condition is described. The use of an ionic liquid as a catalyst has the advantages of high yields, short reaction time and environmentally friendly reaction media.     

A Modified Method for the Determination of N‐Nitrosodiethanolamine in Coconut Diethanolamide Using HPLC with Dual‐Wavelength UV–Vis Detector

A simple and novel method based on high‐performance liquid chromatography with dual‐wavelength ultraviolet detection at 234 and 254 nm has been developed for the determination of underivatized N‐nitrosodiethanolamine in coconut diethanolamide. The correlation coefficient obtained shows that the method is correct.