天然气水合物的勘探、开采及环境效应研究进展

天然气水合物是21世纪具有良好前景的重要潜在能源,基于其重大的资源前景和环境效应,得到了全球的高度关注.对天然气水合物的性质及储量、勘探技术、开采技术以及环境效应进行了综述.     

Effect of miscibility and forced compatibility on damping properties of CIIR/PAc blend

In this study, a kind of novel damping materials was prepared based on the blend of chlorinated butyl rubber (CIIR) and polyacrylate (PAc) synthesized by different molar ratio of butyl methacrylate and ethyl acrylate. Research results from experiments and analyses by employing DMA, TEM, and FTIR show that whether at a cocured system or noncocured system, it can be achieved to shift a loss peak of CIIR towards a higher temperature region and to keep the damping value from markedlly decreasing, which broadens the effective damping function area of CIIR to the vicinity of ambient temperature. In the former system, the thermodynamical miscibility of CIIR and PAc, to some extent, is predominated by the molecular design of PAc, while in the latter system, covulcanized networks play a more significant role in improving compatibility and abating the peak split, though the suppression effect of thermal stress on the transition of CIIR T_ll transition still can not be neglected. Furthermore, transition state derived from the cocuring CIIR and PAc cannot make the phase separation completely take place, and consequently results in the deformation of phase morphology of the cocured CIIR/PAc blend. It is the influence of thermodynamics miscibility and forced compatibility in different size that makes the suppression effect of foreign PAc on CIIR T_ll transition be controllable. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3127–3133, 2006     

中浓度气力输送弯管压力降数值模拟研究

对于中等浓度气力输送90°弯管内的气固流动状态进行数值模拟研究,并对水平转垂直、垂直转水平,不同弯径比(R/D=1.5~6.0)的90°弯管,均匀和非均匀粉体颗粒流过弯管的压力降Δp进行了模拟计算。结果表明,在同一气体流速下,不同R/D的弯管的Δp变化显著;存在一个使Δp最小的R/D值。在模拟的条件范围内,弯管内粉体颗粒的速度分布随R/D变化。并讨论了不同R/D的粉体颗粒流动对弯管压力降及管壁磨损的影响。在同样操作条件下,对煤粉输送进行了弯管压力降数据模拟,其模拟计算结果与周建刚等人的试验结果吻合良好。     

2,6-二乙酰基吡啶合成方法的改进

优化了2，6—二乙酰基吡啶的合成工艺。以2，6—吡啶二羧酸为原料，经过醇化及克莱森酯缩合反应，合成了2，6—二乙酰基吡啶，2，6—吡啶二羧酸二乙醇和2，6—二乙酰基吡啶的分离收率分别为94．1％和88．9％，2，6—二乙酰基毗啶的质量分数大于99％。     

聚四氟乙烯烧结成型的制备工艺

对聚四氟乙烯（PTFE）进行了压制试验和烧结试验，讨论了成型压力与试件的致密度、压缩强度以及压缩模量之间的关系，且对不同烧结工艺下试件的压缩强度进行了分析，得到较合适的成型压力和烧结工艺。结果表明：咖材料的压缩强度随压制压力的升高而减小，压缩模量随压制压力的升高而增加；闻的成型压力为27．5MPa，烧结温度380℃，保温时间4h。     

An Attractive Synthetic Approach to Methyl Formate from Methanol via Methyl Nitrite

Catalytic synthesis of methyl formate has been investigated by a novel route starting from methyl nitrite in vapor phase. The acidic sites of the catalysts play a crucial role for the catalytic activity and the selectivity of formation of methyl formate. The H-Y zeolite catalyst gave higher yield and selectivity of the target product. This study provides a new approach for the synthesis of methyl formate from methanol via methyl nitrite.     

水溶性富勒烯衍生物的设计合成及在生物医药中的应用

介绍了水溶性富勒烯衍生物在抗艾滋病、DNA的裂解、消除自由基和抗菌等方面的应用,及一些水溶性富勒烯衍生物的设计合成。     

高速混合法在共混地膜生产中的应用

介绍了在原有吹制LDPE地膜设备上(挤出机长径比为20:1)吹制LDPE、LLDPE和HDPE共混微膜和超薄微膜,采用高速混合法的混料工艺达到了良好的预热效果,弥补了挤出机长径比小的不足。     

基质沥青及聚合物改性沥青的老化研究进展

介绍了国内外沥青包括基质和聚合物改性沥青老化性能的研究方法,涉及沥青宏观层次(力学、流变及组分等)和微观层次(波谱分析及显微技术等)上各技术的应用,并比较了各研究方法的优缺点,综述了沥青的老化机理。     

利用氯碱厂废弃盐泥制备NO3-吸附剂

将氯碱厂废弃盐泥与丙烯酸、钛酸四正丁酯等共聚，过硫酸钾作引发剂，制得TNO3^-吸附剂，同时还得到了有利用价值的二氧化硅和碳酸钙。用正交试验法与单纯形优化法相结合，确定了废弃盐泥制备NO3^-吸附剂的优良配方及合适的工艺。增添了水净化剂的新品种，探索了氯碱工业废弃盐泥利用的新途径。