Polyurea thin film ultrasonic transducers for nondestructive testing and medical imaging

Ultrasonic transducers using polyurea piezoelectric thin film are studied in this paper. Aromatic polyurea thin films, prepared by vapor deposition polymerization, have useful characteristics for use as an ultrasonic transducer. This paper presents the fabrication and experimental evaluation of ultrasonic transducers formed using polyurea films. First, the vapor deposition polymerization process using two monomers is briefly reviewed, and the temperature conditions for higher piezoelectric constants are explored. Second, in order to test the fundamental characteristics of this material as a high-frequency, ultrasonic transducer, a polyurea film of 2.5 microm thickness was deposited on a silicon substrate. In the pulse/echo experiment results, a resonant frequency of about 100 MHz was observed. Third, we fabricated a concave point focus transducer and a cylindrical line focus transducer. To examine the performances of the focus transducers, two-dimensional images of a coin and V(z) curve measurements for an aluminum surface were demonstrated.     

Automatic Extraction of Rules for Anaphora Resolution of Japanese Zero Pronouns in Japanese–English Machine Translation from Aligned Sentence Pairs

This paper proposes a method to extract rules for the anaphora resolution of Japanese zero pronouns in Japanese–English MT from aligned sentence pairs. After aligned sentence pairs unsuitable for rule extraction because of analysis errors or free translations are automatically rejected, zero pronouns in the Japanese sentences and the English translation equivalents of their antecedents are extracted from the remaining Japanese and English aligned sentence pairs using ten hand-developed alignment rules. This method identifies all Japanese zero pronouns whose translation equivalents are not explicitly expressed in an English sentence, this method identifies these as unalignable. Then, resolution rules for the remaining zero pronouns are automatically extracted using the aligned pairs, equivalent word/phrase pairs extracted from the aligned sentence pairs, and the syntactic and semantic structures of the Japanese sentences. This method was implemented in a Japanese–English MT system, ALT-J/E. 98.4% of all pairs were automatically aligned correctly in a window test, and 94.0% in a blind test. Furthermore, extracted rules for zero pronouns with deictic references created automatically from sentence pairs correctly resolved 99.0% of the zero pronouns in a window test and 85.0% of the zero pronouns in a blind test.     

Growth energetics of Lactococcus lactis subsp. lactis biovar diacetylactis in cometabolism of citrate and glucose

Certain strains of lactic acid bacteria present in commercial cheese starters, characterized by faint transparent colonies on an agar plate containing 1 mg kg ⁻¹ crystal violet (CVT), were identified as Lactococcus lactis subsp. (ssp) lactis biovar diacetylactis. The effect of citrate on the growth of these strains (CVT strains) in the presence of glucose was studied, in comparison with L. lactis strains. Molar growth yield from glucose (Y_G, g dry weight/mole of glucose consumed) for CVT strains grown on glucose plus citrate was significantly higher than the control (i.e. without citrate), but not for other L. lactis strains tested. Enhanced Y_G was also observed at a pH-controlled experiment, indicating that enhanced Y_G did not result from a buffering effect of citrate. CVT strains, in contrast to other strains of the same species, were shown to obtain enough energy to enhance Y_G on glucose–citrate mixtures.     

Influence of microwave roasting on positional distribution of fatty acids of triacylglycerols and phospholipids in sunflower seeds (Helianthus annuus L.)

Whole sunflower seeds were exposed to microwave roasting for 6, 12, 20 or 30 min at a frequency of 2450 MHz. The kernels were then separated from the sunflower seeds, and the lipid components and the positional distribution of fatty acids in triacylglycerols (TAGs) and phospholipids (PLs) were investigated. Major lipid components were TAGs and PLs, while steryl esters, free fatty acids and diacylglycerols were also present in minor proportions. The greatest PL losses (p < 0.05) were observed in phosphatidyl ethanolamine, followed by phosphatidyl choline or phosphatidyl inositol. Significant differences (p < 0.05) in fatty acid distributions occurred (with few exceptions) when sunflower seeds were microwaved for 20 min or more. Nevertheless, the principal characteristics for the positional distribution of fatty acids still remained after 20 min of microwave roasting; unsaturated fatty acids, especially linoleic, were predominantly concentrated in the sn‐2‐position and saturated fatty acids, especially stearic and palmitic acids, primarily occupied the sn‐1‐ or sn‐3‐position. These results indicate that no significant changes in fatty acid distribution of TAGs and PLs would occur within 12 min of microwave roasting, ensuring that a good‐quality product would be attained.     

Numerical simulation model for predicting air quality along urban main roads: First report,development of atmospheric diffusion model

A simulation model for predicting air quality along urban main roads is being studied. The objective of the model is to predict the effects on air quality of various road-related parameters such as configurations of roads and surrounding buildings as well as traffic flow, chemical reactions, and other related phenomena. In this paper, the development of an atmospheric diffusion model, which will be the platform of the whole simulation model, is reported. A new concentration diffusion coefficient model is proposed, in which the effect of vehicle wind is taken into account. By comparing with field experiments in which the diffusing tracer gas concentration was measured in a real street canyon, the validity of the simulation model is verified. Also, the new diffusion coefficient model is found to be capable of improving predictive accuracy of air quality around a street canyon. © 1998 Scripta Technica, Heat Trans Jpn Res, 27(7): 483–496, 1998     

The content of tocopherols and oxidative quality of oils prepared from sunflower (Helianthus annuus L.) seeds roasted in a microwave oven

Sunflower seeds ((Helianthus annuus were roasted for 6, 12, 20 or 30 min at a frequency of 2450 MHz using a domestic microwave oven. After the kernels were separated from the sunflower seeds, the quality characteristics and the compositions of the oils were investigated in relation to their tocopherol distributions, and they were further evaluated as compared with an unroasted oil sample. Only minor increases (p < 0.05) in chemical and physical changes of the oils, such as the carbonyl value, the p‐anisidine value and the color development, occurred at a prolonged roasting period. Significant decrease (p < 0.05) was observed in the amounts of phospholipids in the oils after microwave roasting. Nevertheless, compared to the original level, more than 92 wt‐% tocopherols still remained after 30 min of roasting. With a few exceptions, these results indicate that the exposure of sunflower seeds to microwaves for 12 min caused no significant (p < 0.05) loss or change in the content of tocopherols and polyunsaturated fatty acids in the kernels.     

Periodic overhaul planning system for electric power plants

Periodic overhaul planning for boilers and turbines in electric power plants has been done based on expert experience in order to satisfy various constraints that are hard to formalize, such as legal regulations, the overhaul interval restriction between units, the adjustment strategy in the case of including special events, the daily electric power requirement, and so forth. Although computer processing using the knowledge base approach has been tried, it does not lead to good results because of excessive hardware requirements, low performance, and no assurance of optimality. A two‐step approach is proposed based on the categorization of constraints that are hard to formalize into “strong constraints” and “weak constraints.” It replaces the nonlinear integer programming problem corresponding to “strong constraints” by a combination of integer programming and combinatorial analysis. Consequently, it can lead to optimal solution in terms of fuzzy satisfaction measures within an allowable time with a PC. © 1999 Scripta Technica, Electr Eng Jpn, 127(2): 24–31, 1999     

Construction of self‐organizing algorithms for vector quantization

Vector quantization is used for both storage and transmission of speech and image data, and an algorithm that minimizes the distortion error is often required. To obtain the minimum distortion error in neural networks for vector quantization, corrective competitive learning has been introduced. In a large number of algorithms, self‐creating neural networks and self‐deleting neural networks have performed well. In this paper, we improve the self‐deleting neural network and propose a generalized algorithm combining the creating and deleting neural networks. First, a few weight (reference) vectors are prepared, the self‐creating algorithm is applied, and vectors are created automatically. Next, the self‐deleting algorithm is applied, and weight vectors are deleted sequentially to reach a predetermined number. Experimental results show the effectiveness of the proposed algorithm. © 1999 Scripta Technica, Electr Eng Jpn, 127(1): 47–55, 1999     

Slab optical waveguide high-acidity sensor based on an absorbance change of protoporphyrin IX

A sensitive and fast-responsive evanescent wave absorption sensor has been constructed for pH measurements in highly acidic ranges. This sensor is based on a pH-dependent color change of protoporphyrin IX (PPIX). For the sensitive detection, a visible attenuated total reflection spectrometer with a slab optical waveguide (SOWG) was laboratory-made, and the guiding layer surface was modified with a PPIX-immobilized acrylamide-based thin membrane. The sensing membrane with a thickness of approximately 1 mum was directly fabricated on the SOWG glass surface by copolymerization of acrylamide, N,N'-methylene bisacrylamide, and PPIX in the narrow space confined by a cover plate. PPIX possesses two double bonds in its structure, and so it can be covalently incorporated into the membrane. The response characteristics of the PPIX-immobilized optode membrane were explored using aqueous solutions with different concentrations of HNO(3) or HCl. The optode membrane provided characteristic Soret band absorption spectra depending on the hydrogen ion concentration; the absorbance at 410 nm increased with increasing the concentrations in the range of 0.15-2 M, corresponding to the range of pH -0.3 to 0.8. The absorption signal reached 90% of its final value within 10 s, while the absorption signal was quite readily returned to background level simply by passing 2 mL of distilled water through a flow cell with a volume of 16.5 muL placed on the SOWG. Due to the rapid response and reversibility, this sensor could be operated in a flow-through mode as well as in a conventional static mode, where deionized water was conveniently used as a carrier and conditioning solution. In terms of the stability and precision, this sensor showed no significant change in response even after 100 assays and after being stored in a dry condition for over 6 months. Relative standard deviations for 10 replicate measurements were less than 1.8% in the linear range, and the detection limit calculated from 3 times of the standard deviation was 0.02 pH unit.     

Preparation of high-performance optical coatings with fluoride nanoparticle films made from autoclaved sols

An ultralow refractive index is very advantageous when one designs antireflective coatings. We successfully obtained high-quality MgF2 thin films with ultralow refractive indices from autoclaved sols prepared from magnesium acetate and hydrofluoric acid. The MgF2 films consist of nanosized particles, and they have high laser-exposure durability at 193 nm. The reflectance of the antireflective coating with five layers, of which the top layer is formed by our method, is lower than 0.6% in the incident angle range of 0 degrees - 60 degrees at 193 nm.