铜离子注入Ti6Al7Nb合金的表面改性研究

使用MEVVA强流金属源离子注入机对Ti6Al7Nb合金表面注入能量为80keV、剂量分别为0.5×1017,1×1017,2×1017,4×1017ions/cm2的铜离子,计算得到铜离子饱和注入量为2.15×1017ions/cm2。研究了注入的铜离子对Ti6Al7Nb合金腐蚀性能、显微硬度和磨损行为的影响,采用覆膜法研究了铜离子注入后试样对金黄色葡萄球菌的抗菌性能,并分析了注入剂量与抗菌性能的关系。结果表明,Ti6Al7Nb合金的硬度和耐磨性随着注入剂量的增加而提高,点蚀电位随着注入剂量的提高而下降。抗菌试验显示当注入量达到饱和注入量时,试样的抗菌率达到99%以上。     

消除铸件内应力应注意的几个问题

在对湖南、江西等厂调研的基础上,结合笔者多年的经验,提出了灰铸铁生产中,消除铸件内应力时应注意的几个问题.生产中只有严格控制加热速度、加热温度、保温时间以及冷却速度,才能有效地消除铸件内应力,保证产品质量.     

基于CAN总线DZY300型运梁车转向系统设计与工程实现

本文介绍了上海磁悬浮工程专用DZY300型运梁车的转向系统设计原理与实现过程。以CAN总线为基础，来实现转角信号的实时检测和电液比例阀的远端控制；从而利用总线通讯技术，实现了大闭环控制系统。在采用经典PID控制律时，针对工程实际情况进行了改进。理论充分与实际相结合，保证调节实时性的同时，有效地解决了转向系统中出现的超调振荡、反复微调节和调节不平稳现象。     

The improvement of thermal error modeling and compensation on machine tools by CMAC neural network

In this paper, a cerebellar model articulation controller (CMAC) neural network is proposed for thermal error modeling in machine tools. The CMAC is a systematic learning algorithm which can search for the nonlinear and interaction characteristics between the thermal errors and temperature field on the machine tools. The CMAC is investigated in terms of accuracy in prediction, robustness to sensor placement, speed of learning, and tolerance to sensor failures. Experimental measurements of the spindle drift errors for both a horizontal machining center and a CNC turning center were performed using capacitance sensors and thermal sensors. Results show that the CMAC model has better performance than other modeling methods in robustness to sensor placement and speed of learning. This makes determination of the sensor locations easier, and reduces calibration time. In addition, a sensor failure detection algorithm is developed to provide better reliability.     

搅拌摩擦加工(FSP)AZ91D镁合金的组织分析

研究了AZ91D镁合金经搅拌摩擦加工后的组织。发现组织中搅拌摩擦区、热机械影响区和热影响区分区不明显。在搅拌摩擦区主要为再结晶形成的细小均匀的等轴晶结构,共晶组织α-Mg β相(Mg17Al12)完全均匀化,仅在晶界处有少量存在。     

盐浴硫氮碳共渗45钢的接触疲劳性能

对４５钢经盐浴硫氮碳共渗处理的大批试样，进行了滚子接触疲劳性能试验，绘出了Ｐ－Ｓ－Ｎ曲线，分析了接触疲劳断口形貌及破坏机理。     

La0.6Sr0.4Co1-yFeyO3钙钛矿复合氧化物的结构与电学性能

采用固相反应法合成出La0.6Sr0.4Co1-yFeyO3体系复合氧化物样品，XRD分析结果证实不同Co／Fe比例的样品中均形成菱形六面体钙钛矿结构，采用固相烧结法制备出致密的La0.6Sr0.4Co1-yFeyO3体系陶瓷。研究结果表明，在室温到900℃温度范围内La0.4Sr0.4CoO3(y=0)的电导率随温度的增加而单调降低，其它Co／Fe比例样品的电导率随着温度的增加出现最大值，电导率达到最大值的温度随Co／Fe比例的降低而提高。在低温段，La0.6Sr0.4Co1-yFeyO3体系的导电行为符合小极子导电机制，导电活化能随Co／Fe比例的降低而增加。     

Gd2O2S：Ti的长余辉性能研究及机理探讨

利用高温固相法合成了一种长余辉发光材料Gd2O2S：Ti，利用XRD测试了其结构并测试了其在紫外光激发下的发光特性；停止照射，有橙色的余辉，时间接近2h。分析该磷光体的发光和余辉产生细节，认为空穴和电子的复合导致Ti^3＋的^2E→^2T2的跃迁是产生发光和余辉的原因；并根据缺陷和空位对Gd2O2S：Ti的余辉机理进行探讨，提出了余辉机理模型。     

La0．8Ca0．2CrO3钙钛矿复合氧化物的GNP法合成与表征

采用GNP（Glycine-Nitrate Process）法合成La0.8Ca0.2CrO3初级粉料，研究甘氨酸用量对产物的晶体结构和显微形貌的影响，并测试烧结体的相对密度和电导率。研究结果表明，甘氨酸与金属离子的摩尔比（G／M^n＋）控制在2．0～2．5时可得到颗粒尺寸细小、均匀（100nm～200nm）的单相钙钛矿粉体，烧结温度为1350℃时样品的相对密度达到91．0％，测试温度为800℃时样品的电导率达到30．5S.cm^-1。与常规固相法相比，GNP法制备的样品具有更好的烧结活性和导电性能。     

Nanostructured component fabrication by electron beam-physical vapor deposition

Fabrication of cost-effective, nano-grained net-shaped components has brought considerable interest to Department of Defense, National Aeronautics and Space Administration, and Department of Energy. The objective of this paper is to demonstrate the versatility of electron beam-physical vapor deposition (EB-PVD) technology in engineering new nanostructured materials with controlled microstructure and microchemistry in the form of coatings and net-shaped components for many applications including the space, turbine, optical, biomedical, and auto industries. Coatings are often applied on components to extent their performance and life under severe environmental conditions including thermal, corrosion, wear, and oxidation. Performance and properties of the coatings depend upon their composition, microstructure, and deposition condition. Simultaneous co-evaporation of multiple ingots of different compositions in the high energy EB-PVD chamber has brought considerable interest in the architecture of functional graded coatings, nano-laminated coatings, and design of new structural materials that could not be produced economically by conventional methods. In addition, high evaporation and condensate rates allowed fabricating precision net-shaped components with nanograined microstructure for various applications. Using EB-PVD, nano-grained rhenium (Re) coatings and net-shaped components with tailored microstructure and properties were fabricated in the form of tubes, plates, and Re-coated spherical graphite cores. This paper will also present the results of various metallic and ceramic coatings including chromium, titanium carbide (TiC), titanium diboride (TiB₂), hafnium nitride (HfN), titanium-boron-carbonitride (TiBCN), and partially yttria stabilized zirconia (YSZ) TBC coatings deposited by EB-PVD for various applications. This paper was presented at the International Symposium on Manufacturing, Properties, and Applications of Nanocrystalline Materials sponsored by the ASM International Nanotechnology Task Force and TMS Powder Materials Committee, October 18–20, 2004, Columbus, OH.