Post Consumer Pet Depolymerization by Acid Hydrolysis

The reaction of post-consumer poly(ethylene terephthalate) with aqueous solutions of sulfuric acid 7.5 M was investigated in terms of temperature, time and particle size. The reaction extent reached 80% in four days at 100°C and 90% in 5 hours at 135°C. TPA obtained was purified and considered in the same level of quality of the commercial one after tests of elemental analysis, particle size and color. It was concluded that the hydrolysis occurred preferentially at the chain ends and superficially, having as controller mechanism the acid diffusion into the polymer structure. The shrinking-core model can explain the reaction kinetics.     

Laminar,transitional and turbulent friction factors for gas flows in smooth and rough microtubes

Theoretical and experimental works on microscale transport phenomena have been carried out in the past decade in the attempt to analyze possible new effects and to assess the influence of downscaling on the classical correlations which are used in macro-scale heat and fluid flow, following the need to supply engineers with reliable tools to be used in the design of micro-scale devices. These results were sometimes in mutual contrast, as is the case for the determination of the friction factor, which has been found to be lower, higher or comparable to that for macroscopic channels, depending on the researchers. In this work the compressible flow of nitrogen inside circular microchannels from 26 μm to 508 μm in diameter and with different surface roughness is investigated for the whole range of flow conditions: laminar, transitional and turbulent. Over 5000 experimental data have been collected and analysed. The data confirmed that in the laminar regime the agreement with the conventional theory is very good in terms of friction factors both for rough and smooth microtubes. For the smaller microchannels (<100 μm) when Re is greater than 1300 the friction factor tends to deviate from the Poiseuille law because the flow acceleration due to compressibility effects gains in importance. The transitional regime was found to start no earlier than at values of the Reynolds number around 1800. Both smooth and sudden changes in the flow regime have been found, as reported for conventional tubes. Fully developed turbulent flow was attained with both smooth and rough tubes, and the results for smooth tubes seem to confirm Blasius' relation, while for rough tubes the Colebrook–White correlation is found to be only partially in agreement with the experimental friction factors. In the turbulent regime the dependence of the friction factor on the Reynolds number is less pronounced for microtubes than the prediction of the Colebrook–White correlation and the friction factor depends only on the microtube “relative roughness”.     

Metabolites from the biodegradation of di-ester plasticizers by Rhodococcus rhodochrous

The plasticizers di-2-ethylhexyl phthalate (DEHP) and di-2-ethylhexyl adipate (DEHA) are ubiquitous in the environment and undergo partial biodegradation in the presence of soil micro-organisms. The validity of a proposed pathway for the degradation of these plasticizers by Rhodococcus rhodochrous has been confirmed by the identification of 2-ethylhexanal in gas phase emissions. Complete analyses of the aqueous and gas phases were able to account for more than 98% of the 2-ethylhexanol component of the DEHA added at the beginning of a growth study. Of this, 25% was either 2-ethylhexanol or 2-ethylhexanal that had been stripped into the gas phase and, at most, only 2% of the 2-ethylhexanol component could have been removed by mineralization. It is concluded that plasticizers are of significant environmental concern due to the resistance of the metabolites to biodegradation and their known health impacts. Two of the metabolites are of added concern due to their volatility and their potential impact on indoor air quality.     

Obesity and Male Reproduction: Do Sirtuins Play a Role?

Obesity is a major current public health problem of global significance. A progressive sperm quality decline, and a decline in male fertility, have been reported in recent decades. Several studies have reported a strict relationship between obesity and male reproductive dysfunction. Among the many mechanisms by which obesity impairs male gonadal function, sirtuins (SIRTs) have an emerging role. SIRTs are highly conserved nicotinamide adenine dinucleotide (NAD+)-dependent deacetylases that play a role in gene regulation, metabolism, aging, and cancer. SIRTs regulate the energy balance, the lipid balance, glucose metabolism, and adipogenesis, but current evidence also indicates a role for SIRTs in male reproduction. However, the majority of the studies have been conducted in animal models and very few have been conducted with humans. This review shows that SIRTs play an important role among the molecular mechanisms by which obesity interferes with male fertility. This highlights the need to deepen this relationship. It will be of particular interest to evaluate whether synthetic and/or natural compounds capable of modifying the activity of SIRTs may also be useful for the treatment of obesity and its effects on gonadal function. Although few studies have explored the role of SIRT activators in obesity-induced male infertility, some molecules, such as resveratrol, appear to be effective in modulating SIRT activity, as well as counteracting the negative effects of obesity on male fertility. The search for strategies to improve male reproductive function in overweight/obese patients is a challenge and understanding the role of SIRTs and their activators may open new interesting scenarios in the coming years.     

Preparation,characterization, and antimicrobial activity of ferrocene-containing polymeric materials

Ferrocenyl(benzyl) imidazole (FcIm) and two related methyl-imidazolium salts (FcMIm⁺I^– and FcMIm⁺PF₆^–) were synthesized for their incorporation into plasticized PVC by solvent casting technique. The obtained materials were investigated for their thermal stability and, compared to pure polymer, films containing ionic ferrocene derivatives in 0.5% w/w loading were found slightly more stable. The pure ferrocene compounds showed antibacterial activity against Staphylococcus epidermis, but not against Escherichia coli, with a maximum for FcMIm⁺PF₆^– salt. After incorporation into PVC polymer, antibacterial activity against S. epidermis was observed (by disk diffusion test) only for PVC/FcMIm⁺PF₆^– (5% w/w) film, from which a release of 14.6% of the ferrocenilimidazolium cation in aqueous medium was measured after 24 hr.     

Cognitive radio signal classification based on subspace decomposition and RBF neural networks

Spectrum sensing is one of the major challenges for commercial development of cognitive radio systems, since the detection of the presence of a primary user is a complex task that requires high reliability. This work proposes a signal classifier capable of detecting and identifying a primary user signal on a given channel of the radio spectrum. The proposed approach combines eigen-decomposition techniques and neural networks not only to decide about the presence of a primary user, but also to identify the primary user signal type, a feature that is not encountered in the current approaches proposed in literature. Besides the advantage of identifying the primary user type, the proposed method also considerably reduces the computational cost of the detection process. The proposed classification method has been applied to the development of five primary user signal Classification Modules, which includes wireless microphone, orthogonal frequency-division multiplexing and Digital Video Broadcasting-Terrestrial signals. The results show that the proposed classifier correctly detects and identifies the primary users, even under low signal to noise ratio and multipath scenarios.     

Canonical kernel representations for behaviors over finite Abelian groups

In this paper the problem of constructing canonical kernel representations for systems whose alphabet set is an Abelian group is addressed. In standard linear system theory, there exist two important canonical kernel representations: minimal and row reduced kernel representations. In this paper we propose an extension of such canonical kernel representations to the group case. This topic has applications in the theory of convolutional codes over groups where kernel representations correspond to syndrome formers which are essential in decoding.     

Semantic image interpretation of gamma ray profiles in petroleum exploration

This paper presents the S-Chart framework, an approach for semantic image interpretation of line charts; and the InteliStrata system, an application for semantic interpretation of gamma ray profiles. The S-Chart framework is structured as a set of knowledge models and algorithms that can be instantiated to accomplish chart interpretation in all sorts of domains. The knowledge models are represented in three semantic levels and apply the concept of symbol grounding in order to map the representation primitives between the levels. The interpretation algorithms carry out the interaction between the high-level symbolic reasoning, and the low-level signal processing. In order to demonstrate the applicability of the S-Chart framework, we developed the InteliStrata system, an application in Geology for the semantic interpretation of gamma ray profiles. Using the developed application, we have interpreted the charts of two gamma ray profiles captured in petroleum exploration wells, indicating the position of stratigraphic sequences and maximum flooding surfaces. The results were compared with the interpretation produced by an experienced geologist using the same data input. The system carried out interpretation that were compatible with the geologist interpretation over the data. Our framework has the advantage of allowing the integration of existing domain ontologies with domain independent visual knowledge models and also the ability of grounding domain concepts in low-level data.