Compound-specific chlorine isotope analysis: a comparison of gas chromatography/isotope ratio mass spectrometry and gas chromatography/quadrupole mass spectrometry methods in an interlaboratory study

Chlorine isotope analysis of chlorinated hydrocarbons like trichloroethylene (TCE) is of emerging demand because these species are important environmental pollutants. Continuous flow analysis of noncombusted TCE molecules, either by gas chromatography/isotope ratio mass spectrometry (GC/IRMS) or by GC/quadrupole mass spectrometry (GC/qMS), was recently brought forward as innovative analytical solution. Despite early implementations, a benchmark for routine applications has been missing. This study systematically compared the performance of GC/qMS versus GC/IRMS in six laboratories involving eight different instruments (GC/IRMS, Isoprime and Thermo MAT-253; GC/qMS, Agilent 5973N, two Agilent 5975C, two Thermo DSQII, and one Thermo DSQI). Calibrations of (37)Cl/(35)Cl instrument data against the international SMOC scale (Standard Mean Ocean Chloride) deviated between instruments and over time. Therefore, at least two calibration standards are required to obtain true differences between samples. Amount dependency of δ(37)Cl was pronounced for some instruments, but could be eliminated by corrections, or by adjusting amplitudes of standards and samples. Precision decreased in the order GC/IRMS (1σ ≈ 0.1‰), to GC/qMS (1σ ≈ 0.2-0.5‰ for Agilent GC/qMS and 1σ ≈ 0.2-0.9‰ for Thermo GC/qMS). Nonetheless, δ(37)Cl values between laboratories showed good agreement when the same external standards were used. These results lend confidence to the methods and may serve as a benchmark for future applications.     

Terahertz tomographic imaging of XVIIIth Dynasty Egyptian sealed pottery

A monochromatic millimeter-wave imaging system coupled with an infrared temperature sensor has been used to investigate historic objects preserved at the Museum of Aquitaine (France). In particular, two-dimensional and three-dimensional analyses have been performed in order to reveal the internal structure of nearly 3500-year-old sealed Egyptian jars.     

Instrument for close-to-process light scatter measurements of thin film coatings and substrates

Scatter analysis is an effective method for the characterization of thin film components. The new highly sensitive table top system ALBATROSS-TT (3D-Arrangement for Laser Based Transmittance, Reflectance and Optical Scatter Measurement-Table Top) has been developed at the Fraunhofer Institute in Jena to meet the specific requirements for close-to-process applications. Extremely high sensitivity with a noise equivalent angle resolved scatter level of 2×10(-8)?sr(-1), full three-dimensional spherical measurement capability, and an instrument size as small as 0.8?m×0.8?m×0.8?m have been achieved. Details of specifications, optical components, and software are presented, including a comparison to our laboratory system. Anisotropy analysis of diamond-turned aluminum substrates as well as substrate and coating characterization are demonstrated as examples of application.     

Electronic properties of polyvinylpyrrolidone at the zinc oxide nanoparticle surface

We investigated the electrical effects of polyvinylpyrrolidone (PVP), used as a dispersion agent in zinc oxide (ZnO) nanodispersions. We found PVP reduces the high surface conductivity and atmospheric sensitivity. Compared with polymer free ZnO thin films, the nanoparticulate layers with PVP exhibit a smaller density of thermally active charge carriers, a reduced density of trap states, and a Fermi level shift toward the valence band, yielding improved performance, vanishing hysteresis characteristics and reduced atmospheric sensitivity in thin film transistors (TFT). In addition, we discuss the attachment of PVP to the ZnO surface.     

Ferromagnetism in Ga0.90Mn0.10As1 − yPy: From the metallic to the impurity band conduction regime

The magnetic properties of low temperature MBE grown Ga_0.90Mn_0.10As_1 − yP_y films with 0 < y < 0.20 have been studied as a function of the phosphorous content. The films are ferromagnetic for all phosphorous compositions. For y < 0.15 the conductivity type is metallic but above y > 0.15 it changes to impurity band conduction (IBC). In the IBC regime the main magnetic properties are profoundly modified: the saturation magnetization decreases from typically 50 emu/cm³ to 35 emu/cm³, the critical temperature drops sharply from 130 K to 45 K and the uniaxial magnetic anisotropy spectroscopy is strongly reduced.     

An examination of the mechanisms for stable foam formation in activated sludge systems

Screening pure cultures of 65 mycolic acid producing bacteria (Mycolata) isolated mainly from activated sludge with a laboratory based foaming test revealed that not all foamed under the conditions used. However, for most, the data were generally consistent with the flotation theory as an explanation for foaming. Thus a stable foam required three components, air bubbles, surfactants and hydrophobic cells. With non-hydrophobic cells, an unstable foam was generated, and in the absence of surfactants, cells formed a greasy surface scum. Addition of surfactant converted a scumming population into one forming a stable foam. The ability to generate a foam depended on a threshold cell number, which varied between individual isolates and reduced markedly in the presence of surfactant. Consequently, the concept of a universal threshold applicable to all foaming Mycolata is not supported by these data. The role of surfactants in foaming is poorly understood, but evidence is presented for the first time that surfactin synthesised by Bacillus subtilis may be important.     

Scale-dependency of macroinvertebrate communities: responses to contaminated sediments within run-of-river dams

Due to their nutrient recycling function and their importance in food-webs, macroinvertebrates are essential for the functioning of aquatic ecosystems. These organisms also constitute an important component of biodiversity.Sediment evaluation and monitoring is an essential aspect of ecosystem monitoring since sediments represent an important component of aquatic habitats and are also a potential source of contamination. In this study, we focused on macroinvertebrate communities within run-of-river dams, that are prime areas for sediment and pollutant accumulation. Little is known about littoral macroinvertebrate communities within run-of-river dam or their response to sediment levels and pollution. We therefore aimed to evaluate the following aspects: the functional and structural composition of macroinvertebrate communities in run-of-river dams; the impact of pollutant accumulation on such communities, and the most efficient scales and tools needed for the biomonitoring of contaminated sediments in such environments. Two run-of-river dams located in the French alpine area were selected and three spatial scales were examined: transversal (banks and channel), transversal × longitudinal (banks/channel × tail/middle/dam) and patch scale (erosion, sedimentation and vegetation habitats). At the patch scale, we noted that the heterogeneity of littoral habitats provided many available niches that allow for the development of diversified macroinvertebrate communities. This implies highly variable responses to contamination. Once combined on a global ‘banks’ spatial scale, littoral habitats can highlight the effects of toxic disturbances.     

雷文斯本学院新办公楼

雷文斯本学院以电子媒体与设计著称,其新办公楼坐落在格林威治半岛,位于总平面南北中轴线的右侧,O2建筑西南边界与之接壤,建筑面积21500m2。建筑新址非常特别,雷文斯本旨在满足21世纪学生们对于教育的新要求:希望获得更多的知识资源,希望随     

用无线传感器组成无线传感器网络

物联网的愿景之一是能够测量以前从未测量过的变量。无论应用是监视基础设施老化(例如桥梁、隧道或电力传输线的老化),还是实时提供停车及交通信息,都需要无线传感器网络(WSN)提供与有线网络类似的性能,而且适合实际部署。传感器网络要能够扩展至包含大量无线节点,而且在很多情况下,需要跨越很长的距离。     

GaInAsP semiconductor laser amplifiers for single-mode fiber communications

Gain, polarization sensitivity, saturation power, and noise characteristics of quaternary semiconductor laser amplifiers of the Fabry-Perot (FP) and traveling-wave (TW) types are reviewed. The status of antireflection coatings for TW amplifiers is presented. New results concerning the polarization sensitivity and output saturation power of a 1.5-μm buried-heterostructure (BH) amplifier are reported. A theoretical model is presented concerning the influence of the waveguide structure on the maximum internal gain of a CW-operating 1.5- μm BH amplifier, including thermal effects, and a comparison of this model with recent experimental results is reported. The influence of nonresonant losses on the noise factor of 1.5-μm amplifiers is discussed.