全文获取类型
收费全文 | 538篇 |
免费 | 33篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 5篇 |
化学工业 | 150篇 |
金属工艺 | 7篇 |
机械仪表 | 17篇 |
建筑科学 | 19篇 |
矿业工程 | 3篇 |
能源动力 | 98篇 |
轻工业 | 75篇 |
水利工程 | 5篇 |
石油天然气 | 2篇 |
无线电 | 23篇 |
一般工业技术 | 69篇 |
冶金工业 | 24篇 |
原子能技术 | 4篇 |
自动化技术 | 71篇 |
出版年
2024年 | 4篇 |
2023年 | 8篇 |
2022年 | 8篇 |
2021年 | 19篇 |
2020年 | 18篇 |
2019年 | 17篇 |
2018年 | 23篇 |
2017年 | 23篇 |
2016年 | 20篇 |
2015年 | 14篇 |
2014年 | 28篇 |
2013年 | 53篇 |
2012年 | 35篇 |
2011年 | 42篇 |
2010年 | 46篇 |
2009年 | 29篇 |
2008年 | 41篇 |
2007年 | 42篇 |
2006年 | 23篇 |
2005年 | 11篇 |
2004年 | 4篇 |
2003年 | 11篇 |
2002年 | 5篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 6篇 |
1998年 | 13篇 |
1997年 | 1篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1980年 | 1篇 |
1976年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有572条查询结果,搜索用时 15 毫秒
21.
Carbon black (CB) obtained from used car tire rubbers were treated with concentrated sulfuric and nitric acids. The oxidized CB (CB‐COO‐Na+) is subsequently modified with epichlorohydrin (ECH) and amines including polyethylene imine (PEI). These modified CBs such as CB‐PEI are used as metal‐free catalysts in methanolysis of sodium borohydride (NaBH4) to produce hydrogen. The hydrogen generation rate (HGR) of 3089 ± 44.69 mL.min‐1.g‐1 is accomplished at room temperature with CB‐PEI‐hydrochloric acid (HCl) catalyst. The resulting activation energy of 34.7 kJ/mol for the temperature range of ?20°C to +30°C compares favorably to most of alternative catalysts reported in literature while reaction catalyzing capabilities of CB‐PEI‐HCl particles extend to the subzero temperature range (?20°C‐0°C). The reuse and regeneration studies conducted for the CB‐PEI‐HCl catalyst showed that these catalysts do provide complete conversion at every use up to five consecutive runs and retain 50 ± 2.5% of the original hydrogen generation rate at the fifth consecutive reuse. The CBs‐based catalysts are fully regenerated with HCl treatment. 相似文献
22.
Ezgi Mehteroğlu Ayşe B. Çakmen Büşra Aksoy Sevgi Balcıoğlu Süleyman Köytepe Burhan Ateş İsmet Yılmaz 《应用聚合物科学杂志》2020,137(40):49217
In this study, the synthesis and application of biocompatible steviol glycosides based polyurethane/poly (ε-caprolactone) (PU/PCL) fibers was performed by electrospinning as a potential wound dressing materials that can be used for the closure of nonhealing wounds. During electrospinning, steviol glycoside-based polyurethane structures were used in blend formation with poly (ε-caprolactone) for easy producibility. Steviol glycosides are a natural abundant and easily accessible source as the main component of the wound dressing material due to their free hydroxyl groups, high biocompatibility, and hydrophilicity. The structure of steviol glycosides is composed of saccharide units and the free OH groups. Thus, steviol glycosides act as a crosslinker within the polyurethane structure and provides mechanical strength. For the production of steviol glycosides based PU/PCL fibers first, the steviol glycosides as a monomer were isolated from the stevia rebudiana. Then, polyurethane structures containing stevia glycoside were synthesized with hexamethylene diisocyanate, lactose and PEG-200 by solution polymerization technique. PCL was added to the prepared polyurethanes in a ratio of 1:2 and formation of nanofiber structure. The prepared wound dressing material was characterized by Fourier transform infrared, atomic force microscopy, and scanning electron microscope techniques. Swelling degree, water content and oxygen permeability assay of the steviol glycosides based PU/PCL wound dressing material was determined. In biocompatibility test, cell viability value of PU/PCL fibrous materials in indirect cytotoxicity test was determined as 86.9% and cell adhesion on hybrid PU/PCL fibers was showed as morphological. In accordance with this target, the steviol glycosides based PU/PCL wound dressing material can be produced easily and low cost. As a result, the wound dressing materials obtained with their high biocompatibility and low costs will be an effective and fast method for the healing of open wounds of diabetics. 相似文献
23.
24.
25.
The purpose of this research was to determine the effects of the packaging materials and size on the stability of monomeric anthocyanins, polyphenols, antioxidant activity, ascorbic acid, colour index and hydroxyl methyl furfural (HMF) during the 12‐month shelf life of sour cherry nectars at 4 °C and 20 °C. Sour cherry nectars were aseptically filled out into packaging of different sizes and materials. The packaging included cartons of two different sizes (200 and 1000 mL) and aluminium cans (330 mL). Results showed that the nectars were of better quality when stored at lower temperatures. HMF generally increased significantly for all nectars during storage. Conversely, the total polyphenol content and the antioxidant activity of the nectars stored in aluminium cans and the larger‐sized carton packaging decreased during storage. Lower anthocyanin loss and colour change were found in the nectars stored in aluminium cans. However, the better packaging material was found to be the large‐sized carton package when HMF was analysed. 相似文献
26.
Ayşe Saygün Neşe Şahin-Yeşilçubuk Necla Aran 《Journal of the American Oil Chemists' Society》2014,91(9):1521-1530
Yarrowia lipolytica is known to have the ability to assimilate hydrophobic substrates like triglycerides, fats, and oils, and to produce single-cell oils, lipases, and organic acids. The aim of the present study was to investigate the effects of different oil sources (borage, canola, sesame, Echium, and trout oils) and oil industry residues (olive pomace oil, hazelnut oil press cake, and sunflower seed oil cake) on the growth, lipid accumulation, and lipase and citric acid production by Y. lipolytica YB 423-12. The maximum biomass and lipid accumulation were observed with linseed oil. Among the tested oil sources and oil industry residues, hazelnut oil press cake was the best medium for lipase production. The Y. lipolytica YB 423-12 strain produced 12.32 ± 1.54 U/mL (lipase activity) of lipase on hazelnut oil press cake medium supplemented with glucose. The best substrate for citric acid production was found to be borage oil, with an output of 5.34 ± 0.94 g/L. The biotechnological production of valuable metabolites such as single-cell oil, lipase, and citric acid could be achieved by using these wastes and low-cost substrates with this strain. Furthermore, the cost of the bio-process could also be significantly reduced by the utilization of various low-cost raw materials, residues, wastes, and renewable resources as substrates for this yeast. 相似文献
27.
Degradation kinetics of PVC plasticized with different plasticizers under isothermal conditions 下载免费PDF全文
The aim of the present work is to elucidate the degradation kinetics of polyvinyl chloride (PVC) plasticized with some phthalate and nonphthalate plasticizers. A PVC thermomat instrument was utilized to maintain the isothermal degradation conditions at 140 and 160°C, and to suppress the oxidative degradation by means of nitrogen flow. The conductivity measurements were performed to follow hydrogen chloride (HCl) gas which is released upon PVC degradation and trapped in water. Dehydrochlorination of plasticized PVC films occurred with activation energies of about 23–160 and 26–117 kJ mol?1 and the isokinetic temperatures, at which the dehydrochlorination rate constants of all p‐PVC films would have the same value, were found to be 171 and 128°C for initial and linear regions of dehydrochlorination curve, respectively. Plasticizer incorporation contributes to the stability of the films particularly after the consumption of stabilizer due to the dehydrochlorination. Influence of temperature rise by 20°C on the degradation rate constant is the lowest for DINCH having p‐PVC films as 0.36 and 0.42% increment at the initial region and linear region, respectively. On the other hand, DOTP reveals greater stability than the others do since the compensation ratio of the PVC film having DOTP is greater than the other films. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41579. 相似文献
28.
In this study, bentonite originating from Turkey (Eski?ehir province) and activated carbon obtained from grapeseed were used as adsorbents for the removal of lead (Pb2+) and copper (Cu2+) ions from aqueous solutions. Experiments were performed in single- and binary-ion systems at constant temperature of 298 K and pH value of 5. In order to describe the adsorption mechanism Langmuir, Freundlich and Temkin isotherms were used. The total adsorption capacity values of adsorbents were compared. It was observed that the total adsorption capacity values were changed depending on the type of adsorbent used, type of metal ion and interaction between metal ions. 相似文献
29.
Melek Akman Makbule Bilge Akbulut Mehmet Burak Güneşer Ayçe Ünverdi Eldeniz 《Journal of Adhesion Science and Technology》2016,30(5):459-467
To evaluate the effect of intracanal medicaments on the push-out bond strength of Biodentine in comparison with DiaRoot BioAggregate (BA) when used as apical plugs. Forty single-rooted teeth were prepared using Peeso reamers. The samples were divided into four groups. The intracanal medicaments were applied to the root canals as follows: Group1: a combination of metronidazole–ciprofloxacin–cefaclor, Group2: a combination of metronidazole–ciprofloxacin, Group3: calcium hydroxide, and Group4: no medication. After 21 days, the medicaments were removed. The apical part of each root was horizontally sectioned into 1-mm thick slices. The samples were divided into two subgroups, and the following materials were placed: Biodentine, DiaRoot-BioAggregate. After 48-h incubation, the push-out bond strength was measured. The data were analyzed by a two-way ANOVA. Biodentine showed a significantly higher mean push-out bond strength value than DiaRoot-BioAggregate (P = 0.00). The medications have an effect on the push-out bond strength of both materials (P = 0.002). Biodentine showed better adhesive performance as an apical plug than DiaRoot-BioAggregate. 相似文献
30.
Stabilized electrospinning of heat stimuli/in situ crosslinkable nanofibers and their self‐same nanocomposites 下载免费PDF全文
We present a strategy for stabilizing the morphological integrity of electrospun polymeric nanofibers by heat stimuli in situ crosslinking. Amorphous polymer nanofibers, such as polystyrene (PS) and its co‐polymers tend to lose their fiber morphology during processing at temperatures above their glass transition temperature (Tg) typically bound to happen in nanocomposite/structural composite applications. As an answer to this problem, incorporation of the crosslinking agents, phthalic anhydride (PA) and tributylamine (TBA), into the electrospinning polymer solution functionalized by glycidylmethacrylate (GMA) copolymerization, namely P(St‐co‐GMA), is demonstrated. Despite the presence of the crosslinker molecules, the electrospinning polymer solution is stable and its viscosity remains unaffected below 60 °C. Crosslinking reaction stands‐by and can be thermally stimulated during post‐processing of the electrospun P(St‐co‐GMA)/PA‐TBA fiber mat at intermediate temperatures (below the Tg). This strategy enables the preservation of the nanofiber morphology during subsequent high temperature processing. The crosslinking event leads to an increase in Tg of the base polymer by 30 °C depending on degree of crosslinking. Crosslinked nanofibers are able to maintain their nanofibrous morphology above the Tg and upon exposure to organic solvents. In situ crosslinking in epoxy matrix is also reported as an example of high temperature demanding application/processing. Finally, a self‐same fibrous nanocomposite is demonstrated by dual electrospinning of P(St‐co‐GMA) and stabilized P(St‐co‐GMA)/PA‐TBA, forming an intermingled nanofibrous mat, followed by a heating cycle. The product is a composite of crosslinked P(St‐co‐GMA)/PA‐TBA fibers fused by P(St‐co‐GMA) matrix. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44090. 相似文献