A micro-solid oxide fuel cell system as battery replacement

The concept and the design of a micro-solid oxide fuel cell system is described and discussed. The system in this study is called the ONEBAT system and consists of the fuel cell PEN (positive electrode – electrolyte – negative electrode) element, a gas processing unit, and a thermal system. PEN elements of free-standing multi-layer membranes are fabricated on Foturan^® and on Si substrates using thin film deposition and microfabrication techniques. Open circuit voltages of up to 1.06 V and power of 150 mW cm⁻² are achieved at 550 °C. The membranes are stable up to 600 °C. The gas processing unit allows butane conversion of 95% and hydrogen selectivity of 83% at 550 °C in the reformer and efficient after-burning of hydrogen, carbon monoxide, and lower hydrocarbons in the post-combustor. Thermal system simulations prove that a large thermal gradient of more than 500 °C between the hot module and its exterior are feasible. The correlation between electrical power output – system size and thermal conductivity – heat-transfer coefficient of the thermal insulation material are shown. The system design studies show that the single sub-systems can be integrated into a complete system and that the requirements for portable electronic devices can be achieved with a base unit of 2.5 W and a modular approach.     

Dislocation pile-up and cleavage: effects of strain gradient plasticity on micro-crack initiation in ferritic steel

The paper is devoted to the problem of slow crack growth in heterogeneous media. The crack is subjected to arbitrary pressure distribution on the crack surface. The problem relates to construction of the so-called equilibrium crack. For such a crack, stress intensity factors are equal to the material fracture toughness at each point of the crack contour. The crack shape and size depend on spatial distributions of the elastic properties and fracture toughness of the medium, and the type of loading. In the paper, attention is focused on the case of layered elastic media when a planar crack propagates orthogonally to the layers. The problem is reduced to a system of surface integral equations for the crack opening vector and volume integral equations for stresses in the medium. For discretization of these equations, a regular node grid and Gaussian approximating functions are used. For iterative solution of the discretized equations, fast Fourier transform technique is employed. An iteration process is proposed for the construction of the crack shape in the process of crack growth. Examples of crack evolution for various properties of medium and types of loading are presented.     

Power-to-gas in a smart city context – Influence of network restrictions and possible solutions using on-site storage and model predictive controls

Power-to-gas (P2G or PtG) technology can provide energy storage capacity to the energy system by converting excess electrical energy into hydrogen and feeding it into the natural gas network, where it can be stored. However nowadays hydrogen feed-in has to be limited to certain percentages in order to keep the characteristics of the resulting gas mixture (i.e. heating value) within the national standards. For P2G plants in urban areas this can strongly impact the economic viability. This paper investigates the use of on-site storage and model predictive controller (MPC) to ease the negative effect of restrictions in the gas and power grid on the economics of P2G systems. Three different use-cases for P2G in an urban setting are considered: Optimal utilisation of renewable electricity produced within the boundaries of the city, optimised electricity purchase at the spot market and optimal usage of electric network. MPC is compared to an optimised rule-based control approach. Results show that both controls can be used to meet the objectives and operate the power-to-gas plant. However, the MPC approach results in a smoother operation of the plant and significantly improved economic performance in all cases and is recommended. The results indicate the beneficial effects of on-site hydrogen storage on system operation and economics. For the investigated cases a storage capacity around 6 full load hours of the electrolyser was sufficient to improve results significantly.     

Inline Measurement of the Residence Time Distribution in High-Pressure Extraction Columns

Axial backmixing lowers the efficiency of packed countercurrent high-pressure extraction columns. To quantify backmixing, a method of measuring the residence time distribution and calculating the axial dispersion coefficient in high-pressure extraction columns is introduced. Using a design of experiments, the effect of supercritical and liquid mass flow rates as well as the pressure at a constant temperature on the mean residence time and the axial dispersion coefficient are evaluated for the system water/supercritical CO₂. The experimental data is correlated to the Reynolds and Schmidt number.     

Polyethylene {201} crystal surface: interface stresses and thermodynamics

We describe a method to determine the mechanical and thermodynamic properties of the interface between a polyethylene crystal and melt by united-atom Monte Carlo simulations. In particular, the {201} fold surface is studied in the temperature range 380-450 K. The interface properties are defined by using the concept of a sharp Gibbs dividing surface, which in turn is used to define the interface internal energy and the interface stresses. We find that the internal energy of the interface is of the order 0.3-0.35 J/m². The interface stresses are anisotropic for the {201} crystal surface with values of approximately −0.27 and −0.4 J/m² for the xx- and yy-components, respectively. By way of the Herring equation, the surface tension of the fold surface is independent of shear strains in the interface. The temperature and strain derivatives of the interface properties are also measured and discussed in detail. The influence of the interface internal energy and of phase change contributions on the macroscopic heat capacity of the semi-crystalline material is examined.     

Electrosynthesis of trimethylorthoformate on BDD electrodes

The anodic methoxylation of formaldehyde dimethylacetal (FADMA) to trimethylorthoformate (TMOF) in basic methanol was investigated on boron-doped diamond (BDD) electrodes. Cyclic voltammetry and preparative electrolysis have shown that FADMA is electrochemically inactive in the solvent stability region; nevertheless FADMA can be oxidized in the potential region of methanol oxidation. A reaction scheme involving intermediates of methanol oxidation (methoxy radicals) has been proposed.     

The Saccharomyces cerevisiae NDE1 and NDE2 genes encode separate mitochondrial NADH dehydrogenases catalyzing the oxidation of cytosolic NADH

In Saccharomyces cerevisiae, the NDI1 gene encodes a mitochondrial NADH dehydrogenase, the catalytic side of which projects to the matrix side of the inner mitochondrial membrane. In addition to this NADH dehydrogenase, S. cerevisiae exhibits another mitochondrial NADH-dehydrogenase activity, which oxidizes NADH at the cytosolic side of the inner membrane. To investigate whether open reading frames YMR145c/NDE1 and YDL 085w/NDE2, which exhibit sequence similarity with NDI1, encode the latter enzyme, NADH-dependent mitochondrial respiration was assayed in wild-type S. cerevisiae and nde deletion mutants. Mitochondria were isolated from aerobic, glucose-limited chemostat cultures grown at a dilution rate (D) of 0. 10 h-1, in which reoxidation of cytosolic NADH by wild-type cells occurred exclusively by respiration. Compared with the wild type, rates of mitochondrial NADH oxidation were about 3-fold reduced in an nde1Delta mutant and unaffected in an nde2Delta mutant. NADH-dependent mitochondrial respiration was completely abolished in an nde1Delta nde2Delta double mutant. Mitochondrial respiration of substrates other than NADH was not affected in nde mutants. In shake flasks, an nde1Delta nde2Delta mutant exhibited reduced specific growth rates on ethanol and galactose but not on glucose. Glucose metabolism in aerobic, glucose-limited chemostat cultures (D = 0.10 h-1) of an nde1Delta nde2Delta mutant was essentially respiratory. Apparently, under these conditions alternative systems for reoxidation of cytosolic NADH could replace the role of Nde1p and Nde2p in S. cerevisiae.