Apparatus for steady-state kinetic measurements of the catalytic reduction of nitric oxide by ammonia on iron oxide

The reduction of nitric oxide with ammonia on an unsupported iron oxide catalyst has been studied in a continuous-flow recycle reactor using simulated flue gas. The responses of the employed reactor system to step and pulse inputs of tracer indicate that the system could be regarded as a continuous stirred tank reactor (CSTR). Preliminary tests were carried out to determine the effect of temperature and particle size on the measured reaction rates. Additional experiments were performed in order to study the influence of oxygen and water concentration on these rates. A gas chromatographic system has been developed to analyze the gas components NO, N₂O, NO₂, NH₃, H₂O, O₂, CO₂ and N₂. In addition, the concentrations of NO and NO₂ were measured with a nondisperse infrared (NDUV/NDIR) analyzer.     

An exercise design approach to understanding assessment center dimension and exercise constructs.

Arobust finding in assessment center research is that ratings cluster according to exercises and not dimensions. Seeking further understanding of exercise effects, the authors proposed 2 exercise-based factors (exercise form and exercise content) as sources of variance in assessment center ratings. Exercise designs were manipulated so that 2 levels of form (leaderless group discussions and role-play exercises) were crossed with 2 levels of content (cooperative and competitive task designs). Analysis of variance (ANOVA) and confirmatory factor analysis procedures applied to multitrait–multimethod ratings of 89 high school student assessees revealed that most of the variance in the ratings was explained by exercises and not dimensions. Exercise form accounted for 16% of method variance, whereas exercise content had near zero effect. The form effect was primarily due to higher correlations of dimension ratings across role-play exercises. Practical implications and future directions for exercise design research are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Solubilization of fish muscle proteins with buffers containing sodium dodecyl sulfate

Summary The extraction of fish muscle protein using SDS containing solubilization buffers was studied varying the time and the temperature of solubilization, as well as pH and SDS concentration of the buffer. At pH < 6 the myofbrillar proteins were incompletely solubilized; temperatures of 80-100 °C resulted in protein degradation observable in the SDS-PAGE.Samples of fish muscle containing high amounts of formaldehyde (50 mmoles FA/kg wet weight) could only be solubilised at 100 °C; on the other hand it was possible to solubilize cooked and/or canned products under mild conditions (2% SDS, 1% 2-ME, pH 8.9, shaking for 2 h at 60 °C).

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Solubilisierung von Fischmuskelproteinen durch Natriumdodecylsulfathaltige Puffer

Zusammenfassung Der Einfluß von Solubilisierungszeit und -temperatur, des pH-Wertes und der SDS-Konzentration des Solubilisierungspuffers auf die Extraktion von Fischmuskelproteinen wurde überprüft. Bei pH-Werten < 6 wurden die myofbrillären Proteine nur unvollständig gelöst; Solubilisierungstemperaturen von 80 bis 100 °C führten zu einem in der SDS-PAGE sichtbaren Proteinabbau. Fischmuskelproben mit hohem Formaldehydgehalt (50 mmole FA/kg Feuchtgewicht) ließen sich nur bei 100 °C vollständig solubilisieren; demgegenüber gelang die weitgehende Solubilisierung gegarter und/oder sterilisierter Produkte unter milden Bedingungen (2% SDS, 1% 2-ME, pH 8,9; 2stündiges Schütteln bei 60 °C).

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Abbreviations FA formaldehyde - IEF isoelectric focusing - 2-ME 2-mercaptoethanol - PA polyacrylamide - PAGE polyacrylamide gel electrophoresis - pI isoelectric point - SDS sodium dodecyl sulfate - TMAO trimethylamine oxide - Tris Tris (hydroxymethyl)methylamine     

Structure and Ordination of Epiphytic Invertebrate Communities of Four Coastal Wetlands in Green Bay,Lake Michigan

Epiphytic macroinvertebrate communities of four coastal wetlands of Green Bay, Lake Michigan were compared by taxonomic composition, feeding group composition, and environmental influences using Bray-Curtis ordination. Ordination scores from the most sheltered oligotrophic site, Portage Marsh, were distinct from the eutrophic, exposed sites located in middle and lower Green Bay— Seagull Bar, Little Tail Point, and Dead Horse Bay. Epiphyton chlorophyll a, phytoplankton chlorophyll a, and specific conductance strongly correlated to the ordination axes, indicating the trophic gradient within Green Bay was a primary environmental influence. The feeding group compositions at the sites were consistent with the type and abundance of food available. Portage Marsh is a scraper-shredder system, with macroinvertebrates feeding mainly on epiphyton and coarse particulate detritus. Dead Horse Bay and Little Tail Point are collector systems, sustained by phytoplankton and fine particulate organic matter. Seagull Bar is intermediate in trophic position along the ordination axes, but more closely resemble the latter two sites. The type and abundance of food resources available to these invertebrate communities are influenced by wave exposure, light attenuation, nutrient levels, and algae levels of the littoral and pelagial waters. Macroinvertebrate communities were sensitive to shifts in food resources, which generated shifts in trophic structure.     

Temperature resistance coefficient of composite resistive materials in the mixed-structure approximation

A method of calculating the temperature resistance coefficient and its temperature dependence for resistive materials in the approximation of a matrix-statistical structure is outlined.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 49, No. 3, pp. 477–481, September, 1985.     

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Hinter den Lehrbüchern die vorlesende Forscherpers?nlichkeit, hinter dem Prospekt der Rat des erfahrenen Fachverk?ufers.     

Varieties of working memory as seen in biology and in connectionist/control architectures

Biological and computational concepts that underlie the nature of working memory are briefly reviewed. The conceptualization of working memory has changed dramatically in the last 30 years. Current biological work has monitored several aspects of memory, including activation decay, sustained activation, long-term connection change, and differential structures for episodic (hippocampal formation) and procedural learning. Current connectionist modeling has identified factors including multiple-region-based processing, control processing as well as data storage, tradeoffs between fast- and slow-connection-change learning effects, and the speeding of acquisition via multiple levels of learning. The need to relate the biological, behavioral, and computational constraints into models of working memory is discussed. Finally, conceptualizations of working memory must acknowledge the need for human learning systems to be robust enough to operate in a dynamic world.