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91.
Takeyuki Suzuki Tsutomu Yamazaki Hiroshi Yoshioka Kuniyuki Hikichi 《Journal of Materials Science》1988,23(1):145-149
Amorphous SnOx films were deposited by ion-beam sputtering on sintered alumina substrates. Amorphous film sensors were prepared by annealing the films at 300° C for 2 h in air. The thickness dependence of resistivity and hydrogen gas sensitivity were measured at 150° C over the thickness range 1 to 700 nm. A resistivity maximum was observed in ultrathin films. Resistivity increased by three orders of magnitude with increasing film thickness from 0.9 to 7.4 nm and then decreased by five orders of magnitude from 7.4 to 35 nm. Ultrathin film sensors showed sensitivity maxima around a thickness of 10 nm. Sensitivity and resistivity of ultrathin films were significantly influenced by the thermal expansion coefficient and the surface state of the substrate. 相似文献
92.
Isao Mochida Hiroshi Toshima Yozo Korai Tsutomu Naito 《Journal of Materials Science》1988,23(2):678-686
Polyphenyleneoxide was blended in amounts of 5 or 10 wt% into petroleum-derived mesophase pitch to reinforce the pitch fibre before the oxidative stabilization to achieve better handling properties. Although polyphenyleneoxide was fusible but hardly soluble in the mesophase pitch even at a spinning temperature of 350° C, blended pitch could be smoothly spun into pitch fibre 10m diameter, as could the parent pitch. Fibrous polyphenyleneoxide of less than 1m diameter was homogeneously dispersed in the pitch fibre, being arranged along the fibre axis. Such fibrous polyp henyleneoxide reinforced the pitch fibre considerably. The fibrous substances at the centre of the fibre disappeared in the carbonized fibre at 1300° C after oxidation at 250° C, although some short ones were observed in the skin region of the fibre, suggesting that polyphenyleneoxide was co-carbonized to be assimilated with mesophase pitch at the centre of the fibre, where the effects of oxidation may be rather limited. The oxidation reactivity and its mechanical strength after carbonization were slightly lower in comparison with those of the parent mesophase pitch. 相似文献
93.
We present a theory of the response ofd-wave superconductors to weak applied fields, by taking account of the Coulomb interaction and all the collective degrees of freedom as well as crystal symmetry. We choose two representative phases: the d phase, which has point nodes in the energy gap, and theY
2–1 phase, which has line as well as point nodes. The former is a self-consistent solution for cubic as well as spherical symmetries and the latter is one for spherical, cubic, and hexagonal symmetries. We obtain obviously gauge-invariant expressions for the order-parameter fluctuations and the currents, having forms common not only to thed-wave states, but also to thep-wave states studied earlier. We also investigate the collective excitations; in the long-wavelength limit for spherically symmetric systems, there are, on the frequency-temperature plane, seven branches for eachd-wave phase considered, in addition to the common plasma mode and orbital Goldstone modes resulting from the spontaneous breakdown of the rotational invariance. In theY
2–1-phase two eigenmodes are found to become gapless at a finite temperature, below which they are purely imaginary. This implies instability of the phase. The effect of crystal anisotropy on the collective spectra is also studied.A preliminary report on the present work was published inJpn. J. Appl. Phys. Suppl.
26-3, 167 (1987). 相似文献
94.
Rod-shaped BaTiO3 powder particles have been prepared from rod-shaped TiO2 ·nH2O and BaCO3 in molten chloride. The morphology of BaTiO3 particles was studied referring to the effects of the chemical species of the starting titanium compound, amount of chloride, particle size of the titanium compound and reaction conditions, and the preparation condition of rod-shaped BaTiO3 has been determined: i.e., large TiO2 ·nH2O particles were heated at 700°C in molten salt with an equal amount of BaTiO3. This condition was effective in suppressing the formation of BaTiO3 by a solution-precipitation process as well as the deformation of either TiO2 ·nH2O or BaTiO3, which are responsible for the formation of equiaxed BaTiO3 particles. The obtained rod-shaped BaTiO3 particles had a cubic symmetry. Electron diffraction analysis showed that the following topotactic relation is retained; 0 1 0potassium tetratitanate 0 1 0hydrated titania 1 0 0anatase 1 0 0barium titanate 相似文献
95.
The activities of FexO in CaO + CaF2 + SiO2 + FexO quaternary slags were measured by means of solid-oxide galvanic cell. The FexO activities in the slags are influenced by CaF2 as well as SiO2. At constant FexO mole fractions, e.g., , at low SiO2 mole fractions i.e., , the substitution of CaF2 for CaO has an effect of raising the FexO activity. At higher SiO2 mole fractions, e.g., , however, such an effect becomes insignificant. 相似文献
96.
The change of the conductivity in the rare earth perovskite oxide took place after the chemisorption of flammable gases. The sensitivity for methanol was highest. From the conductivity change of these perovskite oxides after the injection of methanol, the energy needed to promote an electron from a conducting to a nonconducting state, E=E
c-E
t, could be derived from the equation=A
0 exp (–E/kT). LnCoO3 had the smallest E and H (metal-O), which is the binding energy of oxygen coordinating to the metal ions, but exhibited the highest activity for gas sensing. The gas sensing mechanism was also considered. 相似文献
97.
Modified quadratic discriminant functions and the application to chinese character recognition 总被引:8,自引:0,他引:8
Kimura F Takashina K Tsuruoka S Miyake Y 《IEEE transactions on pattern analysis and machine intelligence》1987,(1):149-153
Issues in the quadratic discriminant functions (QDF) are discussed and two types of modified quadratic disriminant functions (MQDF1, MQDF2) which are less sensitive to the estimation error of the covariance matrices are proposed. The MQDF1 is a function which employs a kind of a (pseudo) Bayesian estimate of the covariance matrix instead of the maximum likelihood estimate ordinarily used in the QDF. The MQDF2 is a variation of the MQDF1 to save the required computation time and storage. Two discriminant functions were applied to Chinese character recognition to evaluate their effectiveness, and remarkable improvement was observed in their performance. 相似文献
98.
Natsuhiko Kuratomi Shinichi Takano Mitsuharu Fukasawa Shinya Maekawa Makoto Kadokura Hiroko Shindo Ei Takahashi Sumio Hirose Yoshimitsu Fukasawa Satoshi Kawakami Hiroshi Hayakawa Hitomi Takada Natsuko Nakakuki Ryoh Kato Tatsuya Yamaguchi Yasuhiro Nakayama Hiromichi Kawaida Hiroshi Kono Taisuke Inoue Tetsuo Kondo Daisuke Ichikawa Nobuyuki Enomoto 《International journal of molecular sciences》2021,22(6)
New biomarkers are needed to further stratify the risk of malignancy in intraductal papillary mucinous neoplasm (IPMN). Although microRNAs (miRNAs) are expected to be stable biomarkers, they can vary owing to a lack of definite internal controls. To identify universal biomarkers for invasive IPMN, we performed miRNA sequencing using tumor-normal paired samples. A total of 19 resected tissues and 13 pancreatic juice samples from 32 IPMN patients were analyzed for miRNA expression by next-generation sequencing with a two-step normalization of miRNA sequence data. The miRNAs involved in IPMN associated with invasive carcinoma were identified from this tissue analysis and further verified with the pancreatic juice samples. From the tumor-normal paired tissue analysis of the expression levels of 2792 miRNAs, 20 upregulated and 17 downregulated miRNAs were identified. In IPMN associated with invasive carcinoma (INV), miR-10a-5p and miR-221-3p were upregulated and miR-148a-3p was downregulated when compared with noninvasive IPMN. When these findings were further validated with pancreatic juice samples, miR-10a-5p was found to be elevated in INV (p = 0.002). Therefore, three differentially expressed miRNAs were identified in tissues with INV, and the expression of miR-10a-5p was also elevated in pancreatic juice samples with INV. MiR-10a-5p is a promising additional biomarker for invasive IPMN. 相似文献
99.
Dr. Daisuke Okuno Dr. Noriho Sakamoto Dr. Mohammed S. O. Tagod Yoshiko Akiyama Dr. Sakiko Moriyama Dr. Takuto Miyamura Dr. Atsuko Hara Dr. Takashi Kido Dr. Hiroshi Ishimoto Prof. Yuji Ishimatsu Prof. Takashi Tanaka Prof. Jun Ishihara Prof. Kohsuke Takeda Prof. Yoshimasa Tanaka Prof. Hiroshi Mukae 《ChemMedChem》2021,16(16):2515-2523
Heat shock protein 47 (HSP47), a collagen-specific molecular chaperone, is causally related to fibrotic diseases, including idiopathic pulmonary fibrosis. The identification of Compounds that interfere with the HSP47-collagen interaction is essential for the development of relevant therapeutics. Herein, we prepared human HSP47 as a soluble fusion protein expressed in E. coli and established an assay system for HSP47 inhibitor screening. We screened a natural and synthetic Compound library established at Nagasaki University. Among 1023 Compounds, 13 exhibited inhibitory activity against human HSP47, of which three inhibited its function in a dose-dependent manner. Epigallocatechin-3-O-gallate, one of these three Compounds, is a typical polyphenol Compound derived from tea leaves. Structurally related Compounds were synthesized and examined for their activity, revealing a hydroxyl group at A-ring position 5 as important for its activity. The present findings provide valuable insight for the development of natural product-derived therapeutics for fibrotic diseases, including idiopathic pulmonary fibrosis. 相似文献
100.
Knowledge based approach is effective for renovating design and manufacturing processes. The objective of this paper is to investigate roles and usages of expert engineering knowledge in high-quality manufacturing, and to study a practical knowledge capturing method for realizing engineering support tools. An engineer oriented interface for a capturing method is proposed, and a flexible representation framework is studied for various types of expert knowledge. An integrated knowledge-based system has been developed for mold design support. The results have been evaluated by design and manufacturing of molds for cellular phones, and have shown substantial reduction of lead time for mold production. 相似文献