XPS studies of perovskites surface instability caused by Ar+ ion and electron bombardment and metal deposition

X-ray Photoelectron Spectroscopy (XPS) was used to study the influence of low energy Ar⁺ ion bombardment, electron bombardment and Pt deposition on the SrTiO₃ (STO) single crystal electronic structure. Atomic composition changes were found and attributed to chemical reconstruction of the STO surface. A clear correlation between the presence of conducting, low Ti oxidation states in valence band and core level changes was detected. A strong effect caused by electron irradiation was ascribed to the electroreduction process. The influence of lanthanum doping on surface instability of STO was also discussed. The La doped sample (STO: 3,75% La) was found to be modified upon Pt metal deposition to a higher degree than pure STO crystal.     

Technical foundations for noninvasive assessment of changes in the width of the subarachnoid space with near-infrared transillumination-backscattering sounding (NIR-TBSS)

This paper presents technical foundations for a new technique of near-infrared transillumination-backscattering sounding, which is designed to enable noninvasive detection and monitoring of changes in the width of the subarachnoid space (SAS) and magnitude of cerebrovascular pulsation in humans. The key novelty of the technique is elimination of influence of blood flow in the scalp on the signals received from two infrared sensors-proximal and distal. A dedicated digital algorithm is used to estimate on line the ratio of the powers of received signals, referred to as two-sensor distal-to-proximal received power quotient, TQ (t). The propagation duct for NIR radiation reaching the distal sensor is the SAS filled with translucent cerebrospinal fluid. Information on slow fluctuations of the average width of the SAS is contained in the slow-variable part of the TQ (t), called the subcardiac component, and in TQ itself. Variations in frequency and magnitude of faster oscillations of the width of that space around the baseline value, dependent on cerebrovascular pulsation, are reflected in instantaneous frequency and envelope of the fast-variable component. Frequency and magnitude of the cerebrovascular pulsation depend on the action of the heart, so this fast-variable component is referred to as the cardiac component.     

How to get the most out of two phosphorus chemistries. Studies on H-phosphonates

The biological importance and practical significance of phosphate esters and their analogues have been the major driving forces for research in various areas of synthetic organic phosphorus chemistry. In this Account, the authors' studies on the development of a comprehensive H-phosphonate methodology and the underlying chemistry for the preparation of biologically important phosphate esters and their analogues are briefly discussed.     

Effects of the abdominal belt on muscle-generated spinal stability and L4/L5 joint compression force

The goals of this study were (1) to determine the effects of abdominal belts on muscle-generated active lumbar spine stability, (2) to determine their effect on the subsequent joint compression force at L4/L5 and (3) to determine whether the effective stability of the spine could be predicted by the active spine stability and belt condition. Electromyographic (EMG) and trunk stiffness data from a previously reported experiment in which 10 subjects performed quick-release tasks (perturbation) with and without an abdominal belt were used as inputs to biomechanical models to estimate the active spine stability and effective stability of the spine, respectively. The subjects exerted isometric trunk flexion, extension and lateral bending trials at 0 and 80% of maximum intra-abdominal pressure when the resisted force was suddenly released. Wearing an abdominal belt had no significant effect on either the muscle-generated lumbar spine stability or the L4/L5 joint compression force in any direction. The effective stability of the spine was adequately predicted by the active spine stability and the effect of the belt, which accounted for approximately 34% of the effective spine stability. The study demonstrated that the abdominal belt contributed to the passive stability of the lumbar spine and did not change the active stability for tests performed within the same experimental session.     

Early and late results of surgical treatment in patients with primary mediastinal germ cell tumors]

A group of 37 patients--20 (54%) men and 17 (46%) women--aged 2-65, mean 31.6 years, was treated between 1978 and 1995 for different kinds of primary mediastinal germ cell tumours. In 14 (37.8%) of them a mature solid teratoma was diagnosed, in 13 (35.1%)--dermoid cyst, in 5 (13.5%)--malignant teratoma, in 1 (2.7%)--immature teratoma, in 4 (10.8%)--seminoma. Mediastinal tumour was removed completely in 30 (81.1%) patients, partially in 7 (18.9%). Out of 37 patients, 3 (8.1%) died during postoperative time. Out of 26 patients discharged after surgical removal of mature teratomas, all are alive and have been followed-up for 10 years (17 patients) or 5 years (6 patients). Out of 8 discharged after surgical removal of malignant neoplasm, 3 are alive and all of them had primary mediastinal seminoma. One of them has survived 17 years after complete resection, and two patients--7.5 years and 2 years after partial resection and radiotherapy. Mean survival time is 4 years and 2 months for all patients with malignant neoplasm.     

Data Flow Anomaly Detection

The occurrence of a data flow anomaly is often an indication of the existence of a programming error. The detection of such anomalies can be used for detecting errors and to upgrade software quality. This paper introduces a new, efficient algorithm capable of detecting anomalous data flow patterns in a program represented by a graph. The algorithm based on static analysis scans the paths entering and leaving each node of the graph to reveal anomalous data action combinations. An algorithm implementing this type of approach was proposed by Fosdick and Osterweil [2]. Our approach presents a general framework which not only fillls a gap in the previous algorithm, but also provides time and space improvements.     

A heuristic approach to the reinforcement-learning control of the one-dimensional model of an HTR core

Results of calculations are presented, which are concerned with applications of the heuristic linear reinforcement systems to the control of pebble-bed HTRs with the OTTO-loading scheme. Control results of three types of systems applications are presented and discussed. The systems were found to be satisfactory for control of the complex physical plants.     

Organotin compounds in the liver tissue of marine mammals from the Polish coast of the Baltic Sea

Butyltins (BTs) and phenyltins (PhTs) were determined in the livers of marine mammals found by-caught or stranded along the Polish coast of the Baltic Sea. During the investigation an original analytical method was developed. Butyltin compounds were detected in all the liver samples, whereas phenyltins were not detected in any of the samples. The total concentrations of BTs ranged from 43.9 to 7698 ng(Sn) x g(-1) dry weight. Age-related trends to accumulate BTs in immature porpoises were found. At the same time there were no male-female differences in BTs concentrations observed. No statistically significant spatial distribution differences were found between the locations corresponding to the open Baltic Sea waters and inside the Gulf of Gdańsk, which is characterized by high maritime activity. In comparison to butyltin levels in marine mammals from other geographic regions, the samples analyzed indicate a significant degree of tributyltin pollution along the Polish coast of the Baltic Sea. On the basis of a literature review, higher BT levels are usually found in waters close to highly industrialized areas, such as Japan, Hong Kong, and the United States.     

Computationally effective algorithm for robust weighted averaging

One of the greatest disadvantages of the weighted signal averaging method is its sensitivity to the presence of noise and outliers in data and the need to estimate the noise variance in all signal cycles. The robust weighted averaging method based on the epsilon-insensitive loss function is free of these disadvantages, but has a very high computational burden and requires a choice of the insensitivity parameter epsilon. In this study, a new computationally effective algorithm for robust weighted averaging with automatic adjustment of the insensitivity parameter is introduced.