Shaping Luminescent Properties of Yb3+ and Ho3+ Co‐Doped Upconverting Core–Shell β‐NaYF4 Nanoparticles by Dopant Distribution and Spacing

At the core of luminescence color and lifetime tuning of rare earth doped upconverting nanoparticles (UCNPs), is the understanding of the impact of the particle architecture for commonly used sensitizer (S) and activator (A) ions. In this respect, a series of core@shell NaYF₄ UCNPs doped with Yb³⁺ and Ho³⁺ ions are presented here, where the same dopant concentrations are distributed in different particle architectures following the scheme: YbHo core and YbHo@…, …@YbHo, Yb@Ho, Ho@Yb, YbHo@Yb, and Yb@YbHo core–shell NPs. As revealed by quantitative steady‐state and time‐resolved luminescence studies, the relative spatial distribution of the A and S ions in the UCNPs and their protection from surface quenching has a critical impact on their luminescence characteristics. Although the increased amount of Yb³⁺ ions boosts UCNP performance by amplifying the absorption, the Yb³⁺ ions can also efficiently dissipate the energy stored in the material through energy migration to the surface, thereby reducing the overall energy transfer efficiency to the activator ions. The results provide yet another proof that UC phosphor chemistry combined with materials engineering through intentional core@shell structures may help to fine‐tune the luminescence features of UCNPs for their specific future applications in biosensing, bioimaging, photovoltaics, and display technologies.     

Biofunctionalized upconverting CaF<Subscript>2</Subscript>:Yb,Tm nanoparticles for <Emphasis Type="Italic">Candida albicans</Emphasis> detection and imaging

Versatile optimization of the synthesis method and composition of Yb3+ and Tm3+ co-doped CaF2 nanoparticles as well as a novel biofunctionalization method were developed and evaluated.Through multistep synthesis,the luminescence intensity of the Tm3+ activator was enhanced by more than 10-fold compared to standard one-step synthesis.The proposed methods were used to homogenously distribute the doping ions within the nanoparticle's volume and thus reduce luminescence quenching.Optimization of dopant ions concentration led to the selection of the most efficient visible and near-infrared up-converting nanoparticles,which were CaF2 doped with 10％ Yb3+ 0.05％ Tm3+ and 20％ Yb3+ 0.5％ Tm3+,respectively.To illustrate the suitability of the synthesized nanoparticles as bio-labels,a dedicated biofunctionalization method was used,and the nanoparticles were applied for labeling and imaging of Candida albicans cells.This method shows great promise because of extremely low background and high specificity because of the presence of the attached molecules.     

Measurement and analysis of the water hammer in ram pump

Sādhanā - This paper presents the results of experimental research of the phenomena occurring in water ram during a single cycle of its operation. Apart from a brief introduction and...     

Application of a material fatigue damage model in 4PB tests

The fatigue property of an asphalt mix is an important issue in pavement design. This property is often determined with the aid of a four-point bending (4PB) test in controlled deflection mode. The fatigue property is related to the decrease in the calculated complex stiffness modulus, however, due to the non- homogenous stress and strain field in the beam, the measured response does not represent the stiffness modulus of the material but a weighted stiffness value. For a correct interpretation, a fatigue damage material model like the Asphalt Concrete Pavement-Fatigue model is needed. After integration, the calculated and measured responses are compared. By varying the model parameters, an excellent comparison between the two responses is obtained up to a certain number of cycles. This number of cycles is denoted as the fatigue life N _PH . The accumulated dissipated energy at the surface of the beam in the midsection can be expressed as a constant times the fatigue life N _PH to the power z and also as a constant times the product of the fatigue life N _PH and the initial dissipated energy in the first cycle. Using these two findings, a Wöhler curve was established similar to the one directly based on the strain amplitudes and fatigue life data.     

Recommendation of RILEM Technical Committee 250-CSM: Test method for Textile Reinforced Mortar to substrate bond characterization

Textile Reinforced Mortar (TRM), also known as Fabric Reinforced Mortar or Fabric Reinforced Cementitious Matrix, composites are an emerging technology for the external repair and strengthening of existing structures. For most applications, the effectiveness of the TRM reinforcement relies on its bond performance. This recommendation identifies the best practice to characterize the bond behaviour of TRM. A shear bond test method is proposed to determine the peak axial stress (associated with the maximum load that can be transferred from the structural member to the externally bonded TRM reinforcement), the stress–slip relationship and the failure mode that controls the TRM-to-substrate load transfer capacity. Guidelines on specimen manufacturing, experimental setup, test execution, and determination of test results are provided.     

Insulin-like growth factor I-dependent regulation of prolidase activity in cultured human skin fibroblasts

In metastatic breast cancer the goal to reach must be the best possible palliation with minimum discomfort for the patient. We reviewed our experience with radiotherapy (20 or 30 Gy), systemic therapy and brace. Among 2200 breast cancer patients, we extracted 28 potential candidates for resection. All of them developed new metastases outside the treated field within one year. Local control was achieved in 68%, and 80% of them had stable or better performance status at 3 months. From our analysis, even patients with a so called "solitary lesion" do not seem to have a better prognosis than others. We conclude that radiotherapy (with systemic therapy and a brace) is still first-choice treatment for vertebral metastases; CT-guided percutaneous biopsy can avoid worthless major operations. The role of surgery should be limited to neurological compression, severe mechanical instability and to salvage the failures of conservative treatment.     

Cellular decomposition in Fe-26Ni-(2-3)Ti-Nb steels with an addition of aluminium or molybdenum

Cellular decomposition in three Fe-26Ni-(2-3)Ti-Nb type steels was investigated. One of these steels was alloyed with molybdenum while the two others, differing in grain size, contained an addition of aluminium. In Ni26AITi3Nb and Ni26MoTi2Nb steels quenched from 1223 K in water, the first colonies of decomposition were observed after holding for 4 h at 923 K. A longer holding at this temperature resulted in growth of decomposition cells in the steel with molybdenum while in the steels with aluminium, a halting of the decomposition and the appearance of isolated plates of the phase was observed. In Ni26MoTi2Nb and Ni26Al2Ti3Nb steels, quenched in water and subsequently cold treated in liquid nitrogen, repeated heating in the temperature range 293–999.9 K at a rate of 2.5,10 and 40 Kmin^–1 and cooling at a rate 320 Kmin^–1 favoured the cellular decomposition more markedly in the steel with molybdenum. On cooling to room temperature, austenite within the decomposition cells transformed into martensite. The tendency to cellular decomposition depended to a higher degree on the factors which stabilize austenite as well as on the presence of precipitates in grain boundaries, than on the grain size.