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61.
Sumit K. Mishra Nabanita Saha S. Singh Chhemendra Sharma M. V. S. N. Prasad Sachin Gautam Amit Misra Abhishek Gaur Deepika Bhattu Subhasish Ghosh Anubhav Dwivedi Rosalin Dalai Debajyoti Paul Tarun Gupta Sachchida N. Tripathi R. K. Kotnala 《Mapan》2017,32(3):229-241
Estimation of the direct radiative forcing (DRF) by atmospheric particles is uncertain to a large extent owing to uncertainties in their morphology (shape and size), mixing states, and chemical composition. A region-specific database of the aforementioned physico-chemical properties (at individual particle level) is necessary to improve numerically-estimated optical and radiative properties. Till date, there is no detailed observation of the above mentioned properties over Kanpur in the Indo-Gangetic Plain (IGP). To fill this gap, an experiment was carried out at Kanpur (IITK; 26.52°N, 80.23°E, 142 m msl), India from April to July, 2011. Particle types broadly classified as (a) Cu-rich particles mixed with carbon and sulphur (b) dust and clays mixed with carbonaceous species (c) Fe-rich particles mixed with carbon and sulfur and (d) calcite (CaCO3) particles aged with nitrate, were observed. The frequency distributions of aspect ratio (AR; indicator of extent of particle non-sphericity) of total 708 particles from April to June reveal that particles with aspect ratio range >1.2 to ≤1.4 were abundant throughout the experiment except during June when it was found to shift to high AR range, >1.4 to ≤1.6 (followed with another peak of AR i.e. >2 to ≤2.4) due to dust storm conditions enhancing the occurrence of more non-spherical particles over the sampling site. The spherical particles (and close to spherical shape; AR range, 1.0 to ≤1.2) were found to be <20% throughout the experiment with a minimum (11.5%) during June. Consideration of Homogeneous Equivalent Sphere Approximation (HESA) in the optical/radiative model over the study region is found to be irrelevant during the campaign. 相似文献
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This paper is a case study of visiting an external audit company to explore the usefulness of machine learning algorithms for improving the quality of an audit work. Annual data of 777 firms from 14 different sectors are collected. The Particle Swarm Optimization (PSO) algorithm is used as a feature selection method. Ten different state-of-the-art classification models are compared in terms of their accuracy, error rate, sensitivity, specificity, F measures, Mathew’s Correlation Coefficient (MCC), Type-I error, Type-II error, and Area Under the Curve (AUC) using Multi-Criteria Decision-Making methods like Simple Additive Weighting (SAW) and Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS). The results of Bayes Net and J48 demonstrate an accuracy of 93% for suspicious firm classification. With the appearance of tremendous growth of financial fraud cases, machine learning will play a big part in improving the quality of an audit field work in the future. 相似文献
64.
Ashish Nadar Atindra Mohan Banerjee M.R. Pai R.V. Pai Sher Singh Meena R. Tewari A.K. Tripathi 《International Journal of Hydrogen Energy》2018,43(1):37-52
Supported iron oxides have been established as an important class of catalyst for high temperature sulfuric acid decomposition. With an objective to elucidate the role of support in modifying the overall catalytic properties of dispersed iron oxide catalysts, a series of supported iron oxide based catalysts, Fe2O3 (15 wt%)/MO2 (M = Zr, Ce, Ti and Si), synthesized by adsorption-equilibrium method, is investigated for sulfuric acid decomposition reaction. The structure of dispersed iron oxide phases largely depended on the nature of the support oxide as revealed by the XRD and Mössbauer studies. α-Fe2O3 is found to be present as a major phase on ZrO2 and CeO2 support while ε-Fe2O3 was the major phase on silica supported iron oxide. On the other hand, presence of mixed oxide Fe2TiO5 was revealed over TiO2 support. Strong dispersed metal oxide-support interactions inhibited the total reduction of the dispersed phase on SiO2 and TiO2 as compared to complete reduction of dispersed iron oxide on CeO2 and ZrO2 supports during temperature programmed reduction upto 1000 °C. The order of catalytic activity at a temperature of ~750 °C is observed as Fe2O3/SiO2 > Fe2TiO5/TiO2 > Fe2O3/ZrO2 > Fe2O3/CeO2, while at higher temperatures of ~900 °C the SO2 yield is found to be comparable for all catalysts. A relationship between the rate of sulfate decomposition and catalytic activity is established through detailed TG-DTA investigations of sulfated catalyst and support. Considerable influence of the support oxide on the composition, structure, redox properties, morphology and catalytic activities of the active iron oxide dispersed phase has been observed. Thus, the support oxides operate as a critical component in the complex supported metal oxide catalysts and these findings might influence the design and development of future high temperature sulfuric acid decomposition catalysts. 相似文献
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The thermodynamic analysis and parametric study of an intercooled–reheat closed-cycle gas turbine is presented in this paper, on the basis of a new (harmonic mean) isentropic exponent. An analytical expression is derived for the optimum pressure ratio and maximum non-dimensional net work output. It is found that the optimum pressure ratio and the maximum non-dimensional net work are high when the ratio of extreme temperatures of cycle (i.e. T max and T min) and isentropic efficiencies of compressor and turbine (i.e. ηc and ηt) are high. The theoretical results are also compared with the practical conditions of power plant. 相似文献
67.
S. L. Agrawal Markandey Singh Mridula Tripathi Mrigank Mauli Dwivedi Kamlesh Pandey 《Journal of Materials Science》2009,44(22):6060-6068
Present work deals with findings on dielectric relaxation behaviour and a.c. conduction in a SiO2-doped polymer nanocomposite electrolyte system, namely, [(100 − x)PEO + xSiO2]:yNH4SCN. The formation of nanocomposite has been ascertained by XRD measurements. The effect of salt and filler (SiO2) on conductivity response of PEO-based nanocomposite polymer electrolyte has been investigated by impedance spectroscopy.
The variation of dielectric permittivity, dielectric loss and modulus spectra with frequency and temperature was carried out
from impedance spectroscopy data. The a.c. conductivity seems to follow the universal power law. 相似文献
68.
Abhishek Gawasane Laura Bix Javier de la Fuente Raghav Prashant Sundar Timothy J. Smith 《Packaging Technology and Science》2012,25(7):385-396
The study consisted of three objectives: (a) to test the relative prominence and conspicuousness of a warning required by US law to be conspicuous; (b) to explore whether or not the conspicuousness of the said warning can be enhanced graphically; and (c) to develop preliminary data for power analysis that would guide decisions related to sample size in future studies. Seventeen subjects viewed four over‐the‐counter drug packages (each with a different style of warning) along with five other products while wearing an eye tracking device. Four styles of warning were used on the over‐the‐counter drug packages: no outline and no fill, outline and no fill, no outline and fill, and outline and fill. The surface area and the placement of the warnings were held constant across all four designs and were consistent with those on commercially available products. Collected data were broken into five zones: warning, brand name, strength, product benefit and net weight. Despite the fact that US law requires it to be conspicuous, the tested warning was significantly less noticeable than the brand name (objective one) for all dependent variables analyzed (α = 0.05). No significant difference was indicated for the varied warning designs (objective two). This could be because not much can be done to enhance prominence when constrained to the limited space that is typically used for such warnings or because of the limited sample size. Power calculations suggest that a sample size of nearly 200 subjects would be required to detect a 2.5 s mean difference at 80% confidence (objective three). Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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