An Efficient,Stable and Reusable Palladium Nanocatalyst: Chemoselective Reduction of Aldehydes with Molecular Hydrogen in Water

Palladium nanoparticles (Pd‐BNP) stabilized by a binaphthyl‐backbone can be efficiently used for the chemoselective reduction of aldehydes in the presence of hydrogen at room temperature in water. The Pd‐BNP catalyst is easily recovered and reused for five catalytic cycles.

     

Studies on the physicochemical characteristics of volatile oil from pepper (Piper nigrum) extracted by supercritical carbon dioxide

Pepper (Piper nigrum L) volatile oil was extracted with supercritical fluid carbon dioxide at pressures of 8 and 10 MPa and at two different temperatures, 40°C and 60°C. The mass transfer rates are presented at different supercritical conditions of extraction, together with the fractionation effect that was observed. The volatile oil obtained was analysed for its physical constants: specific gravity, refractive index and optical rotation. The samples were fractionated by column chromatography, and both the samples and fractions were subjected to TLC, gas chromatography and sensory analysis. It was observed that pepper oil obtained with supercritical fluid carbon dioxide at 10 MPa and 60°C was superior to steam-distilled oil.     

A STOCHASTIC CHARACTERIZATION OF THE MACHINE TOOL WORKPIECE SYSTEM IN BTA OEEP HOLE MACHINING Part I: Mathematical Modelling and Analysis

A three dimensional model of the BTA deep-hole machining system is presented by modelling each of the components separately and later combining to represent the total system. A model for the interaction between the workpiece and the cutting tool is also included. Such a model can determine the response of any component of the machine tool as well as the individual influence on the system performance. Based on this, physical models representing the three working methods in the BTA process can be studied, from which stochastic differential equations are derived to represent the resultant force system on the machine tool

A physical model for the stationary workpiece and rotating cutting tool working method is developed. The assumed modes method along with the Lagrange' equation is used to obtain the stochastic differential equation to represent the influence of axial force and torque, in order to obtain the response of the system under the action of the axial force and torque to predict the stability behaviour.     

Hybrid Authentication Using Node Trustworthy to Detect Vulnerable Nodes

An ad-hoc sensor network (ASN) is a group of sensing nodes that transmit data over a wireless link to a target node, direct or indirect, through a series of nodes. ASN becomes a high-risk group for several security exploits due to the sensor node’s limited resources. Internal threats are more challenging to protect against than external attacks. The nodes are grouped, and calculate each node’s trust level. The trust level is the result of combining internal and external trust degrees. Cluster heads (CH) are chosen based on the anticipated trust levels. The communications are then digitally signed by the source, encoded using a key pair given by a trustworthy CH, decoded by the recipient, and supervised by verifications. It authenticates the technique by identifying the presence of both the transmitter and the recipient. Our approach looks for a trustworthy neighboring node that meets the trust threshold condition to authenticate the key produced. The companion node reaffirms the node’s reliability by getting the public-key certification. The seeking sensor node and the certification issuer node must have a close and trusting relationship. The results of the proposed hybrid authentication using a node trustworthy (HANT) system are modeled and tested, and the suggested approach outperforms conventional trust-based approaches in throughput, latency, lifetime, and vulnerability methods.     

Anatase-rutile transformation in Fe/TiO2, Th/TiO2 and Cu/TiO2 catalysts and its possible role in metal-support interaction

Based onin-situ Mössbauer and X-ray diffraction studies, it is shown that in the Fe/TiO₂ catalyst, the anatase-rutile transformation of the TiO₂ support is facilitated by the Fe²⁺ ions formed during the reduction. The transformation occurs at lower temperatures in Th/TiO₂ and Cu/TiO₂ compared to pure TiO₂. In general, the transformation of anatase to rutile seems to occur at or below the temperature (770 K) at which strong-metal-support-interaction manifests itself.Contribution No. 718 from the Solid State and Structural Chemistry Unit.     

A computer program for automatic generation of stiffness and mass matrices in finite-element analysis

A computer program to generate automatically the stiffness and mass matrices in finite element analysis is introduced. By using programs like this, researchers only need to derive the expressions for the energies (strain or kinetic) and the expressions for the displacements or stresses and their derivatives in terms of nodal variables. Tedious calculations to obtain the matrices are avoided. Such programs would facilitate checking of existing matrices and would encourage researchers to try out new finite element models.     

Hot Corrosion Behaviour of Detonation-Gun Sprayed Cr3C2–NiCr Coating on Inconel-718 in Molten Salt Environment at 900 °C

Detonation gun sprayed Cr₃C₂–NiCr coating was deposited on nickel-based superalloy Inconel-718. Hot corrosion studies were conducted on uncoated as well as Cr₃C₂–NiCr coated superalloy in 75 wt% Na₂SO₄ + 25 wt% NaCl salt environment at 900 °C for 50 cycles. The thermo-gravimetric technique was used to establish kinetics of corrosion. X-ray diffraction and scanning electron microscopy/energy-dispersive X-ray analysis techniques were used to analyze the corrosion products. The uncoated superalloy suffered intense spalling, while the Cr₃C₂–NiCr coating provided good protection against hot corrosion in the given salt environment.     

Generation of vertex connected subgraphs for multi-input multi-output reliability networks

In this paper, the problem of evaluation of reliability (probability of success) of a network consisting of several inputs and outputs is studied. Edges are assumed to be perfect and vertices are assigned the probabilities of success. A new concept called “vertex connected subgraph” is introduced for this purpose. This concept is useful even for dense graphs because they are of the order of 2^(v-k-1) which is independent of e, where ν(e) is the number of vertices (edges) and k is the number of outputs of a graph.     

Conformation Analysis of GalNAc‐Appended Sugar Amino Acid Foldamers as Glycopeptide Mimics

Sugar amino acid (SAA)‐based foldamers with well‐defined secondary structures were appended with N‐acetylgalactosamine (GalNAc) sugars to access sequence‐defined, multidentate glycoconjugates with full control over number, spacing and position. Conformation analysis of these glycopeptides by extensive NMR spectroscopic studies revealed that the appended GalNAc units had a profound influence on the native conformational behaviour of the SAA foldamers. Whereas the 2,5‐cis glycoconjugate showed a helical structure in water, comprising of two consecutive 16‐membered hydrogen bonds, its 2,5‐trans congener displayed an unprecedented 16/10‐mixed turn structure not seen before in any glycopeptide foldamer.